The performance of two inorganic ion exchange resins, Isolute SCX and Isolute SCX-2, were compared to the performance of the organic resin AG-50X8 in the separation of the radionuclide bismuth-213 from its parent solution of actinium-225. The breakthrough of the actinium-225 for all three columns was well below the toxicity level but the Isolute SCX and Isolute SCX-2 produced less of the bismuth-213 available on the column.
View Article and Find Full Text PDFWe performed a series of experiments designed to elucidate the effects of the presence of sodium dodecyl sulfate (SDS) surfactant and an applied electrical field on the wetting behavior in a system containing a sessile droplet of phenylmethyl polysiloxane (PMPS) oil on a polished stainless steel surface submersed in aqueous solution. The voltage difference ranged from -3 to +3 V, which is at least 3 orders of magnitude smaller than from comparable recent work. We report the measured equilibrium contact angle of the droplet as a function of surfactant concentration and field strength.
View Article and Find Full Text PDFThe present study investigates the change in the shape of oil droplets immersed in an ionic surfactant solution when the droplets are in contact with metal surfaces to which an electrical potential is applied. The three-phase system of aqueous solution-oil-steel was subjected to low-voltage electric potentials, which resulted in sometimes dramatic changes in droplet shape and wetting. This electric potential was applied to the conductive steel surface directly, and the counter electrode was immersed in the solution.
View Article and Find Full Text PDFJ Colloid Interface Sci
February 2004
A model applying surfactant self-assembly theory and classical thermodynamics has been developed to aid in the prediction of solid surface cleaning by aqueous surfactant solutions. Information gained from a combination of surfactant self-assembly behavior and cleaning system parameters, such as oil species, surfactant type, temperature, alkalinity, and solid surface type has been shown to provide insight into surface cleaning. The model combines minimization of free energy, pertinent component distribution mechanisms, and surfactant self-assembly processes to provide a methodology for the predicting of oil droplet contact angles.
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