Second-Order Nonlinear Circular Dichroism in Square Lattice Array of Germanium Nanohelices.

Second-harmonic generation (SHG) is prohibited in centrosymmetric crystals such as silicon or germanium due to the presence of inversion symmetry. However, the structuring of such materials makes it possible to break the inversion symmetry, thus achieving generation of second-harmonic. Moreover, various symmetry properties of the resulting structure, such as chirality, also influence the SHG.

Extremely high extinction ratio electro-optic modulator via frequency upconversion to visible wavelengths.

Intensity modulators are fundamental components for integrated photonics. From near-infrared (NIR) to visible spectral ranges, they find applications in optical communication and quantum technologies. In particular, they are required for the control and manipulation of atomic systems such as atomic clocks and quantum computers.

Phase-Controlled Synthesis and Phase-Change Properties of Colloidal Cu-Ge-Te Nanoparticles.

Phase-change memory (PCM) technology has recently attracted a vivid interest for neuromorphic applications, in-memory computing, and photonic integration due to the tunable refractive index and electrical conductivity between the amorphous and crystalline material states. Despite this, it is increasingly challenging to scale down the device dimensions of conventionally sputtered PCM memory arrays, restricting the implementation of PCM technology in mass applications such as consumer electronics. Here, we report the synthesis and structural study of sub-10 nm Cu-Ge-Te (CGT) nanoparticles as suitable candidates for low-cost and ultrasmall PCM devices.

Large-scale photonic computing with nonlinear disordered media.

Neural networks find widespread use in scientific and technological applications, yet their implementations in conventional computers have encountered bottlenecks due to ever-expanding computational needs. Photonic computing is a promising neuromorphic platform with potential advantages of massive parallelism, ultralow latency and reduced energy consumption but mostly for computing linear operations. Here we demonstrate a large-scale, high-performance nonlinear photonic neural system based on a disordered polycrystalline slab composed of lithium niobate nanocrystals.

Nanoimprinting Solution-Derived Barium Titanate for Electro-Optic Metasurfaces.

Electro-optic metasurfaces have demonstrated significant potential in enhancing the modulation speed and efficiency for fast and large-scale free-space optical devices. Barium titanate has a strong electro-optic Pockels coefficient, but its availability in thin-film form is restricted due to costly growth processes or low thickness. Here, we fabricated active metasurfaces using an etch-free bottom-up process with sol-gel-based polycrystalline barium titanate with a large electro-optic coefficient similar to bulk lithium niobate.

Monolithic thin-film lithium niobate broadband spectrometer with one nanometre resolution.

Miniaturised optical spectrometers are attractive due to their small footprint, low weight, robustness and stability even in harsh environments such as space or industrial facilities. We report on a stationary-wave integrated Fourier-transform spectrometer featuring a measured optical bandwidth of 325 nm and a theoretical spectral resolution of 1.2 nm.

Polarization Dynamics of Solid-State Quantum Emitters.

Quantum emitters in solid-state crystals have recently attracted a great deal of attention due to their simple applicability in optical quantum technologies. The polarization of single photons generated by quantum emitters is one of the key parameters that plays a crucial role in various applications, such as quantum computation, which uses the indistinguishability of photons. However, the degree of single-photon polarization is typically quantified using the time-averaged photoluminescence intensity of single emitters, which provides limited information about the dipole properties in solids.

Graph model for multiple scattering in lithium niobate on insulator integrated photonic networks.

We present a graph-based model for multiple scattering of light in integrated lithium niobate on insulator (LNOI) networks, which describes an open network of single-mode integrated waveguides with tunable scattering at the network nodes. We first validate the model at small scale with experimental LNOI resonator devices and show consistent agreement between simulated and measured spectral data. Then, the model is used to demonstrate a novel platform for on-chip multiple scattering in large-scale optical networks up to few hundred nodes, with tunable scattering behaviour and tailored disorder.

Sol-Gel Barium Titanate Nanohole Array as a Nonlinear Metasurface and a Photonic Crystal.

The quest of a nonlinear optical material that can be easily nanostructured over a large surface area is still ongoing. Here, we demonstrate a nanoimprinted nonlinear barium titanate 2D nanohole array that shows the optical properties of a 2D photonic crystal and a metasurface, depending on the direction of the optical axis. The challenge of nanostructuring the inert metal-oxide is resolved by direct soft nanoimprint lithography with sol-gel derived barium titanate enabling critical dimensions of 120 nm with aspect ratios of five.

