In this study, a high- aerospace-grade epoxy composite plate was co-curing welded using a unidirectional PEEK thermoplastic carbon fibre tape to develop advanced composite joints. To account for the surface roughness and the weldability of carbon-epoxy/carbon-PEEK composites, plasma treatments were performed. The co-curing was conducted by the following steps: each treated thermoplastic tape was first placed in the mould, and followed by nine layers of dry-woven carbon fabrics.
View Article and Find Full Text PDFThe melt strength of Elium acrylic resin is an important factor to ensure limited fluid flow during welding. To provide Elium with a suitable melt strength via a slight crosslink, this study examines the effect of two dimethacrylates, namely butanediol-di-methacrylate (BDDMA) and tricyclo-decane-dimethanol-di-methacrylate (TCDDMDA), on the weldability of acrylic-based glass fibre composites. The resin system impregnating a five-layer woven glass preform is a mixture of Elium acrylic resin, an initiator, and each of the multifunctional methacrylate monomers in the range of 0 to 2 parts per hundred resin (phr).
View Article and Find Full Text PDFJoining of dissimilar thermoplastics and their composites is a challenge for thermal welding techniques due to different melting points. Reactive welding with an auxiliary functional material can offer the clear opportunities to develop joining processes due to robustness to joining dissimilar thermoplastic polymers and their composites. The current study employed reactive compatibilization to offer the possibility of joining an acrylic-based glass fiber composite to polyamide (PA)-12 by applying a hot-tool welding technique.
View Article and Find Full Text PDFThe growing concern for climate change and global warming has given rise to investigations in various research fields, including one particular area dedicated to the creation of solid sorbents for efficient CO capture. In this work, a new family of poly(ionic liquid)s (PILs) comprising cationic polyureas (PURs) with tetrafluoroborate (BF) anions has been synthesized. Condensation of various diisocyanates with novel ionic diamines and subsequent ion metathesis reaction resulted in high molar mass ionic PURs (M = 12 ÷ 173 × 10 g/mol) with high thermal stability (up to 260 °C), glass transition temperatures in the range of 153-286 °C and remarkable CO capture (10.
View Article and Find Full Text PDFPoly(methyl methacrylate) (PMMA) based nanocomposites were synthesized by melt intercalation technique using organoclays (Cloisite 30B and Cloisite 20A) as fillers. X-ray diffraction (XRD) and transmission electron microscopy (TEM) were used to determine the dispersion and the morphology of the nanocomposites obtained. Thermomechanical tests including tensile test and dynamic mechanical analysis (DMA) were used to evaluate the Young's modulus, storage modulus and the glass transition temperature.
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