Multiform NiO nanowalls with a high specific surface area were constructed in situ on carbon foam (CF) to construct NiO@CF/OD composite phase change materials (CPCMs). The synthesis mechanism, microstructures, thermal management capability, and photothermal conversion of NiO@CF/OD CPCMs were systematically studied. Additionally, the collaborative enhancement effects of CF and multiform NiO nanowalls on the thermal properties of OD PCMs were also investigated.
View Article and Find Full Text PDFPhys Chem Chem Phys
February 2024
Theory and experiment have revealed that spin-orbit coupling (SOC) strongly depends on the relativistic effect in topological insulators (TIs), while the influence of orbitals is always ignored. Herein, we provide a direct way of controlling effective SOC with the help of orbital effects, reducing the dependence on elements. Taking 5d WCO and 4d MoCO MXenes as a specific example, we predict that by decreasing the hybridization strength of W atoms with C or O atoms in 2D WCO, the nontrivial bandgaps at the -point are directly enhanced.
View Article and Find Full Text PDFThe specific heat capacity plays a crucial role in influencing the heat transfer efficiency of materials. Considering the relatively low specific heat capacity of metals, this study focuses on investigating the impact of second-phase nano Ni particles on the microstructure and thermophysical properties of the alloy matrix. The alloys' phase compositions and microstructures were examined using X-ray diffraction phase analysis (XRD), electron probe micromorphology analysis (EPMA), and X-ray fluorescence spectroscopy (XRF).
View Article and Find Full Text PDFThe effect of gallium on the oxide film structure and overall oxidation resistance of low melting point Sn-Bi-Zn alloys was investigated under air atmosphere using thermogravimetric analyses. The liquid alloys studied had a Ga content of 1-7 wt.%.
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