Despite decades of emission control measures aimed at improving air quality, Los Angeles (LA) continues to experience severe ozone pollution during the summertime. We incorporate cooking volatile organic compound (VOC) emissions in a chemical transport model and evaluate it against observations in order to improve the model representation of the present-day ozone chemical regime in LA. Using this updated model, we investigate the impact of adopting zero-emission vehicles (ZEVs) on ozone pollution with increased confidence.
View Article and Find Full Text PDFTropospheric ozone (O) is a strong greenhouse gas, particularly in the upper troposphere (UT). Limited observations point to a continuous increase in UT O in recent decades, but the attribution of UT O changes is complicated by large internal climate variability. We show that the anthropogenic signal ("fingerprint") in the patterns of UT O increases is distinguishable from the background noise of internal variability.
View Article and Find Full Text PDFEnviron Sci Technol
December 2023
The extent to which emission control technologies and policies have reduced anthropogenic NO emissions from motor vehicles is large but uncertain. We evaluate a fuel-based emission inventory for southern California during the June 2021 period, coinciding with the Re-Evaluating the Chemistry of Air Pollutants in CAlifornia (RECAP-CA) field campaign. A modified version of the Fuel-based Inventory of Vehicle Emissions (FIVE) is presented, incorporating 1.
View Article and Find Full Text PDFState inventories indicate that dairy operations account for nearly half of California's methane budget. Recent analyses suggest, however, that these emissions may be underestimated, complicating efforts to develop emission reduction strategies. Here, we report estimates of dairy methane emissions in the southern San Joaquin Valley (SJV) of California in June 2021 using airborne flux measurements.
View Article and Find Full Text PDFIn China, emissions of ozone (O)-producing pollutants have been targeted for mitigation to reduce O pollution. However, the observed O decrease is slower than/opposite to expectations affecting the health of millions of people. For a better understanding of this failure and its connection with anthropogenic emissions, we quantify the summer O trends that would have occurred had the weather stayed constant by applying a numerical tool that "de-weathers" observations across 31 urban regions (123 cities and 392 sites) over 8 years.
View Article and Find Full Text PDFThe hydroxyl radical (OH) is the most important oxidant on global and local scales in the troposphere. Urban OH controls the removal rate of primary pollutants and triggers the production of ozone. Interannual trends of OH in urban areas are not well documented or understood due to the short lifetime and high spatial heterogeneity of OH.
View Article and Find Full Text PDFThe hydroxyl radical (OH) is the primary cleansing agent in the atmosphere. The abundance of OH in cities initiates the removal of local pollutants; therefore, it serves as the key species describing the urban chemical environment. We propose a machine learning (ML) approach as an efficient alternative to OH simulation using a computationally expensive chemical transport model.
View Article and Find Full Text PDFBackground: Facemasks are increasingly worn during air pollution episodes in China, but their protective effects are poorly understood. We aimed to evaluate the filtration efficiencies of N95 facemasks and the cardiopulmonary benefits associated with wearing facemasks during episodes of pollution.
Results: We measured the filtration efficiencies of particles in ambient air of six types of N95 facemasks with a manikin headform.