Understanding the underlying hydrodynamics of impinging blood droplets and finding out the physical parameters determining the bloodstain characteristics are of great importance in blood related forensic investigations. In this work, the impact of non-Newtonian blood droplets on solid surfaces ranging from lyophilic to superlyophobic was systematically investigated and compared to that of Newtonian droplets with a similar dynamic shear viscosity. We show that impinging blood droplets behave as low-viscosity Newtonian droplets in the short-time spreading, which is dominated by capillary and inertial forces, but their non-Newtonian viscoelasticity would notably affect the droplet retraction and post-impact oscillation occurring in large timescales.
View Article and Find Full Text PDFIn this study, ball mill pretreated iron ore tailings were modified with tetraethoxysilane (TEOS) and hexadecyltrimethoxysilane (HDTMS) to obtain iron ore tailings/polysiloxane (IOT/POS) superhydrophobic powders, which were subsequently mixed with chloroprene rubber solution (CRS) to prepare durable superhydrophobic composite coatings. The effect of HDTMS amount and reaction time on the wettability of the superhydrophobic powder was investigated. The influence of the superhydrophobic powders concentration on the wettability of the composite coatings as well as the degree of damage of the superhydrophobicity of the composite coating was analyzed by using the sandpaper abrasion and tape peeling tests.
View Article and Find Full Text PDFIn order to realize the high value-added resource utilization of solid waste and reduce the cost of rubber manufacturing, iron ore tailings (IOTs) were used as raw material to prepare a reinforcing filler of rubber through ultrafine grinding and surface organic modification techniques. We studied the effects of ball mill grinding conditions on the particle size and distribution of grinded iron ore tailings (G-IOTs). The effects of bis-(triethoxy-silyl-propyl)-tetrasulfide (Si69)-modified G-IOT (Si69-G-IOT) loading levels on the cure characteristics, static mechanical and dynamic mechanical properties of the styrene butadiene rubber (SBR) composites were also explored in this paper.
View Article and Find Full Text PDFIn this paper, we investigate robust parameter estimation and variable selection for binary regression models with . We investigate estimation procedures based on the minimum-distance approach. In particular, we employ minimum Hellinger and minimum symmetric chi-squared distances criteria and propose regularized minimum-distance estimators.
View Article and Find Full Text PDFIn this work, a new organic-inorganic composite filter was prepared. The thickness, pore size, air permeability, bursting strength and microstructure were characterized systematically, proving that coatings had regulatory effect on filters physical properties. Benefitting from the distinct coatings containing 5% sepiolite nanofibers after five times dilution, the physical properties of corresponding air filter exhibits the most favorable performance and meet the standard of air filter.
View Article and Find Full Text PDFThe longitudinal and cross sectional TEM images of sepiolite mineral nanofibers were prepared by cutting in the direction parallel and perpendicular to nanofibers, and the channel microstructure of sepiolite nanofibers was studied. The thermal insulation mechanism of sepiolite nanofibers was analyzed according to the diagrammatic sketch obtained from the above experimental method. The results showed that many discontinuously connected bending shape channels with about 23-26 nm in diameter existed in the center region of nanofibers, and many discontinuously connected irregular micropores and mesopores with the size of about 1-9 nm existed on the wall of nanofibers.
View Article and Find Full Text PDFNano zinc oxide with a high refractive index has good thermal reflection performance, hollow glass microspheres have good thermal reflection and insulation performance, and sepiolite nanofibers with many nanostructural pores have good thermal insulation performance. The dispensability of nano zinc oxide in coating materials was improved by optimizing surface silane coupling agent modification process, leading to the good thermal reflection performance. The thermal insulation performance was improved by hollow glass microspheres and sepiolite nanofibers.
View Article and Find Full Text PDFThe cleanability of easy-to-clean ceramic glazes doped with nanometer far-infrared materials was compared with that of some high-quality household ceramic glazes from the market. The cleanability was evaluated by the contact angle measurement using a sessile drop method with a Dataphysics OCA-30 contact angle analyzer. The results showed that the difference of contact angles of water on the glazes before soiling and after cleaning could be used as a parameter for evaluating the cleanability of the glazes.
View Article and Find Full Text PDFSurface modification is used to regulate surface free energy of sepiolite with 3-glycidoxypropyltrimethoxysilanes (3-GPTMS), 3-methacryloxypropyltrimethoxysilanes (3-MAPTMS) and 3-mercaptopropyltrimethoxysilane (3-MPTMS). Through characterization by Fourier transform infrared spectroscopy, surface free energy, zeta potential and sedimentation measurements and infrared emissivity, it is found that the surface free energy of 3-MPTMS modified sepiolite decreases to 31.72 mJ/m2 and the percentage of polar component increases to 89.
View Article and Find Full Text PDFIn the research described, ZrO2 nanotubes were prepared by anodization. The morphologies, crystal structure, etc. were characterised by scanning electron microscope (SEM), transmission electron microscope (TEM), X-ray diffractometer (XRD), and Fourier transform infrared spectroscopy (FTIR).
View Article and Find Full Text PDFJ Nanosci Nanotechnol
March 2010
Sepiolite nanofibers were prepared by high-speed air current superfine technique, using natural sepiolite samples as raw materials. Through characterization by scanning electron microscope (SEM), X-ray diffraction (XRD), dynamic contact angle meter and tensiometer (DCAMT) and Fourier transform infrared spectroscope (FTIR), it was found that the defibered sepiolite nanofibers with an average diameter of about 100 nm and length greater than 9 microm had a better far infrared emitting performance than acid-purified sepiolite as the contrast sample, and the defibering treatment led to the improvement of far infrared emitting performance of sepiolite due to the increase of surface free energy, the increase of infrared active bond vibrations, and the decrease of cell volume caused by the distortion of structural channel.
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