Nanoscale Imaging of Electrically Driven Charge-Density Wave Phase Transitions.

Structural transformations in strongly correlated materials promise efficient and fast control of materials' properties via electrical or optical stimulation. The desired functionality of devices operating based on phase transitions, however, will also be influenced by nanoscale heterogeneity. Experimentally characterizing the relationship between microstructure and phase switching remains challenging, as nanometer resolution and high sensitivity to subtle structural modifications are required.

Overcoming Intrinsic Quantum Confinement and Ultrafast Self-Trapping in Ag-Bi-I- and Cu-Bi-I-Based 2D Double Perovskites through Electroactive Cations.

The possibility to combine organic semiconducting materials with inorganic halide perovskites opens exciting pathways toward tuning optoelectronic properties. Exploring stable and nontoxic, double perovskites as a host for electroactive organic cations to form two-dimensional (2D) hybrid materials is an emerging opportunity to create both functional and lead-free materials for optoelectronic applications. By introducing naphthalene and pyrene moieties into Ag-Bi-I and Cu-Bi-I double perovskite lattices, intrinsic electronic challenges of double perovskites are addressed and the electronic anisotropy of 2D perovskites can be modulated.

Interaction-Driven Quasi-Insulating Ground States of Gapped Electron-Doped Bilayer Graphene.

Bernal bilayer graphene has recently been discovered to exhibit a wide range of unique ordered phases resulting from interaction-driven effects and encompassing spin and valley magnetism, correlated insulators, correlated metals, and superconductivity. This Letter reports on a novel family of correlated phases characterized by spin and valley ordering, distinct from those reported previously. These phases emerge in electron-doped bilayer graphene where the energy bands are exceptionally flat, manifested through an intriguing nonlinear current-bias behavior that occurs at the onset of the phases and is accompanied by an insulating temperature dependence.

Probing the tunable multi-cone band structure in Bernal bilayer graphene.

Bernal bilayer graphene (BLG) offers a highly flexible platform for tuning the band structure, featuring two distinct regimes. One is a tunable band gap induced by large displacement fields. Another is a gapless metallic band occurring at low fields, featuring rich fine structure consisting of four linearly dispersing Dirac cones and van Hove singularities.

A CuBHT-Graphene van der Waals Heterostructure with Strong Interlayer Coupling for Highly Efficient Photoinduced Charge Separation.

Two-dimensional van der Waals heterostructures (2D vdWhs) are of significant interest due to their intriguing physical properties critically defined by the constituent monolayers and their interlayer coupling. Synthetic access to 2D vdWhs based on chemically tunable monolayer organic 2D materials remains challenging. Herein, the fabrication of a novel organic-inorganic bilayer vdWh by combining π-conjugated 2D coordination polymer (2DCP, i.