The effect of annealing temperature and capping ligands on the electron mobility and electronic structure of indium oxide (InO) nanocrystals (NCs) was investigated using oleic acid (OA), benzoic acid (BA), and 4-aminobenzoic acid (4ABA). The NCs were deposited on SiO/Si wafers for electron mobility measurements using a field effect transistor device, and the annealing temperature () was varied from 150 to 350 °C. At = 200 °C, the electron mobility of the BA-capped InO NC thin film was greater than that of 4ABA-capped InO NCs, while the opposite trend was observed at = 250 °C.
View Article and Find Full Text PDFACS Appl Mater Interfaces
May 2023
A highly sensitive and flexible gas sensor that can detect a wide range of chemicals is crucial for wearable applications. However, conventional single resistance-based flexible sensors face challenges in maintaining chemical sensitivity under mechanical stress and can be affected by interfering gases. This study presents a versatile approach for fabricating a micropyramidal flexible ion gel sensor, which accomplishes sub-ppm sensitivity (<80 ppb) at room temperature and discrimination capability between various analytes, including toluene, isobutylene, ammonia, ethanol, and humidity.
View Article and Find Full Text PDFEnhanced carbon capture and oxygen production via water splitting was observed by controlling the plasmon-induced resonance energy transfer (PIRET) for photosystem II (PSII) in thylakoid extracts and spirulina assembled on gold nanoparticle (AuNP) dimer arrays. The two types of vertical (V) and horizontal (H) AuNP dimer arrays were uniformly inserted inside pore diameter-controlled templates. Based on the theoretical calculations, the longitudinal mode of the H AuNP dimer array was found to be sensitive to the nanogap distances between the two AuNPs in resonance with the absorption at P680 of the PSII.
View Article and Find Full Text PDFIn this study, a systematic multi-spectroscopic analysis of microplastics (MPs) sampled from a metropolitan area of Seoul was undertaken to elevate understanding of the role of wastewater treatment plants (WWTPs) in eliminating suspended contaminants including MPs before releasing the effluent water into the environment. We analyzed pollutants in influent and effluent samples from a WWTP in Seoul, South Korea. Spectroscopic and microscopic methods were used to analyze MPs.
View Article and Find Full Text PDFWe prepared novel Raman substrates for the sensitive detection of submicron-sized plastic spheres in water. Anisotropic nanostar dimer-embedded nanopore substrates were prepared for the efficient identification of submicron-sized plastic spheres by providing internal hot spots of electromagnetic field enhancements at the tips of nanoparticles. Silver-coated gold nanostars (AuNSs@Ag) were inserted into anodized aluminum oxide (AAO) nanopores for enhanced microplastic (MP) detection.
View Article and Find Full Text PDFA novel and cost-efficient technique is presented to generate non-return-to-zero (NRZ) and ultra-wideband (UWB) signals in different time slots of time division multiplexing-passive optical network (TDM-PON) by using a single chirped controlled semiconductor laser associated with an optical bandpass filter. In this technique, the chirp of the laser is controlled by different bias burst amplitudes (BBA) for different time slots. Through the proper selection of the burst amplitudes, 10 Gbps NRZ and 1.
View Article and Find Full Text PDFThis paper proposes the use of chirp-managed lasers (CML) as cost-effective downstream (DS) transmitters for next generation access networks. As the laser bandwidth is as high as 10 GHz, the CML could be directly modulated at 10 Gbit/s for downstream transmission in future wavelength division multiplexing passive optical networks (WDM PON). The laser adiabatic chirp, which is the main drawback limiting the transmission performance of directly modulated lasers, is now utilized to generate phase-shift keying (PSK) modulation format by direct modulation.
View Article and Find Full Text PDFSaturated Collision Amplifier (SCA) is a novel amplification scheme that uses SOA saturation in order to maximize the output power and minimize the ASE noise and the polarization sensitivity. We demonstrate the SCA reach extension in a commercial single-wavelength XGPON1 prototype system where bidirectional optical budget of up to 50 dB is obtained. The traffic performances are compared between the SCA and the conventional SOA extender.
View Article and Find Full Text PDFWe report on the experimental and theoretical study of a self-phase-modulation-based regenerator at 42.6 Gbit/s with a return-to-zero 33% format. We point out some detrimental effects such as intrachannel interactions and Brillouin scattering.
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