One-pot synthesis of highly active and hydrothermally stable Pd@mHSiO yolk-shell-structured nanoparticles for high-temperature reactions in hydrothermal environments.

The facile synthesis of yolk-shell-structured nanoparticles (YSNPs) with mobile active metal cores and mesoporous inorganic-organic hybrid silica shells (mHSiO2) is important for their applications. In this work, Pd@mHSiO2 YSNPs have been synthesized in aqueous solution at 95 °C by a one-pot method without the need for extensive purification and separation steps. The method is simple and facile, and ingeniously combines the controlled synthesis of Pd nanocubes, coating of mesoporous silica, and transition from core-shell-structured nanoparticles (CSNPs) to YSNPs.