Reducing Solvent Consumption in Reductive Catalytic Fractionation through Lignin Oil Recycling.

Reductive catalytic fractionation (RCF) enables the simultaneous valorization of lignin and carbohydrates in lignocellulosic biomass through solvent-based lignin extraction, followed by depolymerization and catalytic stabilization of the extracted lignin. Process modeling has shown that the use of exogenous organic solvent in RCF is a challenge for economic and environmental feasibility, and previous works proposed that lignin oil, a mixture of lignin-derived monomers and oligomers produced by RCF, can be used as a cosolvent in RCF. Here, we further explore the potential of RCF solvent recycling with lignin oil, extending the feasible lignin oil concentration in the solvent to 100 wt %, relative to the previously demonstrated 0-19 wt % range.