Insights into the adsorption and corrosion inhibition properties of newly synthesized diazinyl derivatives for mild steel in hydrochloric acid: synthesis, electrochemical, SRB biological resistivity and quantum chemical calculations.

Two azo derivatives, 4-((4-hydroxy-3-((4-oxo-2-thioxothiazolidin-5-ylidene)methyl)phenyl) diazinyl) benzenesulfonic acid (TODB) and 4-((3-((4,4-dimethyl-2,6-dioxocyclohexylidene) methyl)-4-hydroxyphenyl)diazinyl) benzenesulfonic acid (DODB) were synthesized and characterized using Fourier-transform infrared spectroscopy (FTIR), proton nuclear magnetic resonance (H-NMR) and mass spectral studies. Gravimetric methods, potentiodynamic polarization (PDP), electrochemical impedance spectroscopy (EIS), electrochemical frequency modulation (EFM) techniques and inductive coupled plasma-optical emission spectroscopy were used to verify the above two compounds' ability to operate as mild steel (MS) corrosion inhibitors in 1 M HCl. Tafel data suggest that TODB and DODB have mixed-type characteristics, and EIS findings demonstrate that increasing their concentration not only alters the charge transfer ( ) of mild steel from 6.

Corrosion mitigation for steel in acid environment using novel -phenylenediamine and benzidine coumarin derivatives: synthesis, electrochemical, computational and SRB biological resistivity.

Three novel -phenylenediamine and benzidine coumarin derivatives were synthetized, namely: 4,4'-((((1,4-phenylenebis(azaneylylidene))bis(ethan-1-yl-1-ylidene))bis(2-oxo-2-chromene-3,6-diyl))bis(diazene-2,1-diyl))dibenzenesulfonic acid (PhODB), 4,4'-(((-([1,1'-biphenyl]-4,4'-diylbis(azaneylylidene))bis(ethan-1-yl-1-ylidene))bis(2-oxo-2-chromene-3,6-diyl))bis(diazene-2,1-diyl))dibenzenesulfonic acid (BODB) and 4,4'-(((-((3,3'-dimethoxy-[1,1'-biphenyl]-4,4'-diyl)bis(azaneylylidene))bis(ethan-1-yl-1-ylidene))bis(2-oxo-2-chromene-3,6-iyl))bis(diazene-2,1-diyl))dibenzenesulfonic acid (DODB). Their chemical structures were proved by performing Fourier-transform infrared spectroscopy, proton nuclear magnetic resonance and mass spectrometry analysis. The synthesized -phenylenediamine and benzidine coumarin derivatives were tested as corrosion inhibitors for mild steel (MS) in 1 M HCl solution using weight loss, electrochemical, morphological, and theoretical studies.