Two mass-imbalanced atoms in a hard-wall trap: Deep learning integrability of many-body systems.

The study of integrable systems has led to significant advancements in our understanding of many-body physics. We design a series of numerical experiments to analyze the integrability of a mass-imbalanced two-body system through energy-level statistics and deep learning of wave functions. The level spacing distributions are fitted by a Brody distribution and the fitting parameter ω is found to separate the integrable and nonintegrable mass ratios by a critical line ω=0.

Autophagy-Inducing MoO Nanowires Boost Photothermal-Triggered Cancer Immunotherapy.

Autophagy could play suppressing role in cancer therapy by facilitating release of tumor antigens from dying cells and inducing immunogenic cell death (ICD). Therefore, discovery and rational design of more effective inducers of cytotoxic autophagy is expected to develop new strategies for finding innovative drugs for precise and successful cancer treatment. Herein, we develop MoO nanowires (MoO NWs) with high oxygen vacancy and strong photothermal responsivity to ablate tumors through hyperthermia, thus promote the induction of cytotoxic autophagy and severe ICD.

A monolayer crystalline covalent network of polyoxometalate clusters.

Monolayer two-dimensional (2D) materials are of great interest because of their unique electronic structures, noticeable in-plane confinement effect, and exceptional catalytic properties. Here, we prepared 2D covalent networks of polyoxometalate clusters (CN-POM) featuring monolayer crystalline molecular sheets, formed by the covalent connection between tetragonally arranged POM clusters. The CN-POM shows a superior catalytic efficiency in the oxidation of benzyl alcohol, and the conversion rate is five times higher than that of the POM cluster units.

Trimethoxyflavanone relieves Paclitaxel-induced neuropathic pain via inhibiting expression and activation of P2X7 and production of CGRP in mice.

Paclitaxel (PTX) is an anticancer drug used to treat solid tumors, but one of its common adverse effects is chemotherapy-induced peripheral neuropathy (CIPN). Currently, there is limited understanding of neuropathic pain associated with CIPN and effective treatment strategies are inadequate. Previous studies report the analgesic actions of Naringenin, a dihydroflavonoid compound, in pain.

Enhancing CO Electrocatalysis on 2D Porphyrin-Based Metal-Organic Framework Nanosheets Coupled with Visible-Light.

2D catalysts combined with single atom sites are promising candidates to promote CO reduction performance, but the ability to target stable materials with distinct structure still remains challenging. Herein, a series of single metal atoms anchored 2D metal-organic framework nanosheets (MOF-NS-M) with visualized and well-ordered mesoporous structures are fabricated and exhibit enhanced CO reduction activity and selectivity with the assistance of visible-light. Encouragingly, the CO Faradaic efficiency of MOF-NS-Co exceeds 90% in a wide potential window of -0.

Tailoring Layer Number of 2D Porphyrin-Based MOFs Towards Photocoupled Electroreduction of CO.

Inspired by the success of graphene, a series of single- or few-layer 2D materials have been developed and applied in the past decade. Here, the successful preparation of monolayer and bilayer 2D porphyrin-based metal-organic frameworks (MOFs) by a facile solvothermal method is reported. The structure transition from monolayer to bilayer drives distinct electronic properties and restructuring behaviors, which finally results in distinct catalytic pathways towards CO electrocatalysis.

Recent Progress of Sub-Nanometric Materials in Photothermal Energy Conversion.

Sub-nanometric materials (SNMs) are an attractive scope in recent years due to their atomic-level size and unique properties. Among various performances of SNMs, photothermal energy conversion is one of the most important ones because it can efficiently utilize the light energy. Herein, the SNMs with photothermal energy conversion behaviors and their applications are reviewed.

Single-Crystal Inorganic Helical Architectures Induced by Asymmetrical Defects in Sub-Nanometric Wires.

Constructing single-crystal inorganic helical structures is a fascinating subject for a large variety of research fields. However, the driving force of self-coiling, particularly in helical architectures, still remains a major challenge. Here, using MoO sub-nanometric wires (SNWs) as an example, we identified that spontaneous helical architecture with different dimensional features is closely related with their surface asymmetrical defects.

Sub-Nanometer Nanobelts Based on Titanium Dioxide/Zirconium Dioxide-Polyoxometalate Heterostructures.

In addition to offering conformational flexibility, sub-nanometer nanobelts (SNBs) also outperform many larger nanobelts with large size owing to their ultrathin morphologies. However, to date, only a few monocomponent SNBs have been synthesized. This study presents a facile method for synthesizing ZrO -PMoO (PMZ) SNBs and TiO -PMoO (PMT) SNBs with heterostructures.

Nanoconfined Water-Molecule Channels for High-Yield Solar Vapor Generation under Weaker Sunlight.

Solar vapor generation is a promising method to efficiently produce fresh water. However, the insufficient vapor yields under natural daylight restrict its practical applications, and the basic evaporation mechanisms are deficient for reasonable design of evaporator structure. Here, hydrophobic nano-confined water molecule channels (NCWMCs) are demonstrated, which can reduce the vaporization enthalpy for water evaporation and achieve a record vapor generation rate of 1.

Atomic-Level Nanorings (A-NRs) Therapeutic Agent for Photoacoustic Imaging and Photothermal/Photodynamic Therapy of Cancer.

Photothermal therapy (PTT) and photodynamic therapy (PDT) have emerged as effective approaches for cancer treatment. Herein, we present atomic-level scale (0.5 nm thickness) ultrathin sulfur-doped molybdenum oxide nanorings (S-MoOx A-NRs) and with surface coating of polyethylene glycol (PEG) (PEG@S-MoOx A-NRs).

Bio-inspired synthesis of mesoporous HfO nanoframes as reactors for piezotronic polymerization and Suzuki coupling reactions.

Complex nanostructures with high compositional and structural tailorability are highly desired in order to meet the material needs in the rapid development of nanoscience and nanotechnology. Therefore, the synthetic technique is of essential importance but currently still suffers from many challenges. Herein, we elaborately explore and demonstrate the flexibility of the anisotropic metallo-organic compound (dihafnium dichloride, Cp2HfCl2) for the fabrication of inorganic architectures by mimicking the assembly behaviors in biomolecules.

Atomic-level molybdenum oxide nanorings with full-spectrum absorption and photoresponsive properties.

Superthin nanostructures, particularly with atomic-level thicknesses, typically display unique optical properties because of their exceptional light-matter interactions. Here, we report a facile strategy for the synthesis of sulfur-doped molybdenum oxide nanorings with an atomic-level size (thickness of 0.5 nm) and a tunable ring-in-ring architecture.