Electrochemical water-splitting with non-noble metal catalysts provides an eco-friendly strategy for renewable production of hydrogen. In this study, the MoP@C@reduced graphene oxide (rGO) composite was prepared via mild reactions through a chemical bath and postannealing process. With the assistance of citric acid, the MoP@C@rGO composite containing ultrafine MoP nanoparticles with a size of 3 nm anchored on two-dimensional C/rGO nanosheets has been obtained.
View Article and Find Full Text PDFHigh-performance stretchable and wearable electronic skins (E-skins) with high sensitivity and a large sensing range are urgently required with the rapid development of the Internet of things and artificial intelligence. Herein, a reduced graphene oxide (rGO)/polyaniline wrapped sponge is prepared via rGO coating and the in situ synthesis of polyaniline nanowires (PANI NWs) on the backbones of sponge for the fabrication of pressure sensors. From the as-prepared flexible sensor, tunable sensitivity (0.
View Article and Find Full Text PDFNickel-cobalt binary hydroxide nanotubes were fabricated by a facile synthetic approach by using Cu O nanowires as sacrificial templates. The surface morphology of the binary hydroxide nanotubes can be easily controlled by adjusting the molar ratio of Ni to Co. With increasing Co content, the surfaces of the nanotubes tend to form hierarchical nanoflakes.
View Article and Find Full Text PDFMultifunctional microelectronic components featuring large stretchability, high sensitivity, high signal-to-noise ratio (SNR), and broad sensing range have attracted a huge surge of interest with the fast developing epidermal electronic systems. Here, the epidermal sensors based on all-carbon collaborative percolation network are demonstrated, which consist 3D graphene foam and carbon nanotubes (CNTs) obtained by two-step chemical vapor deposition processes. The nanoscaled CNT networks largely enhance the stretchability and SNR of the 3D microarchitectural graphene foams, endowing the strain sensor with a gauge factor as high as 35, a wide reliable sensing range up to 85%, and excellent cyclic stability (>5000 cycles).
View Article and Find Full Text PDFACS Appl Mater Interfaces
October 2016
Developing highly active electrocatalysts with low cost and high efficiency for oxygen evolution reactions (OER) is important for the practical implementations of hydrogen energy. Here, we report a Zn-doped CoSe nanosheets grown on free-standing carbon fabric collector (CFC), which was synthesized by using a metal-organic framework (MOF) as precursor and followed by a selenylation process. Importantly, the Zn-doped CoSe/CFC electrode exhibited an obviously enhanced catalytic activity for OER in 1 M KOH aqueous solution compared with CoSe/CFC, showing a small overpotential of 356 mV for a current density of 10 mA cm, a small Tafel slope of 88 mV dec, and an excellent stability.
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