Publications by authors named "R R C Clement"

Sensors play an important role in both the continuous monitoring and intermittent analyses, which are essential for the study of wastewater treatment plant management and conducting related research. Given the significant environmental impact of the issues involved, accurate measurement of the volume of water flowing into and out of treatment plants is a key parameter for plant management, ecotoxicological studies and academic research programs. Traditionally, flow measurements have been based on calibrated weirs or venturi flumes, using water level measurements for conversion into flow, according to established relationships.

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Of the few weberite-type Na-ion cathodes explored to date, NaFeF exhibits the best performance, with capacities up to 184 mAh/g and energy densities up to 550 Wh/kg reported for this material. However, the development of robust structure-property relationships for this material is complicated by its tendency to form as a mixture of metastable polymorphs, and transform to a lower-energy Na FeF perovskite compound during electrochemical cycling. Our first-principles-guided exploration of Fe-based weberite solid solutions with redox-inactive Mg and Al predicts an enhanced thermodynamic stability of NaMg Fe F as the Mg content is increased, and the = 0.

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Solid polymer electrolytes (SPEs) with mechanical strength and reduced flammability may also enable next-generation Li batteries with higher energy densities. However, conventional SPEs have fundamental limitations in terms of Li conductivity. While an imidazole functionalized polymer (PMS-Im) has been previously shown to have ionic conductivity related to the imidazole-Li coordination, herein we demonstrate that quaternization of this polymer to form an analogous imidazolium functionalized polymer (PMS-Im) more efficiently solvates lithium salts and plasticizes the polymer.

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Article Synopsis
  • Sulfide solid-state electrolytes (SSEs) show great potential for all solid-state batteries due to their high ionic conductivity and flexibility, but they are sensitive to moisture, making current manufacturing methods incompatible.
  • A new reversible surface modification technique using 1-undecanethiol enhances the moisture resistance of sulfide SSEs, allowing them to maintain conductivity above 1 mS cm even after 2 days of exposure to 33% relative humidity, which is significantly better than existing methods.
  • This modification involves a thiol group that adheres to the SSE surface and a hydrophobic tail that repels water, paving the way for more efficient and cost-effective sulfide SSE manufacturing in battery applications.
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