Background-Free Near-Infrared Biphoton Emission from Single GaAs Nanowires.

The generation of photon pairs from nanoscale structures with high rates is still a challenge for the integration of quantum devices, as it suffers from parasitic signals from the substrate. In this work, we report type-0 spontaneous parametric down-conversion at 1550 nm from individual bottom-up grown zinc-blende GaAs nanowires with lengths of up to 5 μm and diameters of up to 450 nm. The nanowires were deposited on a transparent ITO substrate, and we measured a background-free coincidence rate of 0.

Colloidal Ternary Telluride Quantum Dots for Tunable Phase Change Optics in the Visible and Near-Infrared.

A structural change between amorphous and crystalline phase provides a basis for reliable and modular photonic and electronic devices, such as nonvolatile memory, beam steerers, solid-state reflective displays, or mid-IR antennas. In this paper, we leverage the benefits of liquid-based synthesis to access phase-change memory tellurides in the form of colloidally stable quantum dots. We report a library of ternary MGeTe colloids (where M is Sn, Bi, Pb, In, Co, Ag) and then showcase the phase, composition, and size tunability for Sn-Ge-Te quantum dots.

Redeposition-free inductively-coupled plasma etching of lithium niobate for integrated photonics.

Lithium niobate on insulator is being established as a versatile platform for a new generation of photonic integrated devices. Extensive progress has been made in recent years to improve the fabrication of integrated optical circuits from a research platform towards wafer-scale fabrication in commercial foundries, and optical losses have reached remarkably low values approaching material limits. In this context, argon etching of lithium niobate waveguides has been shown to provide the best optical quality, yet the process is still challenging to optimise due to its physical nature.

High-bandwidth thermo-optic phase shifters for lithium niobate-on-insulator photonic integrated circuits.

Phase shifters are key components of large-scale photonic integrated circuits. For the lithium niobate-on-insulator (LNOI) platform, thermo-optic phase shifters (TOPS) have emerged as a more stable and compact alternative to common electro-optic phase shifters (EOPSs), which are prone to anomalous behavior and drifting at low frequencies. Here, we model and experimentally characterize the influence of geometry on the performance of metal strip TOPSs.

Photonic Assemblies of Randomly Oriented Nanocrystals for Engineered Nonlinear and Electro-Optic Effects.

Nonlinear crystals that have a noncentrosymmetric crystalline structure, such as lithium niobate (LiNbO) and barium titanate (BaTiO) exhibit nonzero second-order tensor susceptibilities (χ) and linear electro-optic coefficients ( ). The constraints associated with top-down nanofabrication methods have led to bottom up approaches to harness the strong nonlinearities and electro-optical properties. Here, we present an overview of photonic assemblies made of randomly oriented noncentrosymmetric nanocrystals via bottom-up fabrication methods.

Multiple Scattering and Random Quasi-Phase-Matching in Disordered Assemblies of LiNbO Nanocubes.

Nonlinear disordered photonic media (NDPM), composed of a random configuration of noncentrosymmetric crystals, offer a versatile platform to tailor nonlinear optical effects. The second-harmonic generation (SHG) and its random quasi-phase-matching (RQPM) in the multiple scattering regime are still poorly explored. In this work, we bottom-up assemble NDPM in two different geometries by using LiNbO nanocubes as building blocks and investigate both the multiple scattering and the nonlinear properties.

Second-harmonic generation tuning by stretching arrays of GaAs nanowires.

We present a wearable device with III-V nanowires in a flexible polymer, which is used for active mechanical tuning of the second-harmonic generation intensity. An array of vertical GaAs nanowires was grown with metalorganic vapour-phase epitaxy, then embedded in polydimethylsiloxane and detached from the rigid substrate with mechanical peel off. Experimental results show a tunability of the second-harmonic generation intensity by a factor of two for 30% stretching which matches the simulations including the distribution of sizes.

Electro-mechanical to optical conversion by plasmonic-ferroelectric nanostructures.

