The title compound, [Ag(CHNS)]ClO·2CHOH, is monoclinic. The Ag atom is coordinated by pyrido N atoms and is two-coordinate; however, the Ag atom has nearby O atoms that can be assumed to be weakly bonded - one from the perchlorate anion and one from the methanol solvate molecule. One of the thienyl groups on a 2,3-bis-(thio-phen-2-yl)pyrido[3,4-]pyrazine is flipped disordered and was refined to occupancies of 68.
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