Microplastics (MPs) discharged from wastewater treatment plants (WWTPs) have emerged as serious pollutants in aquatic environments. Herein, a new magnetic filter (MFA) was prepared using an acidification-magnetization method with fly ash (FA) as the base material. The filter specifically targeted the removal of 1-μm polystyrene microspheres (PSMPs) because of the challenges they pose in filtration processes.
View Article and Find Full Text PDFHeavy metal ions and antibiotics were simultaneously detected in authentic water systems. This research, for the first time, employed synthesized sophorolipid-modified fly ash(SFA) to eliminate tetracycline(TC) and lead(Pb) from wastewater. Various characterization techniques, including SEM-EDS, FTIR, XPS, BET, and Zeta, were employed to investigate the properties of the SFA.
View Article and Find Full Text PDFThis study bridges the knowledge gap pertaining to the pathways of heavy metal accumulation and migration within the industrial chain of large-scale cattle farms. Two such farms in Shaanxi serve as a basis for our exploration into Zn, Cu, Cr, Pb, As, and Cd dynamics. Employing material flow analysis complemented by predictive models, we evaluate the potential ecological risks of arable soil from heavy metal influx via manure application.
View Article and Find Full Text PDFCocomposting coal gangue and sludge eliminates the challenge of utilizing coal gangue. However, there is limited understanding about the feasibility of cocomposting sludge and coal gangue, as well as the composting indicators, functional microorganisms, and safety risks involved. Therefore, this study evaluated the feasibility of enhancing carbon composting in coal gangue by incorporating sludge along with sawdust as a conditioner.
View Article and Find Full Text PDFThe pollution of water bodies by heavy metals (HMs) such as Pb(II) and Cd(II) poses a serious environmental risk. Herein, rice straw biochar (RBC) modified with calcium thioglycolate was used to remove Pb(II) and Cd(II) from aqueous solutions. The adsorption performance of the modified biochar was investigated via adsorption kinetics and isotherm model fitting.
View Article and Find Full Text PDFLong-term accumulation of toxic heavy metals in the environment was a potential hidden danger. High energy consumption, complicated operation and low adsorption capacity were the disadvantages of most current adsorbents. This study used one-step modification of fly ash (FA) by low-temperature melting method with KOH as the activator to generate modified fly ash (KFA) with high adsorption capacity to remove heavy metals from aqueous solutions.
View Article and Find Full Text PDFSeveral studies have been conducted on nanoplastics (NPs). However, few studies have investigated the complexity of the interactions between NPs and other aqueous pollutants in multi-solute media. In this study, the adsorption of polystyrene nanoplastics (PSNPs) on magnetic materials (MS) in the presence of available nitrogen (AN) was studied.
View Article and Find Full Text PDFNanomaterials (Basel)
October 2021
The use of carbon nanoparticles (CNPs) as a fertilizer synergist to enhance crop growth has attracted increasing interest. However, current understanding about plant growth and soil response to CNPs is limited. In the present study, we investigated the effects of CNPs at different application rates on soil properties, the plant growth and nutrient use efficiency (NUE) of corn ( L.
View Article and Find Full Text PDFLead (Pb) is a toxic metal in industrial production, which can seriously threat to human health and food safety. Thus, it is particularly crucial to reduce the content of Pb in the environment. In this study, raw fly ash (FA) was used to synthesise a new active silicate materials (IM) employing the low-temperature-assisted alkali (NaOH) roasting approach.
View Article and Find Full Text PDFIn this study, modified coal fly ash (NMFA) was prepared by sodium hydroxide (NaOH) with low-temperature hydrothermal method. The differences of the ash to alkali mass ratio (5:3, 5:4, 5:5, 5:6), calcination temperature (100 ℃, 200 ℃, 300 ℃), and calcination time (1 h, 3 h, 5 h) were investigated. The adsorption experiments obtained the optimal result with the ash to base ratio of 5:5, calcination temperature of 200 ℃, and calcination time of 3 h, adsorbing 90.
View Article and Find Full Text PDFEcotoxicol Environ Saf
June 2021
In this study, a low-temperature roasting and hydrothermal methods were used to modify the fly ash resulting in two new types of adsorption materials - modified fly ash (MFA) and artificial zeolite (ZE). These modified fly ashes, as well as a natural zeolite (ZO) were applied to two types of contaminated soils to explore their effects and mechanisms on the behavior of Cd and Pb through leaching column experiments. The bioavailable of Pb, Cd, pH, dissolved organic carbon (DOC), organic matter, as well as the microbial community changings were detected.
View Article and Find Full Text PDFCadmium (Cd) and lead (Pb) are toxic heavy metals that impact human health and biodiversity. Removal of Cd/Pb from contaminated soils is a means for maintaining environmental sustainability and biodiversity. In this study, we applied a newly modified material fly ash (NA), zeolite (ZE), and fly ash (FA) to the paddy soils and evaluated the effects of Cd/Pb accumulation in rice via a one-year field experiment.
