Concerns over food safety arising from conventional plastic and resin-based corrosion barriers cannot be underestimated, particularly in light of the potential for plasticizer migration. We introduce an environmental-friendly and sustainable approach to develop superhydrophobic and anticorrosion coatings. This involved a unique process where glutenin, post-reduction with tris(2-carboxyethyl)phosphine, underwent a phase transition, naturally adhering to diverse surfaces to form a foundational primer.
View Article and Find Full Text PDFNicotine dependence is an important cause of excessive exposure to tobacco combustion compounds in most smokers. Nicotine replacement therapy is the main method to treat nicotine dependence, but it still has its shortcomings, such as the inability to mitigate withdrawal effects and limited applicability. It has been hypothesized that a combination of low-dose nicotine and caffeine could achieve the same psychological stimulation effect as a high dose of nicotine without causing nicotine withdrawal effects.
View Article and Find Full Text PDFBackground: Mycotoxin contamination of food has been gaining increasing attention. Hidden mycotoxins that interact with biological macromolecules in food could make the detection of mycotoxins less accurate, potentially leading to the underestimation of the total exposure risk. Interactions of the mycotoxins alternariol (AOH) and alternariol monomethyl ether (AME) with high-molecular glutenin were explored in this study.
View Article and Find Full Text PDFThe surface of food processing equipment is easily affected by biofilm-forming bacteria, leading to cross-contamination and food safety hazards. The critical issue is how to endow the surface of contact materials with antibacterial and antibiofilm abilities. A sustainable, stable, and antibiofilm coating was prepared by phase transition of glutenin.
View Article and Find Full Text PDFIn order to investigate the adsorption behavior and mechanism of microplastics (MPs) on multiple coexisting pesticides in practical systems, as well as their hazardous changes upon binding, diethofencarb and pyrimethanil were selected to be studied with four MPs. The adsorption rate of both pesticides would be faster in the binary-component case, conforming to pseudo-second-order kinetics, with adsorption sites and chemical adsorption dominating. And the more hydrophobic the pesticide, the faster the adsorption rate and the higher the adsorption capacity.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
August 2024
Based on the fact that not all chemical substances possess good Raman signals, this article focuses on the Raman silent region signals of pesticides with cyano group. Under the optimized conditions of methanol-water (1:1, v/v) as the solvent, irradiation at 302 nm light source for 20 min, and the use of 0.5 mol/L KI as the aggregating agent, Surface-enhanced Raman spectroscopy (SERS) method for azoxystrobin detection was developed by the Raman silent region signal of 2230 cm, and verified by detecting the spiked grapes with different concentrations of azoxystrobin.
View Article and Find Full Text PDFContext: Ab initio calculations were employed in this investigation to scrutinize the adsorption characteristics of a linear chain (HF)n on a BN nanocage (BN), wherein the chain lengths varied (n = 1, 2, 3, and 4). The overarching aim was to assess the efficiency of this setup in detecting and adhering to (HF)n under both liquid and gaseous scenarios. This study encompassed an array of aspects, encompassing adsorption energy, optimal configuration determination, work function analysis, and charge exchange assessment.
View Article and Find Full Text PDFMicroplastics (MPs) are now not only emerging as pollutants in the environment, but their current state of contamination in food is also a cause for concern. It is necessary to focus how to control, reduce, and even remove MPs. In this study, a magnetic metal-organic framework (MOF) material, FeO@SiO@MIL-53(Al), was synthesized and applied to simulate the magnetization and removal of four types of MPs.
View Article and Find Full Text PDFMicroplastics (MPs), an emerging pollutant in the environment and food, may adsorb other contaminants such as pesticide due to particles' properties. The adsorption behavior and their hazardous changes of four common types of MPs to thiram was investigated. The adsorption kinetics and isotherm models were fitted well using the pseudo-second-order model and the Langmuir model respectively, indicating forces such as van der Waals forces dominate, and the maximum adsorption capacity at pH values of 6-7 also indicates that electrostatic forces play a smaller role.
View Article and Find Full Text PDFNanoplastics could modulate the fibrillation of amyloid proteins. However, many chemical functional groups are adsorbed to change the interfacial chemistry of nanoplastics in the real world. Herein, this study aimed to investigate the effects of polystyrene (PS), carboxyl modified PS (PS-COOH), and amino modified PS (PS-NH) on the fibrillation of hen egg-white lysozyme (HEWL).
View Article and Find Full Text PDFThrough utilizing density functional theory (DFT), the current work investigates the potential uses of AlP fullerene for detecting CS, HS, SO, and COS. The interaction order for the stability of these gases was SO > HS > COS > CS. The moment of electric dipole and molecules' adsorption energy seems correlated.
View Article and Find Full Text PDFColloids Surf B Biointerfaces
October 2022
At present, nanoplastics have been detected in food and the environment, but they have serious impacts on the human body. As one of the typical representatives of nanoplastics, polystyrene (PS) is generally used as an experimental object. Few studies found that PS could modulate the formation of amyloid fibrils, leading to the occurrence of diseases.
View Article and Find Full Text PDFIn modern society, plastics also play an indispensable role in people's lives due to their various excellent properties. However, when these plastic products are discarded after being used, after being subjected to external influences, they will continue to be worn, damaged and degraded into micro- and nano-scale plastics, which are microplastics and nanoplastics (M/NPs). Although people's attention has been paid to M/NPs at present, the focus is still mainly on the detection and hazard of M/NPs, and how to remove M/NPs is relatively less popular.
View Article and Find Full Text PDFNowadays, the widespread distribution of microplastics (MPs) in various foods has received much attention. In this study, eggs were purchased as samples from local supermarkets to detect and analyze the presence of MPs. The digestion method was optimized for eggs to better isolate MPs, which proved MPs indeed exist in eggs, and the average content was 11.
View Article and Find Full Text PDFSelf-assembly of misfolded proteins into ordered fibrillar aggregates known as amyloid results in various human diseases. However, more and more proteins, whether in human body or in food, have been found to be able to form amyloid fibrils with in-depth researches. As a model protein for amyloid research, lysozyme has always been the focus of research in various fields.
View Article and Find Full Text PDFBacterial residue is one of the main causes of diseases and economic losses. In recent years, microfabrication technology has inspired the introduction of microstructures on the surfaces of relevant materials to provide antibacterial effects. This antibacterial method has become a popular research topic due to its safety, effectiveness, and stability.
View Article and Find Full Text PDFAs current concerns about food safety issues around the world are still relatively serious, more and more food safety issues have become the focus of people's attention. What's more serious is that environmental pollution and changes in human lifestyles have also led to the emergence of contaminants in food, microplastics (MPs) and nanoplastics (NPs) being typical representatives. MPs and NPs (M/NPs) in food are gradually becoming recognized by regulatory authorities and the public.
View Article and Find Full Text PDFA simple dual-colour fluorescent nanoprobe has been designed composed of blue and yellow emission carbon quantum dots (CQDs). This system is inexpensive and easy to operate and was successfully employed for on-site measurements based on a smartphone app. The designed nanoprobe exhibited increased selectivity for Cr(VI), leading to a double stable response of the two CQDs.
View Article and Find Full Text PDFIn this study, the pine nut (Pinus yunnanensis Franch.) protein was hydrolyzed by alkaline protease and trypsin to prepare pine nut protein hydrolysate (PNPH). The chemical, intracellular and in vivo antioxidant capacity of PNPH were evaluated.
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