Interfacial electron transfer (IET) through saturated single-linker and dual-linker groups from a perylene chromophore into nanostructured TiO2 films was studied by ultrafast spectroscopy. Perylene chromophores with one and two propanoic acid linker groups in the peri and ortho positions were investigated. In comparison to previously studied perylenes bound via unsaturated acrylic acid linkers, the chromophores with saturated linkers showed bi-exponential IET dynamics.
View Article and Find Full Text PDFBackground: In England, demand for primary care services is increasing and GP shortages are widespread. Recently introduced primary care networks (PCNs) aim to expand the use of additional practice-based roles such as physician associates (PAs), pharmacists, paramedics, and others through financial incentives for recruitment of these roles. Inequalities in general practice, including additional roles, have not been examined in recent years, which is a meaningful gap in the literature.
View Article and Find Full Text PDFThe threat posed by invasive non-native species worldwide requires a global approach to identify which introduced species are likely to pose an elevated risk of impact to native species and ecosystems. To inform policy, stakeholders and management decisions on global threats to aquatic ecosystems, 195 assessors representing 120 risk assessment areas across all six inhabited continents screened 819 non-native species from 15 groups of aquatic organisms (freshwater, brackish, marine plants and animals) using the Aquatic Species Invasiveness Screening Kit. This multi-lingual decision-support tool for the risk screening of aquatic organisms provides assessors with risk scores for a species under current and future climate change conditions that, following a statistically based calibration, permits the accurate classification of species into high-, medium- and low-risk categories under current and predicted climate conditions.
View Article and Find Full Text PDFAn investigation into the abundance and distribution of meso- and microplastics within the Port of Durban was conducted using a static immersible water pump and particle filtration system to collect meso- and microplastics from the water column, microplastics from sediment samples and corresponding CTD. Microplastics were detected in all samples under investigation. Results suggest that sewage overflow, stormwater drains, port operations, followed by rivers are input areas for mitigation to focus on.
View Article and Find Full Text PDFThe identification of microplastic hotspots is vital to our long-term understanding of their environmental fate and distribution. Although case studies have increased globally, sampling campaigns are often restricted geographically, with poor spatial resolution. Here, we use citizen science to increase our geographical reach, which improved our understanding of microplastic distribution in estuarine and beach sediment along the south-west coast of England.
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