Nanoparticles-based glues have recently been shown with substantial potential for hydrogel adhesion. Nevertheless, the transformative advance in hydrogel-based application places great challenges on the rapidity, robustness, and universality of achieving hydrogel adhesion, which are rarely accommodated by existing nanoparticles-based glues. Herein, we design a type of nanohesives based on the modulation of hydrogel mechanics and the surface chemical activation of nanoparticles.
View Article and Find Full Text PDFACS Appl Mater Interfaces
September 2020
Interface is the Achilles' heel in flexible electronics, where slipping, delamination, or cracking resulting from the intrinsic mechanical property mismatch of different materials might fail the device or cause degradation. Robust connections with strong interfacial strength and low interfacial impedance are highly desired in all kinds of flexible devices, especially when they require stretchability. Here, a new strategy of employing homogeneity is proposed to facilely achieve robust connection without introducing a third-party interlayer.
View Article and Find Full Text PDFThe anode oxygen evolution reaction (OER) is known to largely limit the efficiency of electrolyzers owing to its sluggish kinetics. While crystalline metal oxides are promising as OER catalysts, their amorphous phases also show high activities. Efforts to produce amorphous metal oxides have progressed slowly, and how an amorphous structure benefits the catalytic performances remains elusive.
View Article and Find Full Text PDFCopper nanowires (Cu NWs) are among ideal candidates for fabricating various advanced nanodevices, especially flexible electronics and transparent conductive electrodes. However, although many efforts have been made, the commercialization of Cu NWs is still difficult. Herein, we report an in situ seed-mediated two-step strategy to synthesize well-defined Cu NWs in high yield.
View Article and Find Full Text PDFImproving heteroatomic interactions via alloying or forming heterogeneous catalysts is of importance to the enhancement in terms of electrocatalytic activity and stability. In this work, a simple galvanic replacement reaction was utilized to synthesize low Pt-based quaternary nanotubes (NTs). It is easy to obtain PtPdRuTe NTs with different composition and controlled shape using ultrathin Te nanowires (NWs) as sacrificial templates for its high activity.
View Article and Find Full Text PDFThis article reports a novel scalable method to prepare ultrathin and uniform Pd@Pt nanowires (NWs) with controllable composition and shell thickness, high aspect ratio, and smooth surface, triggered by bromide ions via a galvanic replacement reaction between PtCl6(2-) and Pd NWs. It was found that bromide ions played a vital role in initiating and promoting the galvanic reaction. The bromide ions served as capping and oxidized etching agents, counterbalancing the Pt deposition and Pd etching on the surface to give final Pd@Pt core-shell nanostructures.
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