Barium titanate (BaTiO) is a lead-free ferroelectric crystal used in electro-mechanical transducers and electro-optic films. Nanomechanical devices based on thin films of BaTiO are still unavailable, as the internal stress of thin ferroelectric films results in brittle fracture. Here, we use the electro-mechanical force to fabricate deformable assemblies (nanobeams) of BaTiO nanocrystals, on top of plasmonic metasurfaces.

Mapping of Fabry-Perot and whispering gallery modes in GaN microwires by nonlinear imaging.

Engineering nonlinear optical responses at the microscale is a key topic in photonics for achieving efficient frequency conversion and light manipulation. Gallium nitride (GaN) is a promising semiconductor material for integrated nonlinear photonic structures. In this work, we use epitaxially grown GaN microwires as nonlinear optical whispering gallery and Fabry-Perot resonators.

Gallium Phosphide Nanowires in a Free-Standing, Flexible, and Semitransparent Membrane for Large-Scale Infrared-to-Visible Light Conversion.

Engineering of nonlinear optical response in nanostructures is one of the key topics in nanophotonics, as it allows for broad frequency conversion at the nanoscale. Nevertheless, the application of the developed designs is limited by either high cost of their manufacturing or low conversion efficiencies. This paper reports on the efficient second-harmonic generation in a free-standing GaP nanowire array encapsulated in a polymer membrane.

How to organize an online conference.

The first online-only meeting in photonics, held on 13 January 2020, was a resounding success, with 1100 researchers participating remotely to discuss the latest advances in photonics. Here, the organizers share their tips and advice on how to organize an online conference.

Forward and Backward Switching of Nonlinear Unidirectional Emission from GaAs Nanoantennas.

High-index III-V semiconductor nanoantennas have gained great attention for enhanced nonlinear light-matter interactions, in the past few years. However, the complexity of nonlinear emission profiles imposes severe constraints on practical applications, such as in optical communications and integrated optoelectronic devices. These complexities include the lack of unidirectional nonlinear emission and the severe challenges in switching between forward and backward emissions, due to the structure of the susceptibility tensor of the III-V nanoantennas.

Image-based autofocusing system for nonlinear optical microscopy with broad spectral tuning.

We present an image-based autofocusing system applied in nonlinear microscopy and spectroscopy with a wide range of excitation wavelengths. The core of the developed autofocusing system consists of an adapted two-step procedure maximizing an image score with six different image scorings algorithms implemented to cover different types of focusing scenarios in automated regime for broad wavelength region. The developed approach is combined with an automated multi-axis alignment procedure.

Crystalline heterogeneity in single ferroelectric nanocrystals revealed by polarized nonlinear microscopy.

Ferroelectric nanocrystals have considerable interest for applications in nanophotonics, optical memories and bio-imaging. Their crystalline nature at the nanoscale remains however poorly known, mostly because structural investigation tools on single nanocrystals are lacking. In this work we apply polarization resolved second harmonic generation (P-SHG) imaging on isolated Barium Titanate (BaTiO) nanocrystals to unravel their crystalline nature, exploiting the sensitivity of polarized SHG to local non-centrosymmetry and nanocrystals surface responses.

Reshaping the Second-Order Polar Response of Hybrid Metal-Dielectric Nanodimers.

We combine the field confinement of plasmonics with the flexibility of multiple Mie resonances by bottom-up assembly of hybrid metal-dielectric nanodimers. We investigate the electromagnetic coupling between nanoparticles in heterodimers consisting of gold and barium titanate (BaTiO or BTO) nanoparticles through nonlinear second-harmonic spectroscopy and polarimetry. The overlap of the localized surface plasmon resonant dipole mode of the gold nanoparticle with the dipole and higher-order Mie resonant modes in the BTO nanoparticle lead to the formation of hybridized modes in the visible spectral range.

Tunable 2D binary colloidal alloys for soft nanotemplating.

The realization of non-close-packed nanoscale patterns with multiple feature sizes and length scales via colloidal self-assembly is a highly challenging task. We demonstrate here the creation of a variety of tunable particle arrays by harnessing the sequential self-assembly and deposition of two differently sized microgel particles at the fluid-fluid interface. The two-step process is essential to achieve a library of 2D binary colloidal alloys, which are kinetically inaccessible by direct co-assembly.