Publications by authors named "R R Sheha"

A facile modification of a strontium-based MOF using oxalic acid was carried out to prepare MTSr-OX MOF, which was used as a potential substance for eliminating Eu radioisotopes. Various analytical techniques were used to characterize MTSr-OX-MOF. The prepared MOF had a rod-like structure with a BET surface area of 101.

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The nuclear industry is rapidly developing and the effective management of nuclear waste and monitoring the nuclear fuel cycle are crucial. The presence of various radionuclides such as uranium (U), europium (Eu), technetium (Tc), iodine (I), thorium (Th), cesium (Cs), and strontium (Sr) in the environment is a major concern, and the development of materials with high adsorption capacity and selectivity is essential for their effective removal. Metal-organic frameworks (MOFs) have recently emerged as promising materials for removing radioactive elements from water resources due to their unique properties such as tunable pore size, high surface area, and chemical structure.

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Radioactive europium can be released as a fission product during nuclear incidents and pose a threat to the human and surrounding environment because of its biological activity and long decay half-lives. For safe design issues and human health protection demands in construction of the planned nuclear power plants (NPPs) at Al-Dabaa site, it is necessary to study the sorption and transport of different radionuclides as europium within the selected area for predicting their fate at any crisis. Many soil samples were collected from different locations at the area selected along the northwestern coast of Egypt.

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Removal of hazardous radioactive materials such as Eu from active waste using the batch approach has attracted attention nowadays. In this work, a novel melamine-terephthalic strontium metal-organic framework (MTSr-MOF) was prepared a hydrothermal method. The MTSr-MOF was characterized by various analytical techniques such as FT-IR, H/C-NMR, mass spectroscopy, XPS, XRD, TGA, BET, FE-SEM/EDX, TEM, and UV.

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A magnetic hydroxyapatite composite (CaHAP/NF) derived from calcium hydroxyapatite [Ca(PO)(OH)] and nickel ferrite [NiFeO] was successfully synthesized by a coprecipitation method. The synthesized composite was characterized using Fourier transform infrared spectroscopy (FT-IR), X-Ray diffractometer (XRD), thermogravimetric differential thermal analysis (TG-DTA), scanning electron microscopy (SEM) and vibrating sample magnetometer (VSM). Results clarify that the composite is a crystalline in nature, thermally stable up to 800 °C and possesses a high porous structure.

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