Mechanical Mapping of the Common Carotid Artery in Healthy Individuals Aged 2 to 40 Years.

: In 2022, the World Stroke Organization said there were more than 12.2 million new cases of stroke each year, between all ages and sexes. Six and a half million people die each year from stroke.

Is the protactinium(V) mono-oxo bond weaker than what we thought?

The bond distance is the simplest and most obvious indicator of the nature of a given chemical bond. However, for rare chemistry, it may happen that it is not yet firmly established. In this communication, we will show that the formally-triple protactinium(V) mono-oxo bond is predicted to be longer than what was previously reported in the solid state and in solution, based on robust quantum mechanical calculations, supported by an extensive methodological study.

Post-COVID-19: Time to Change Our Way of Life for a Better Future.

From the year 1 anno Domini until 1855, with the third plague, major pandemics occurred on average every 348 years. Since then, they have occurred on average every 33 years, with coronavirus disease 2019 (COVID-19) now underway. Even though current technologies have greatly improved the way of life of human beings, COVID-19, with more than 700,000,000 cases and 6,950,000 deaths worldwide by the end of 2023, reminds us that much remains to be done.

The resolution of the weak-exchange limit made rigorous, simple and general in binuclear complexes.

The correct interpretation of magnetic properties in the weak-exchange regime has remained a challenging task for several decades. In this regime, the effective exchange interaction between local spins is quite weak, of the same order of magnitude or smaller than the various anisotropic terms, which generates a complex set of levels characterized by spin mixing. Although the model multispin Hamiltonian in the absence of local orbital momentum, , is considered good enough to map the experimental energies at zero field and in the strong-exchange limit, theoretical works pointed out limitations of this simple model.

Stability of the Protactinium(V) Mono-Oxo Cation Probed by First-Principle Calculations.

This study explores the distinctive behavior of protactinium (Z=91) within the actinide series. In contrast to neighboring elements like uranium or plutonium, protactinium in the pentavalent state diverges by not forming the typical dioxo protactinyl moiety PaO in aqueous phase. Instead, it manifests as a monooxo PaO cation or a Pa .