A new red phosphor for high time-resolved thermal sensitivity and plant growth.

Luminous materials with a rapid lifetime response have garnered significant interest in sensing technology. In this work, the transition element Mn doped phosphor SrTiO:Mn was synthesized by a traditional high temperature solid phase method. The emission peak of SrTiO:0.

Rh-Catalyzed Direct Heteroarylation of Unactivated C(sp)-H with -Heteroaryl Boronates.

Disclosed herein is a rhodium(III)-catalyzed direct heteroarylation reaction between unactivated aliphatic C(sp)-H bonds in 2-alkylpyridines and heteroaryl organoboron reagents. This catalytic protocol is compatible with various heterocyclic boronates containing - and -pyridine, pyrazoles, furan, and quinoline with strong coordination capability. The achievement of this methodology provides an efficient route to build new C(sp)-heteroaryl bonds.

Fluorescence Lifetime-Based Luminescent Thermometry Material with Lifetime Varying over a Factor of 50.

Recently, the growing demand for temperature detection is pushing forward the flourishing development of noncontact optical thermometry. Herein, a new red phosphor SrInTaO:Mn (SIT:Mn) was first constructed and systematically investigated. Based on the fairly rapid decline of the lifetime from 0.

The synthesis of aryl-heteroaryl derivatives the Rh-catalyzed heteroarylation of arenes and heteroaromatic boronates.

An efficient Rh-catalyzed strategy for constructing aryl-heteroaryl derivatives with removable ketoxime ether auxiliaries direct C-H heteroarylation based on arenes and heteroaromatic boronates has been disclosed. This protocol could tolerate various pyridine, pyrimidine, pyrazole, thiophene, and furan heteroaromatic boronates well, providing the desired products with high reactivities and excellent regioselectivity. The easy synthetic accessibility may offer potential for application in the synthesis of heterocyclic drug molecules containing aryl-heteroaryl motifs.

Designing a Polyphosphate Polymorph of CsMg(PO) as Host Lattice for Preparing Single Mn-Oxidation Doped Phosphor in the Open Environment.

Within Mn-activated phosphors, the oxidation state of Mn dopant strongly depends on the structural features of the host lattice. This paper reported a new polymorph of CsMg(PO) (CMP) with a complicated three-dimensional (3D) framework of [Mg(PO)] that is constructed by MgO octahedra and 1D infinite [PO] chains. Then we prepared a series of red phosphors CsMg(PO):Mn (CMP:Mn) by high temperature solid state reactions in the open air.

Rh-Catalyzed Direct Heteroarylation of C(sp)-H and C(sp)-H Bonds in Heterocycles with -Heteroaromatic Boronates.

Herein, we disclose a Rh-catalyzed heteroarylation of C(sp)-H and C(sp)-H bonds in heterocycles with organoboron reagents. This protocol displays high efficiency and excellent functional group tolerance. A range of heterocyclic boronates with strong coordinating atoms, including pyridine, pyrimidine, pyrazole, thiophene, and furan derivatives, can be extensively served as the coupling reagents.

Rh-Catalyzed C-H (Het)arylation/Vinylation of -2,6-Difluoroaryl Acrylamides.

Rh-catalyzed sp C-H cross-coupling of acrylamides with organoboron reactants has been accomplished using a commercially available -2,6-difluoroaryl acrylamide auxiliary. A broad range of aryl and vinyl boronates as well as a variety of heterocyclic boronates with strong coordinating ability can serve as the coupling partners. This transformation proceeds under moderate reaction conditions with excellent functional group tolerance and high regioselectivity.

Two microporous Fe-based MOFs with multiple active sites for selective gas adsorption.

Two Fe-based porous MOFs have been constructed from dimeric Fe-clusters and rod-shaped heterobimetallic {FeNa} chains as SBUs, respectively. Both of them exhibit highly selective CO adsorption over CH and N, owing to their abundant multiple active sites.

22-Azametallacrown-8 complex with a triazole-bridged ligand: synthesis, structure and magnetic properties.

Reaction of Mn(OAc)2·4H2O with the H2L ligand affords a new manganese 22-MC-8 azametallacrown [Mn8(μ3-O)2(μ3-OH)2(μ2-OH)2(L)6(OAc)2(OH2)4]·2DMF (H2L = 3-(2-oxyphenyl)-5-(pyrazin-2-yl)-1,2,4-triazole). The structural analysis of the complex reveals that the azaMC ring possesses -[Mn-O-Mn-N-N-Mn-N-N-Mn-N-N]- connectivity. The magnetic behavior of the complex shows the dominant antiferromagnetic interactions between the manganese ions with S = 4 and the frequency-dependent out-of-phase signal.

Targeted functionalization of porous materials for separation of alcohol/water mixtures by modular assembly.

