Metallic Coatings Boost the Cooling Power of Nanoporous Alumina.

Passive daytime radiative cooling (PDRC) has emerged as a promising strategy to mitigate the increasing impact of heat waves. However, achieving effective PDRCs requires cost-effective, ecofriendly, and industrially scalable materials. In this study, we investigate the potential of anodic aluminum oxide (AAO) nanostructures coated with metals as passive radiative coolers.

Passive Daytime Cooling Foils for Everyone: A Scalable Lamination Process Based on Upcycling Aluminum-Coated Chips Bags.

The increasing energy demand for space cooling and environmental pollution caused by post-consumer plastic waste are two of the most challenging issues today. Passive daytime cooling, which dissipates heat to outer space without external energy input, has emerged recently as a sustainable technique for space cooling. In this work, a plastic waste-based passive daytime cooling foil is reported to alleviate both issues simultaneously.

Effect of Particle Size on the Orientation and Order of Assemblies of Functionalized Microscale Cubes Formed at the Water/Air Interface.

The impact of the particle size and wettability on the orientation and order of assemblies obtained by self-organization of functionalized microscale polystyrene cubes at the water/air interface is reported. An increase in the hydrophobicity of 10- and 5-μm-sized self-assembled monolayer-functionalized polystyrene cubes, as assessed by independent water contact angle measurements, led to a change of the preferred orientation of the assembled cubes at the water/air interface from face-up to edge-up and further to vertex-up, irrespective of microcube size. This tendency is consistent with our previous studies with 30-μm-sized cubes.

Investigation of the Orientation and Assembly of Functionalized Microcubes at the Oil-Water Interface.

The dependence of the preferred orientation of polystyrene microcubes on surface hydrophobicity at the water/hexadecane interface is reported. Similar to the water/air interfaces, the microcubes were shown to reside at the water/hexadecane interface with three distinct orientations: face-up, edge-up, and vertex-up. Concomitantly, ordered aggregates with flat plate, tilted linear, and close-packed hexagonal structures were formed, driven by capillary force.

From Chitosan to Chitin: Bio-Inspired Thin Films for Passive Daytime Radiative Cooling.

Passive radiative daytime cooling is an emerging technology contributing to carbon-neutral heat management. Optically engineered materials with distinct absorption and emission properties in the solar and mid-infrared range are at the heart of this technology. Owing to their low emissive power of about 100 W m during daytime, substantial areas need to be covered with passive cooling materials or coatings to achieve a sizeable effect on global warming.

A tailored indoor setup for reproducible passive daytime cooling characterization.

Passive daytime cooling materials can lower global energy consumption owing to their autonomous cooling capability. Although a significant number of passive cooling materials have been developed recently, their performance characterization is still challenging. Field tests experience high variability due to uncontrollable changes in environmental conditions.

Probing of local polarity in poly(methyl methacrylate) with the charge transfer transition in Nile red.

The permittivity of polymers and its spatial distribution play a crucial role in the behavior of thin films, such as those used, e.g., as sensor coatings.

Reconfigurable Microcube Assemblies at the Liquid/Air Interface: The Impact of Surface Tension on Orientation and Capillary-Force-Interaction-Driven Assembly.

The systematic investigation of the dependence of the orientation and capillary interaction of hydrophobized polystyrene microcubes at the liquid/air interface on the surface tension of the aqueous subphase is reported. By decreasing the subphase surface tension, the preferential orientation of the cubes was observed to change independent of the surfactant type from the vertex up to the edge up and finally to the face up. Concomitantly, the structure of the aggregates obtained by cube assembly was observed to change from a close-packed hexagonal to tilted linear and finally to flat plate.

Control of Orientation, Formation of Ordered Structures, and Self-Sorting of Surface-Functionalized Microcubes at the Air-Water Interface.

The dependence of the orientation of microscale PS cubes, which are surface functionalized on only five faces, at the water/air interface and the ordered aggregates formed by capillary force assembly are reported. Depending on the wettability of the faces, the cubes were shown to adopt a preferred orientation that changes with decreasing wettability from face up to edge up and further to vertex up. Concomitantly, stable aggregates with different structures were formed by capillary force self-assembly.

Sanggenon O induced apoptosis of A549 cells is counterbalanced by protective autophagy.

Sanggenon O (SO) is a Diels-Alder type adduct extracted fromMorus alba, which has been used for its anti-inflammatory action in the Oriental medicine. However, whether it has regulatory effect on human cancer cell proliferation and what the underlying mechanism remains unknown. Here, we found that SO could significantly inhibit the growth and proliferation of A549 cells and induce its pro-apoptotic action through a caspase-dependent pathway.

Tailored Combinatorial Microcompartments through the Self-Organization of Microobjects: Assembly, Characterization, and Cell Studies.

A new concept enables the generation of cell microenvironments by microobject assembly at an water/air interface. As the orientation of 30 μm sized polymer cubes and their capillary force assembly are controlled by the surface wettability, which in turn can be modulated by coating the initially exposed surfaces with gold and self-assembled monolayers, unique niches in closely packed arrays of cubes with vertex up orientation can be realized. The random assembly of distinctly different cubes, prefunctionalized or surface-structured exclusively on their top surface, facilitates the parallel generation of different microenvironments in a combinatorial manner, which paves the way to future systematic structure-property relationship studies with cells.

Development of formaldehyde dehydrogenase-coupled assay and antibody-based assays for ALKBH5 activity evaluation.

N6-methyladenosine (mA) is the most prevalent internal modification of eukaryotic messenger RNA (mRNA). Until now, two RNA demethylases have been identified, including FTO (fat mass and obesity-associated protein) and ALKBH5 (α-ketoglutarate-dependent dioxygenase alkB homologue 5). As a mammalian mA demethylase, ALKBH5 significantly affects mRNA export and RNA metabolism as well as the assembly of mRNA processing factors in nuclear speckles, and ALKBH5 may play a significant role in these biological processes.

Thin Poly(Di(Ethylene Glycol)Methyl Ether Methacrylate) Homopolymer Brushes Allow Controlled Adsorption and Desorption of PaTu 8988t Cells.

Poly(di(ethylene glycol)methyl ether methacrylate) (PDEGMA) brushes, which are known to suppress protein adsorption and prevent cell attachment, are reported here to possess interesting and tunable thermoresponsive behavior, if the brush thickness is reduced or the grafting density is altered. PDEGMA brushes with a dry ellipsometric thickness of 5 ± 1 nm can be switched from cell adherent behavior at 37 °C to cell nonadherent at 25 °C. This behavior coincides with the temperature-dependent irreversible adsorption of fibronectin from phosphate saline buffer and proteins present in the cell culture medium, as unveiled by surface plasmon resonance measurements.

Thickness Dependence of Bovine Serum Albumin Adsorption on Thin Thermoresponsive Poly(diethylene glycol) Methyl Ether Methacrylate Brushes by Surface Plasmon Resonance Measurements.

This study reports on the dependence of the temperature-induced changes in the properties of thin thermoresponsive poly(diethylene glycol) methyl ether methacrylate (PDEGMA) layers of end-tethered chains on polymer thickness and grafting density. PDEGMA layers with a dry ellipsometric thickness of 5-40 nm were synthesized by surface-initiated atom transfer radical polymerization on gold. To assess the temperature-induced changes, the adsorption of bovine serum albumin (BSA) was investigated systematically as a function of film thickness, temperature, and grafting density by surface plasmon resonance (SPR), complemented by wettability and quartz crystal microbalance with dissipation monitoring (QCM-D) measurements.