Corrosion poses a significant problem for several industrial sectors, inducing continuous research and development of corrosion inhibitors for use across a wide range of industrial applications. Here, we report the effectiveness of three newly developed Schiff bases derived from amino acids and 4-aminoacetophenone, namely, , , and , as environmentally friendly corrosion inhibitors for Q235 steel in hydrochloric acid using electrochemical and surface analyses, in addition to theoretical techniques. The electrochemical findings of potentiodynamic polarization (PDP) demonstrated that the explored compounds serve as mixed-type inhibitors and can effectively suppress steel corrosion, with maximal protection efficiencies of 93.
View Article and Find Full Text PDFThree new organic molecules having a benzimidazole base were synthesized and used for the protection of carbon steel (X56) against corrosion in 1.00 M HCl solution. The protection against corrosion was assessed by electrochemical frequency modulation (EFM), electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization (PDP).
View Article and Find Full Text PDFThe turbine blades of turbochargers are corroded after being cleaned with water in the presence of gasses produced during the combustion of heavy fuel. For that, manganese oxide (MnO), titanium dioxide (TiO), and titanium oxide-graphene (TiO-C) nanomaterials have been coated on the nickel alloy, which is the composition of turbine blades, by the electrophoretic deposition technique for protection against the corrosion process. The anticorrosion performance of nanomaterial coatings has been investigated using electrochemical methods such as open circuit potential, potentiodynamic, electrochemical impedance, and linear polarization resistance in a 1 M HSO solution saturated with carbon dioxide.
View Article and Find Full Text PDFThis study uses nickel nanoparticles coated on the nickel-chromium (Ni-Cr) alloy by the electrodeposition technique to protect the alloy against corrosion. An open-circuit potential and potentiodynamic and linear polarization resistance in a 1 M HSO solution saturated with carbon dioxide were used to study the anticorrosion performance of nanoparticle coatings. When coated with nanomaterials, the corrosion rate of Ni-Cr alloy was lower than when it was bare, and the potential for corrosion increased from -0.
View Article and Find Full Text PDFIn this study, we addressed a selective and sensitive electrochemical approach for detecting morphine (MO) using the TbFeO/CuO nanocomposite. Crataegus and walnut leaf as the environmentally friendly agents were used to synthesis TbFeO/CuO and energy disperse spectroscopy (EDS), Fourier-transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), scanning electron microscope (SEM), as well as vibrating-sample magnetometer (VSM) were employed for characterizing the products. In addition, chronoamperometry, cyclic voltammetry (CV) and differential pulse voltammetry (DVP) were applied to examine the electrochemical behavior of MO.
View Article and Find Full Text PDFThe present study is on the fabrication of new photocatalytic nanocomposites (DyO-SiO) employing a basic agent, tetraethylenepentamine (Tetrene), through a simple, efficient and, quick sonochemical approach. The features of the fabricated photocatalytic nanocomposite were examined employing a variety of microscopic and spectroscopic methods such as XRD, EDS, TEM, FTIR, DRS, and FESEM. The outcomes of morphological studies demonstrated that by proper tuning of sonication time and ultrasonic power (10 min and 400 W), a porous nanocomposite composed of sphere-shaped nanoparticles with a particle size in the range of 20 to 60 nm could be fabricated.
View Article and Find Full Text PDFAn effective process for the green and rapid synthesis of biologically active polysubstituted pyrroles and 1,2,4,5-tetrasubstituted imidazoles derivatives using Cu@imine/FeO MNPs catalyst under solvent-free conditions is explained. This catalyst showed high reactivity for the synthesis of a set of different derivatives of polysubstituted pyrroles and 1,2,4,5-tetrasubstituted imidazole derivatives under appropriate reaction conditions and short times. Moreover, the catalyst was also recycled and reused for six runs with no considerable reduction in reactivity and yields.
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