Objective: The objective of this study was to examine sex differences in the antidepressant and neurocognitive effects of adjunctive nonconvulsive electrotherapy (NET) in patients with treatment-refractory depression (TRD), which has not yet been thoroughly investigated.
Methods: The study enrolled 20 patients with TRD, comprising 11 males and 9 females, who underwent a series of 6 NET sessions. The 17-item Hamilton Depression Rating Scale (HAMD-17) was used to assess depressive symptoms, response, and remission at baseline and after the first, third, and sixth NET sessions.
Objective: This systematic review of randomized controlled studies (RCTs) and observational studies evaluated the efficacy and safety of stanford neuromodulation therapy (SNT) for patients with treatment-resistant depression (TRD).
Methods: A systematic search (up to 25 September, 2023) of RCTs and single-arm prospective studies was conducted.
Results: One RCT ( = 29) and three single-arm prospective studies ( = 34) met the study entry criteria.
In this study, we have successfully constructed AgPO/Ag/g-CN heterojunctions via the hydrothermal method, which displays a wide photo-absorption range. The higher photocurrent intensity of AgPO/Ag/g-CN indicates that the separation efficiency of the photogenerated electron-hole pairs is higher than that of both AgPO and Ag/g-CN pure substances. It is confirmed that the efficient separation of photogenerated electron-hole pairs is attributed to the heterojunction of the material.
View Article and Find Full Text PDFObjective: Intermittent theta-burst stimulation (iTBS), which is a form of repetitive transcranial magnetic stimulation (rTMS), can produce 600 pulses to the left dorsolateral prefrontal cortex (DLPFC) in a stimulation time of just over 3 min. The objective of this systematic review was to compare the safety and efficacy of iTBS and high-frequency (≥ 5 Hz) rTMS (HF-rTMS) for patients with treatment-resistant depression (TRD).
Methods: Randomized controlled trials (RCTs) comparing the efficacy and safety of iTBS and HF-rTMS were identified by searching English and Chinese databases.
We aimed to systematically evaluate the clinical efficacy and safety of accelerated intermittent theta burst stimulation (aiTBS) for patients with major depressive disorder (MDD) or bipolar depression (BD). A random-effects model was adopted to analyze the primary and secondary outcomes using the Review Manager, Version 5.3 software.
View Article and Find Full Text PDFRecently, we revealed the electronic nature of the tubular Au based on spherical aromaticity. The peculiar structure of the Au could be an ideal catalyst model for studying the adsorptions of the Au nanotubes. However, through Google Scholar, we found that no one has reported connections between the structure and reactivity properties of Au.
View Article and Find Full Text PDFRecently, the first example of Au-Ga clusters is synthesized and characterized, which can be described by the jellium model as a superatom with 8 valence electrons that come from the joint contribution of Au and Ga atoms, opening a whole new field for further research. Here, the structure features and stability of one Ga-doped Au cluster with magic number electrons (6 and 8) are analyzed in detail. Moreover, the valence electron fillings and chemical bonding of them are also further explored.
View Article and Find Full Text PDFEarlier findings have confirmed that CO molecules have propensities to adsorb on low-coordinated gold atoms (top sites) of Au-based clusters, which can be treated by the Blyholder model wherein the donation and π-back donation take place. Here, the structural features and stability of (AuLi) ( = 1-9) clusters were first analyzed using the GA-DFT method. The new adsorption modes, vibration frequencies and electronic interactions for Au-Li clusters with CO were investigated in detail.
View Article and Find Full Text PDFThe pyramidal Au cluster is a highly inert and stable superatomic molecule, but it is not suitable as a potential catalyst for covalent bond activations, , CO oxidation reaction. Herein, the adsorption and electronic properties of CO molecules on various pyramidal clusters based on the structural framework of Au are investigated using density functional theory. According to the SVB model, we constructed isoelectronic superatomic molecules with different pyramid configurations by replacing the vertex atoms of the Au using metal M atoms (M = Li, Be, Ni, Cu, and Zn group atoms).
View Article and Find Full Text PDFDue to their strong relativistic effects, Au clusters exhibit many unusual geometric structures. Among them, Au7-, Au8 and Au9+ have 18 valence electrons satisfying the magic numbers in the jellium model, respectively, but these three non-spherical clusters are not superatoms. In general, a single dopant atom can drastically change the structural and electronic properties of Au clusters.
View Article and Find Full Text PDFPhys Chem Chem Phys
February 2020
Owing to their unique properties, thiolate-protected gold clusters (denoted as Au(SR)) have attracted intense research interest both experimentally and theoretically. The superatom complex (SAC) and superatom network (SAN) models are significantly well-known concepts to explain the electronic stability of Au(SR). Based on the structural characters of Au(SR), the tetrahedral Au unit was found to be an elementary building block and used to design a series of tetrahedron-network clusters.
View Article and Find Full Text PDFGold clusters, which display a variety of unusual geometric structures due to their strong relativistic effects, have attracted much attention. Among them, Au has a high-symmetry tubular structure (D) with a large HOMO-LUMO energy gap, but its electronic stability still remains unclear. In this paper, the electronic nature of the Au cluster is investigated using the density functional theory method.
View Article and Find Full Text PDF