Laser cleaning and Raman analysis of the contamination on the optical window of a rubidium vapor cell.

In this work, we present the laser cleaning of a Rubidium vapor cell and the Raman analysis of the contaminant material to be removed. The optical window of the vapor cell had gradually lost transparency due to the development of an opaque layer of unknown composition at the inner side during the normal operation of the cell. Laser cleaning was successfully performed by a frequency-doubled Nd:YAG laser focusing the beam inside the cell, avoiding any possible damage to the window.

Ex vivo confocal Raman microspectroscopy of porcine dura mater supported by optical clearing.

The effect of tissue optical clearing (TOC) to increase the probing depth and observe in-depth structure of the ex vivo porcine dura mater was studied by confocal Raman microspectroscopy (CRM). Raman intensities were significantly increased at the depth of 250 μm for all collagen bands after treatment with glycerol. The influence of glycerol on collagen hydration was also investigated.

Super-bandgap light stimulated reversible transformation and laser-driven mass transport at the surface of AsS chalcogenide nanolayers studied .

The super-bandgap laser irradiation of the prepared As-S chalcogenide films was found to cause drastic structural transformations and unexpected selective diffusion processes, leading to As enrichment on the nanolayer surface. Excitation energy dependent synchrotron radiation photoelectron spectroscopy showed complete reversibility of the molecular transformations and selective laser-driven mass transport during "laser irradiation"-"thermal annealing" cycles. Molecular modeling and density functional theory calculations performed on As-rich cage-like clusters built from basic structural units indicate that the underlying microscopic mechanism of laser induced transformations is connected with the realgar-pararealgar transition in the As-S structure.

Hysteresis of Low-Temperature Thermal Conductivity and Boson Peak in Glassy (g) AsS: Nanocluster Contribution.

Experimental results of the thermal conductivity (k(T)) of nanostructured g-AsS during cooling and heating processes within the temperature range from 2.5 to 100 K have been analysed. The paper has considered thermal conductivity is weakly temperature k(T) dependent from 2.

Coherent Light Photo-modification, Mass Transport Effect, and Surface Relief Formation in AsS Nanolayers: Absorption Edge, XPS, and Raman Spectroscopy Combined with Profilometry Study.

As S (x = 40, 45, 50) thin films top surface nanolayers affected by green (532 nm) diode laser illumination have been studied by high-resolution X-ray photoelectron spectroscopy, Raman spectroscopy, optical spectroscopy, and surface profilometry. It is shown that the composition of obtained films depends not only on the composition of the source material but as well on the composition of the vapor during the evaporation process. Near-bandgap laser light decreases both As-As and S-S homopolar bonds in films, obtained from thermal evaporation of the AsS and AsS glasses.