View Article and Find Full Text PDFIn this study, the modified gangue (GE) was prepared by calcination at lower temperatures using potassium hydroxide (KOH) as the activating agent. The field emission scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS), Fourier transform infrared spectroscopy (FTIR), and X-ray fluorescence (XRF) methods were employed to analyze the physicochemical characteristics of GE before and after the modification. Besides, the GE and commercial zeolite (ZE) were compared in the remediation of Cd-contaminated soil in field experiments.
View Article and Find Full Text PDFThis work focused on preparation a novel adsorbent from coal fly ash (CFA) and solid alkali (NaOH) by low temperature roasting method. The modification parameters (mass ratio, calcination time and temperature) were specifically studied and optimized. The adsorption experiment results indicated that, the adsorption amounts of Cd were enhanced with the decreasing mass ratio of CFA and NaOH, and the adsorption amounts of Cd were 32.
View Article and Find Full Text PDFEnviron Sci Pollut Res Int
February 2020
Coal fly ash (FA) is a solid waste produced in coal combustion. This study focused on the removal of Cd from wastewater by a newly synthesized adsorbent material, the low-temperature and sodium hydroxide-modified fly ash (SHM-FA). The SEM and BET analyses of SHM-FA demonstrated that the adsorbent was porous and had a huge specific surface area.
View Article and Find Full Text PDFInt J Phytoremediation
April 2020
Contamination of the soil by Cadmium (Cd) is emerged as a critical environmental problem in China due to current urbanization and industrial activities that hinder the sustainable future development of agriculture. In this study, a system combined by earthworm and L. () was designed for remediation of Cadmium from contaminated soils.
View Article and Find Full Text PDFModified fly ash was prepared through low-temperature roasting method using NaOH as activator. The techniques of Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), energy dispersive X-ray (EDX), X-ray photoelectron spectroscopy (XPS) and the X-ray diffraction (XRD) were introduced to analyze the chemical and physical performance of samples, respectively. It was found that a significant improvements in activity and specific surface area of adsorbent.
View Article and Find Full Text PDFInt J Phytoremediation
September 2016
A two-year in-situ phytoremediation trial was launched in Shenyang Zhangshi (Sewage) Irrigation Area (SZIA). The phytoremediation efficiency of Solanum nigrum L. was determined, by both monitoring the change of soil Cadmium level in the upper 20 cm of soil, and calculating the plant uptake of soil Cd.
View Article and Find Full Text PDFEcotoxicol Environ Saf
March 2016
Because of its high Cd uptake and translocation, lettuce is often used in Cd contamination studies. However, there is a lack of information on Cd accumulation in the above-ground parts of lettuce during the entire growing season. In this study, a field experiment was carried out in a Cd-contaminated area.
View Article and Find Full Text PDFBull Environ Contam Toxicol
December 2015
A microcosm experiment with artificially contaminated soils was conducted in a greenhouse to evaluate the effect of gibberellic acid 3 (GA3) on phytoremediation efficiency of Solanum nigrum L. The GA3 was applied at three different concentrations (10, 100, 1000 mg L(-1)) to S. nigrum.
View Article and Find Full Text PDFBull Environ Contam Toxicol
September 2013
In this study, Solanum nigrum L. was used as a hyperaccumulator for remediation of cadmium contaminated soil, and 3 different cultivation protocols were investigated. The results showed that a double cropping treatment enhanced the phytoremediation efficiency significantly, since it increased the amount of Cd extracted in one growing season by a factor of 1.
View Article and Find Full Text PDFIn this study, the effects of heavy metals (Cd, Cu, Pb, Zn) on EROD and CYP3A4 activities in the earthworm Eisenia fetida were evaluated to find out their possible induction and potential as biomarkers for soil heavy metal contamination. The earthworms were exposed to increasing concentrations of Cd (0.1-8 mg L(-1)), Cu (10-200 mg L(-1)), Pb (20-400 mg L(-1)) or Zn (50-400 mg L(-1)) in filter papers for 48 h.
View Article and Find Full Text PDFBull Environ Contam Toxicol
April 2012
A field study was conducted to evaluate the phytoremediation efficiency of cadmium (Cd) contaminated soil utilizing the Cd hyperaccumulator Beta vulgaris L. var. cicla during one growing season (about 2 months) on farmland in Zhangshi Irrigation Area, the representative wastewater irrigation area in China.
View Article and Find Full Text PDFInt J Phytoremediation
August 2012
In this study, Solanum nigrum L. was used in-situ for Cdphytoremediation in Cd polluted soil on Shenyang Zhangshi Irrigation area (SZIA) in 2008. The performance of the plant over the whole growth stage was assessed.
View Article and Find Full Text PDFField trials contribute practical information towards the development of phytoremediation strategies that cannot be provided by laboratory tests. We conducted field experiments utilizing the Cd hyperaccumulator plant Solanum nigrum L., on farmland contaminated with 1.
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