Publications by authors named "Qiao-Wei Yan"
Chempluschem
January 2025
Article Synopsis
- The study focused on synthesizing 5,15-bis(perfluorophenyl)-10-(4-carboxyphenyl) corrole and its metal complexes with Co(III), Mn(III), and Cu(III) to investigate their ability to catalyze the hydrogen evolution reaction (HER).
- Various proton sources, including AcOH, trifluoroacetic acid, and TsOH, were tested in dimethylformamide to analyze the pathways (EECC, EECEC, EEECEC) for HER based on acidity and concentration.
- Among the complexes, the Co corrole exhibited the highest efficiency with a turnover frequency of 201 s, showing the catalytic activity ranking as Co > Cu > Mn in
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