The compounds Sm₂TGe₆ (T = Pd, Pt,) were synthesized and characterized by x-ray diffraction, magnetization, electrical resistivity, thermoelectric power, and specific heat measurements performed in the temperature range 2-300 K. Additional resistivity and thermoelectric power measurements performed down to 0.35 K have not indicated superconductivity.
View Article and Find Full Text PDFJ Phys Condens Matter
January 2010
The crystal and electronic structures of the orthorhombic compound UCoGe are presented and discussed. It has been either refined by the x-ray diffraction on a single crystal or computed within the local spin density functional theory, employing the fully relativistic version of the full-potential local-orbital band structure code, respectively. We particularly give our attention to investigating the Fermi surface and de Haas-van Alphen quantities of UCoGe.
View Article and Find Full Text PDFJ Phys Condens Matter
March 2009
A novel ternary compound U(3)Ru(4)Al(12) has been identified in the U-Ru-Al ternary diagram. Single-crystal x-ray diffraction indicates a hexagonal Gd(3)Ru(4)Al(12)-type structure for this uranium-based intermetallic. While this structure type usually induces geometrically a spin-glass behaviour, an antiferromagnetic ordering is observed at T(N) = 8.
View Article and Find Full Text PDFThe structure of UCoAl(4) can be viewed as a succession of atomic layers, with the compositions UCoAl and Al(3), that alternate along the c axis. The packing within the pure Al layer at z = 1/2 results from edge-sharing of triangles, squares and pentagons of Al atoms. Two successive Al(3) layers thus define pentagonal, square-based and trigonal prisms which are centred at z = 0 by the U, Co and remaining Al atoms.
View Article and Find Full Text PDFThe ternary compound UNiAl exhibiting an antiferromagnetic order below T(N) = 19.3 K has been studied in the paramagnetic state using the 27Al NMR technique and different magnetically oriented samples. The quadrupole coupling constant e2qQ/h = 1.
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