Recent climate warming has greatly shaped snow-cover patterns globally. Variances in snow cover are expected to affect soil microclimate and microorganisms, which may cause vegetation productivity to vary. However, exactly how snow cover influences the productivity of terrestrial vegetation remains unclear.
View Article and Find Full Text PDFAs many coal mines in China enter the deep mining stage, underground mining is starting to cause some problems, including dust disasters, rockburst, and coal and gas outburst in enclosed sites. In this study, water injection tests were conducted on coal samples using a coal rock multi-field seepage simulation experimental system under geo-stress conditions. Experimental results demonstrate that, as the cycle period increases, permeability exhibits a gradual increase.
View Article and Find Full Text PDFBackground: The multi-leaf collimator (MLC) is an advanced device utilized for beam shaping and intensity modulation in radiotherapy. With the framework of the contemporary single-layer MLC featuring a rounded leaf tip, the leaf tip transmission and leakage exert a considerable influence on radiotherapy.
Purpose: To scale down the leakage and transmission from the leaf gap when the opposite leaves are closed.
Glycine decarboxylase (GLDC) has been identified to be dysregulated and plays pivotal roles in various cancers. Besides, studies have suggested that GLDC expression is elevated in oral squamous cell carcinoma (OSCC) and associated with a worse prognosis, but the precise role and molecular mechanism of GLDC in OSCC remain unexplored. The current study first confirmed the high expression of GLDC in OSCC and its correlation with worse survival in patients with OSCC.
View Article and Find Full Text PDFRemoval of organic solvents (such as chloroform, toluene, etc.) in trace amounts using adsorbents from water is a challenge due to their low removal efficiencies and poor selectivities. Herein, four polysulfates (P1-P4) with different flexible group embedded backbones were synthesized via a sulfur fluoride exchange (SuFEx) reaction, and their swelling behaviors in organic solvents were investigated.
View Article and Find Full Text PDFDrought can cause significant disruption to forest ecosystems and may have long-term impacts on the structure and function of ecosystems after the end of drought. This is the key to quantifying the ability of ecosystem to respond to disturbance events by comprehensively analyzing the impact of drought on vegetation, the lagged effect, and ecosystem resilience to drought. This article takes broad-leaved forests and coniferous forests in multiple temperature zones of China as the object of study, using distributed lagged nonlinear model (DLNM) to construct a systematic method.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
September 2024
Organic piezoelectric nanogenerators (PENGs) are attractive in harvesting mechanical energy for various self-powering systems. However, their practical applications are severely restricted by their low output open circuit voltage. To address this issue, herein, we prepared two two-dimensional (2D) covalent organic frameworks (COFs, CityU-13 and CityU-14), functionalized with fluorinated alkyl chains for PENGs.
View Article and Find Full Text PDFAntibiotics are refractory degradable organic pollutants that present a significant hazard to water environments. In this work, a ternary composite (KB/BMO-GO) comprising of graphene oxide (GO), BiMoO (BMO), and a cross-linked benzene polymer (KB) was synthesized and applied to promote the synergistic adsorption-photocatalytic degradation of the refractory pollutant, oxytetracycline (OTC). The inclusion of GO and KB in the composite enhanced the OTC adsorption performance of the catalysts, and the construction of Z-scheme heterojunction promoted the photogenerated charge separation efficiency and broadened the range of light absorption, thereby enhancing the photocatalytic performance.
View Article and Find Full Text PDFEndothelial repair is essential for restoring tissue fluid homeostasis following lung injury. R-spondin3 (RSPO3), a secreted protein mainly produced by endothelial cells (ECs), has shown its protective effect on endothelium. However, the specific mechanisms remain unknown.
View Article and Find Full Text PDFJ Colloid Interface Sci
August 2024
Photocatalysis is a green and environmentally friendly method for degrading dangerous and nonbiodegradable pollutants. In this study, a sequence of metal-free triazine-based electronic donor-acceptor (D-A) conjugated polymers Tr-X (X = Th, BT, BTh) were prepared by D-A configuration regulation between triazine (Tr) and monomers containing N and S, such as thiophene (Th), bithiophene (BTh) and benzothiadiazole (BT) units, for the photocatalytic degradation of bisphenol A (BPA) and benzene contaminants in water under visible light. Among these, Tr-BTh exhibited complete photocatalytic degradation owing to its excellent D-A configuration.
