Estimation of electron transfer properties of ferrocenyl-dicholesteryl-peptide in liquid and gel.

Molecular dynamics simulations were carried out to investigate the conformations of ferrocenyl-dicholesteryl N-formamidoformamide (Fc-LS2) molecules in solvents of methanol and 1-propanol. Fc-LS2 comprises ferrocene and cholesteryl units linked by a biocompatible N-formamidoformamide peptide unit. Our results showed that Fc-LS2 formed a gel with 1-propanol but not with methanol.