A novel adsorbent (PN-FeO-IDA-Zr) was developed from the chemical modification of peanut husk (a low cost material) with FeO, iminodiacetic acid (IDA) and zirconium (Zr) and its efficacy for the sequestration of wastewater assessed using Alizarin red (AR) and Acid chrome blue K (AK) as model pollutants. To elucidate the characteristics of the formed adsorbent, analytical techniques such as the Bruauner-Emmet-Teller (BET) method, X-ray photoelectron spectroscopy (XPS), Fourier-transform infrared (FTIR) spectroscopy, X-ray diffractive spectroscopy (XRD) and vibrating sample magnetometer (VSM) were applied. Results from these studies confirmed the formation of a crystalline mesoporous adsorbent with surface properties which enhanced its usefulness.
View Article and Find Full Text PDFTo enhance adsorption capacity of wheat straw (WS) toward copper ion from solution, carbon disulfide was used to modify WS by a facile grafting method through epichlorohydrin and ethylenediamine. So WS containing xanthate groups (XWS) was obtained. The XWS was characterized using elemental analysis, X-ray diffraction, infrared spectroscopy and adsorption property of XWS toward copper ions.
View Article and Find Full Text PDFThe presence of emerging micropollutants and dyes in water resource has raised global concern about their intense effects to aquatic environments, ecosystem and human health in general. So far, various adsorbents have been suggested for reducing the levels of bisphenol A, methylene blue and neutral red contamination in wastewaters. However, a number of these adsorbents seemed to have low adsorptive capacities and regeneration performances.
View Article and Find Full Text PDFWater Sci Technol
February 2020
Modified walnut shell (MWS) was obtained using diethylenetriamine through a grafting reaction and its adsorption capacity toward Cr(VI) was enhanced. The adsorbent was characterized by Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), and elemental analysis and the results showed that the modification was effective. To optimize experimental conditions, the effect of temperature, solution pH, salinity, contact time, and Cr(VI) concentration on adsorption quantity were performed in batch mode.
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