Three isoreticular hydrogen-bonded frameworks with functionalized pore structures were constructed by a modular self-assembly process in which a series of amino acids with various substituents serve as facile exchange subassemblies to decorate the pore wall. The ordered amino acid side-chain groups in the pore channels play an important role in determining the adsorption behavior of the framework materials, and ensure exclusive adsorption of methanol/water over ethanol. Gas-chromatographic separation experiments demonstrated that alcohols can be efficiently separated from ternary water/methanol/ethanol mixtures and revealed a key influence of the adsorbate-host framework interaction on the practical separation performance of mixtures.

Borromean-entanglement-driven assembly of porous molecular architectures with anion-modified pore space.

A series of metal-organic frameworks based on a flexible, highly charged Bpybc ligand, namely 1⋅Mn⊃OH(-), 2⋅Mn⊃SO(4)(2-), 3⋅Mn⊃bdc(2-), 4⋅Eu⊃SO(4)(2-) (H(2)BpybcCl(2) = 1,1'-bis(4-carboxybenzyl)-4,4'-bipyridinium dichloride, H(2)bdc = 1,4-benzenedicarboxylic acid) have been obtained by a self-assembly process. Single-crystal X-ray-diffraction analysis revealed that all of these compounds contained the same n-fold 2D→3D Borromean-entangled topology with irregular butterfly-like pore channels that were parallel to the Borromean sheets. These structures were highly tolerant towards various metal ions (from divalent transition metals to trivalent lanthanide ions) and anion species (from small inorganic anions to bulky organic anions), which demonstrated the superstability of these Borromean linkages.

Bipyridinium array-type porous polymer displaying hydrogen storage, charge-transfer-type guest inclusion, and tunable magnetic properties.

A multifunctional pillared-layer porous coordination polymer, {[Mn(2)(Bpybc)(ox)(2)]8 H(2)O}(n), has been constructed based on a flexible viologen derivative, 1,1'-bis(4-carboxybenzyl)-4,4'-bipyridinium dichloride (H(2)BpybcCl(2)), and an oxalate (ox) coligand. Single-crystal X-ray analysis reveals that the compound possesses multichannels with dimensions of about 6.1x6.

Novel polythreaded coordination polymer: from an armed-polyrotaxane sheet to a 3D polypseudorotaxane array, photo- and thermochromic behaviors.

A novel coordination compound, {[Cd(BDC)(Bpybc)(1.5)].10H(2)O}(n), obtained by the reaction of CdCl(2) with 1,1'-bis(4-carboxybenzyl)-4,4'-bipyridinium dichloride (H(2)BpybcCl(2)) and 1,4-benzenedicarboxylic acid (H(2)BDC), contains 1D polymeric chains that are comprised of alternating rings and rods and dangling lateral arms.

The formation of a hydrated homochiral helix from an achiral zwitterionic salt, spontaneous chiral symmetry breaking and redox chromism of crystals.

A unique supramolecular helix assisted by water tetramers is obtained by static evaporation of aqueous solution of a zwitterionic salt, 1,1'-bis(4-carboxylatebenzyl)-4,4'-bipyridinium; spontaneous chiral symmetry breaking occurs in crystallization; interestingly, redox chromism behavior of crystals upon exposure to alcohol atmosphere has been observed.

Strong electron-accepting methylviologen dication confined in magnetic hosts: synthesis, structural characterization, charge-transfer and magnetic properties of {(MV)2[Ni(SCN)5].Cl.2H2O}n and {(MV)[m(N3)2(SCN)2]}n (M=Mn, Co).

Three hybrid host-guest compounds {(MV)2[Ni(SCN)5].Cl.2H2O}n (1), {(MV)[Mn(N3)2(SCN)2]}n (2) and {(MV)[Co(N3)2(SCN)2}n (3) (where MV2+ = methylviologen dication) have been obtained by self-assembly methods and characterized by X-ray crystallography, spectral methods and magnetic measurements.

[Construction of the recombinant adenovirus carrying porcine interferon gamma (poIFNgamma) and identification of its antiviral activity].

The total RNA was extracted from peripheral blood mononuclear cells (PBMC) which was isolated from Meishan porcine and induced with concanavaline A (ConA), then the porcine interferon gamma gene (PoIFNgamma, 501bp) was amplified by RT-PCR. The result of sequencing demonstrated that the amplified PoIFNgamma had 100% nucleotide homology with the other porcine IFNgamma sequence published on GenBank. The objective gene (PoIFNgamma) was inserted into adenoviral shuttle vector, pShuttle-CMV, to construct recombinant plasmid pSh-PoIFNgamma.

[Construction of recombinant retroviral vector carrying porcine interferon-gamma and its expression in porcine kidney cells (PK-15)].

Porcine interferon-gamma (PoIFN-gamma) of Chinese local brand, Meishan porcine, was cloned and inserted into retroviral vector pLXSN (neo r) . Using Lipofectamine, this recombinant plasmid was transfected into retroviral packing cell line, PA317 cells. These transfected cells were selected by DMEM containing 400microg/mL G418 for one week.