Publications by authors named "Qingming Jia"

Article Synopsis
  • The study explores the creation of silica/cellulose aerogels using old corrugated containers and fly ash, synthesized in a NaOH/urea solution.
  • The structural composition of the aerogels changes based on the ratio of silicon to cellulose; lower ratios favor fibrils with silica nanoparticles, while higher ratios result in silica particles mixed with cellulose.
  • The resulting composite material effectively captures CO at room temperature, showing a decrease in CO adsorption capacity with increasing silicon content, but improving selectivity for CO over N.
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Objective: To investigate the effect of Golgi phosphoprotein 3 (Golph3) on paclitaxel- induced apoptosis and autophagy in HeLa cells.

Methods: HeLa cells were transfected with a lentiviral vector expressing Golph3 or a small interfering RNA (siRNA) targeting Golph3 for up-regulation or down-regulation of Golph3 which was verified by Western blotting. The autophagic bodies in the cells were observed using transmission electron microscopy.

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A series of magnetically separable rGO/FeO nanocomposites with various amounts of graphene oxide were successfully prepared by a simple ultrasonication assisted precipitation combined with a solvothermal method and their catalytic activity was evaluated for the selective liquid phase oxidation of cyclohexene using hydrogen peroxide as a green oxidant. The prepared materials were characterized using XRD, FTIR, FESEM, TEM, HRTEM, BET/BJH, XPS and VSM analysis. The presence of well crystallized FeO as the active iron species was seen in the crystal studies of the nanocomposites.

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Old corrugated containers with low recyclability were used as raw materials to synthesize a series of aerogels with varying cellulose concentrations in NaOH/urea solution via a freeze-drying process. The resulting aerogels had a rich porous structure with specific surface areas in the range of 132.72-245.

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As the important component of humus, fulvic acids (FA) have a good antidiarrhoeal effect on animals and humans, and have been worldwide used in animal husbandry and even clinical practice for a long time. Due to the extremely complex chemical composition and structure of FA, the material basis and mechanism of its antidiarrhoeal activity have not been fully elucidated. In this study, we used ultrafiltration technique to fractionate this heterogeneous mixture into a series of relatively uniform fractions.

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Article Synopsis
  • * The study introduces a straightforward method for creating iron oxide nanoparticle-loaded magnetic dextran nanogels, which serve as effective MRI probes due to their favorable magnetic properties and high T relaxivity.
  • * The presence of Schiff base linkages in the dextran matrix allows the nanogel to be pH-sensitive and offers reactive sites for further modifications, positioning it as a promising platform for MRI-guided drug delivery that responds to acidic environments.
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Solid sorbents are considered to be promising materials for carbon dioxide capture. In recent years, many studies have focused on the use of solid waste as carbon dioxide sorbents. The use of waste resources as carbon dioxide sorbents not only leads to the development of relatively low-cost materials, but also eliminates waste simultaneously.

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A novel magnetic MIL-101(Fe)/TiO composite was synthesized for photo degradation of tetracycline (TC) under solar light. The composite was characterized by XRD, TGA, SEM, TEM, EDS, BET, FTIR, XPS, VSM, ESR, and PL. The resultant composite was environment friendly material, which exhibited high TC degradation efficiency and excellent reusability.

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In the present work, liquid-liquid phase-change absorption of SO was investigated using N, N-dimethylcyclohexylamine (DMCHA) as an absorbent, and high boiling liquid paraffin (LP) as a solvent to reduce volatilization of the absorbent. The homogenous solution was split into two immiscible phases upon SO loading. The phase-change mechanism was attributed to the polarity variation of DMCHA before and after absorption by forming the charge-transfer complex DMCHA·SO.

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Using aluminum nitrate (AlN) and bauxite tailings (BTs) as different dopants, and lime mud (LM) as calcium source, a series of CaO-based sorbents were prepared for CO capture by dry mixing method; then, the carbonation conversions of multiple carbonation/calcination cycles were detected in a thermogravimetric analyzer (TGA). Effects of different dopants, dopant contents, precalcination conditions, and a long series of cycles on CO absorption properties were scrutinized, and the phase composition and morphologies were tested by scanning electron microscopy (SEM) and X-ray diffraction (XRD). Durability studies show that the sample doped with AlN remains a higher absorption conversion (30.

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Stimuli-responsive hydrogels have been widely researched as carrier systems, due to their excellent biocompatibility and responsiveness to external physiologic environment factors. In this study, dextran-based nanogel with covalently conjugated doxorubicin (DOX) was developed via Schiff base formation using the inverse microemulsion technique. Since the Schiff base linkages are acid-sensitive, drug release profile of the DOX-loaded nanogel would be pH-dependent.

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The search for green catalytic processes for the synthesis of useful polymers and incorporating the waste SO in highly-selective pathways become extremely important in the coming years. Herein, cellulose was modified by ethylenediamine, and then synthesized Schiff base with 3,5-di-tert-butyl-2-hydroxybenzaldehyde to immobilize chromium chloride and formed a novel heterogeneous cellulosic Cr(salen)-type catalyst for the first time. The cellulosic Cr(salen)-type catalyst shows high efficiency and recyclability in copolymerization of cyclohexene oxide with SO.

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Polysaccharide-based microgels with high water content, excellent biocompatibility and controllable particle size have been widely studied as ideal candidates for drug release and delivery. In this study, microgels based on dextran were developed via the Schiff base formation between aldehyded dextran and ethylenediamine in a water-in-oil (W/O) microemulsion. Particle size of the resulted microgel was controllable between 800 and 1100nm by modulating the amount of the employed co-surfactants (Span 80/Tween 80).

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Carbon dioxide, one of the major greenhouse gases, are believed to be a major contributor to global warming. As a consequence, it is imperative for us to control and remove CO2 emissions. The CaO, a kind of effective CO2 sorbent at high temperature, has attracted increasing attention due to some potential advantages.

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Using lime mud (LM) purified by sucrose method, derived from paper-making industry, as calcium precursor, and using mineral rejects-bauxite-tailings (BTs) from aluminum production as dopant, the CaO-based sorbents for high-temperature CO2 capture were prepared. Effects of BTs content, precalcining time, and temperature on CO2 cyclic absorption stability were illustrated. The cyclic carbonation behavior was investigated in a thermogravimetric analyzer (TGA).

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