View Article and Find Full Text PDFACS Appl Mater Interfaces
November 2023
Herein, self-assembled monolayers (SAMs) are constructed on the surface of TiC MXene to improve its environmental stability and piezocatalytic activity. TiC/SAMs-X (X = H, Cl, and NH) was prepared to enhance the piezocatalytic degradation of bisphenol A (BPA) and hydrogen production. Surface-treated TiC exhibits different lattice parameters and symmetry, thus leading to an increased polarization.
View Article and Find Full Text PDFProducing sulfur from a sulfide oxidation reaction (SOR)-based technique using sulfide aqueous solution has attracted considerable attention due to its ecofriendliness. This study demonstrates that NiS-doped cobalt sulfide NiS-CoS-supported NiCo alloy foam can deliver the SOR with superior electrocatalytic activity and robust stability compared to reported non-noble metal-based catalysts. Only 0.
View Article and Find Full Text PDFDysregulation of vitamin D receptor (VDR) is implicated in chronic obstructive pulmonary disease. However, whether VDR dysregulation contributes to the development of pulmonary fibrosis remains largely unknown. Analysis of bulk and single-cell RNA profiling datasets revealed VDR upregulation in lung fibroblasts from patients with pulmonary fibrosis or fibrotic mice, which was validated in lung fibroblasts from bleomycin-exposed mice and bleomycin-treated fibroblasts.
View Article and Find Full Text PDFAim: Exercise training exerts protective effects against sepsis-associated multiple organ dysfunction. This study aimed to investigate whether aerobic exercise protected against sepsis-associated acute kidney injury (AKI) via modulating R-spondin 3 (RSPO3) expression.
Methods: To investigate the effects of aerobic exercise on lipopolysaccharide (LPS)-induced AKI, LPS (20 mg/kg) was intraperitoneally injected after six weeks of treadmill training.
The production of hydrogen peroxide (HO) from oxygen and water is an attractive route for converting solar energy into chemical energy. In order to achieve high solar-to-HO conversion efficiency, floral inorganic/organic (CdS/TpBpy) composite with strong oxygen absorption and S-scheme heterojunction was synthesized by simple solvothermal-hydrothermal methods. The unique flower-like structure increased the active sites and oxygen absorption.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
August 2023
Converting CO into high-value C2 chemicals such as acetate with high selectivity and efficiency is a critical issue in renewable energy storage. Herein, for the first time we present a vibration-driven piezocatalysis with tin(II) monosulfide (SnS) nanobelts for conversion of CO to acetate with 100 % selectivity, and the highest production rate (2.21 mM h ) compared with reported catalysts.
View Article and Find Full Text PDFUrea degradation is one of the most crucial links in the natural nitrogen cycle. Exploring the real active species in the urea electro-oxidation process is of great significance for understanding the urea electro-oxidation mechanism and designing catalysts. A highly active and stable Prussian blue analogue catalyst (PBA@NiFe/NF) loaded on nickel foam was synthesized for electro-oxidation of urea.
View Article and Find Full Text PDFIn this study, a 3D thornball-like hierarchical β-InS, displaying extremely rapid photodegradation of cationic dyes, was synthesized by a facile method. The formation of a uniform thornball-like structure depended on the microwave reaction method and citric acid as the pH regulator. The size of InS was easily adjusted by changing the microwave irradiation time from 5 min to 15 min.
View Article and Find Full Text PDFA long-standing challenge in pneumonia diagnosis is recognizing the pathological lung texture, especially the ground-glass appearance pathological texture. One main difficulty lies in precisely extracting and recognizing the pathological features. The patients, especially those with mild symptoms, show very little difference in lung texture, neither conventional computer vision methods nor convolutional neural networks perform well on pneumonia diagnosis based on chest X-ray (CXR) images.
View Article and Find Full Text PDFAn optimized oxygen activity of catalysts can facilitate oxidation of volatile organic compounds. This work shows the first construction of Ce-Co oxide thin-walled nanoboxes. Bulk-phase lattice oxygen is activated by metal-metal interactions.
View Article and Find Full Text PDFElectrocatalyzed urea-assisted wastewater splitting is a promising approach for sustainable hydrogen production. However, the lack of cost-efficient electrocatalysts hinders its practical application. Herein, bimetal phosphide (NiCoP) nanowire arrays decorated with ultrathin NiFeCo metal-organic framework (NiFeCo-MOF) nanosheets on porous nickel foam (NF) were designed for urea-assisted wastewater splitting.
View Article and Find Full Text PDFKaohsiung J Med Sci
October 2022
Oral squamous cell carcinoma (OSCC) is one of the most frequent malignancies found in head and neck cancers. Dysregulation of lncRNAs has been proposed to be related to the development of OSCC. Here, we investigated the function and probable mechanisms of lncRNA DLEU1 in OSCC.
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