Publications by authors named "R F Brinkhuis"

The non-equilibrium assembly of bimodal colloids during evaporative processes is an attractive means to achieve gradient or stratified layers in thick films. Here, we show that the stratification of small colloids on top of large is prevented when the viscosity of the continuous aqueous phase is too high. We propose a model where a too narrow width of the gradient in concentration of small colloids suppresses the stratification.

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The molecular composition of polymer blend surfaces defines properties such as adhesion, wetting, gloss, and biocompatibility. The surface composition often differs from the bulk because of thermodynamic effects or modification. Mixtures of colloids and linear polymers in a common solvent are often used to deposit films for use in encapsulants, inks, coatings, and adhesives.

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Traditionally, natural medicines have been administered as plant extracts, which are composed of a mixture of molecules. The individual molecular species in this mixture may or may not contribute to the overall medicinal effects and some may even oppose the beneficial activity of others. To better control therapeutic effects, studies that characterized specific molecules and describe their individual activity that have been performed over the past decades.

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Copolymer/water interfacial tensions of statistical copolymers of styrene/ n-butyl acrylate were estimated by pendant drop tensiometry using an "inverse" configuration according to which a drop of water was formed in toluene/copolymer solutions. The study first involved the precise measurement of copolymer solutions density using pycnometry. Subsequently, interfacial tensions of copolymer solutions against water were plotted as a function of copolymer concentration in toluene.

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