Insights into the Efficient Release of the Polyacrylamide Drag Reducer via a pH-Responsive Inverse Polymer Emulsion.

The enormous demand for petroleum consumption has resulted in the shortage of fossil resources, prompting the need to explore unconventional reservoirs. Polyacrylamide emulsion drag reducers are capable of inhibiting the turbulence of fracturing fluids for enhancing the reservoir stimulation results, but the poor dissolution efficiency of polyacrylamide emulsion drag reducers is the primary limitation to their large-scale application. Here, a pH-responsive ionic liquid surfactant, oleic acid/cyclohexanediamine (HOA/HMDA), is synthesized by using oleic acid (HOA) and cyclohexanediamine (HMDA).

Novel Strategy of Polymers in Combination with Silica Particles for Reversible Control of Oil-Water Interface.

Hybrid smart emulsification systems are highly applicable in manipulating oil-in-water (O/W) droplets. Herein, novel switchable block polymers containing both zwitterionic and tertiary amine pendent groups were designed and synthesized to combine with charged silica particles to stabilize the O/W emulsion responsive to pH. This study was carried out in O/W emulsions stabilized with the polymer and silica particles under different pH conditions.