J Phys Chem C Nanomater Interfaces
August 2023
The rapid growth of the livestock sector in some areas of Europe has caused an imbalance between the generation of livestock manure and the availability of agricultural soil for its direct application as a fertilizer. Since the transport of pig slurry to other areas with nutrient-deficient soils is costly from an economic point of view due to its high water content, the application of new technologies for the concentration of this waste is considered key for reducing management costs. Consequently, the main objective of this study was to demonstrate the potential of vibratory shear enhanced processing (VSEP) operated with reverse osmosis membranes to recover nutrients from the liquid fractions of pig slurry (LF-pig slurry) and digestate (LF-digestate) and obtain concentrated fertilizing products.
View Article and Find Full Text PDFThis joint experimental and theoretical study of the structural and vibrational properties of β-InS upon compression shows that this tetragonal defect spinel undergoes two reversible pressure-induced order-disorder transitions up to 20 GPa. We propose that the first high-pressure phase above 5.0 GPa has the cubic defect spinel structure of α-InS and the second high-pressure phase (ϕ-InS) above 10.
View Article and Find Full Text PDFWe report a joint experimental and theoretical study of the low-pressure phase of α'-GaS under compression. Theoretical ab initio calculations have been compared to X-ray diffraction and Raman scattering measurements under high pressure carried out up to 17.5 and 16.
View Article and Find Full Text PDFHigh pressure X-ray diffraction, Raman scattering, and electrical measurements, together with theoretical calculations, which include the analysis of the topological electron density and electronic localization function, evidence the presence of an isostructural phase transition around 2 GPa, a Fermi resonance around 3.5 GPa, and a pressure-induced decomposition of SnSbTe into the high-pressure phases of its parent binary compounds (α-SbTe and SnTe) above 7 GPa. The internal polyhedral compressibility, the behavior of the Raman-active modes, the electrical behavior, and the nature of its different bonds under compression have been discussed and compared with their parent binary compounds and with related ternary materials.
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