Achieving selective detection of ppb-level CO is important for air quality testing at industrial sites to ensure personal safety. Noble metal doping enhances charge transfer, which in turn reduces the detection limit of metal oxide gas sensors. In this work, metal-organic framework-derived Au-doped InO nanotubes with high electrical conductivity are synthesized by pyrolysis of the Au-doped metal-organic framework (In-MIL-68) as a template.
View Article and Find Full Text PDFInO is an optimal material for sensitive detection of carbon monoxide (CO) gas due to its low resistivity and high catalytic activity. Yet, the gas response dynamics between the CO gas molecules and the surface of InO is limited by its solid structure, resulting in a weak gas response value and sluggish electron transport. Herein, we report a strategy to synthesize porous InO/FeO core-shell nanotubes derived from In/Fe bimetallic organic frameworks.
View Article and Find Full Text PDFGuang Pu Xue Yu Guang Pu Fen Xi
July 2015
Flame photometric analysis technology has been proven to be a rapid and sensitive method for sulfur and phosphorus detection. It has been widely used in environmental inspections, pesticide detection, industrial and agricultural production. By improving the design of the traditional flame photometric detector, using grating and CCD sensor array as a photoelectric conversion device, the types of compounds that can be detected were expanded.
View Article and Find Full Text PDFGuang Pu Xue Yu Guang Pu Fen Xi
February 2015
A novel naphthalimide derivatives N-hexyl-4-benzylamino-naphthalimide(HBN) was synthesized from 4-bromo-1, 8-naphthalic anhydride, and the structure was characterized by NMR and MS. Spectral properties of HBN for recognition of Fe3+ were investigated by fluorescence spectrum. In a certain range of Fe3+ from 4 x 10(-7) to 1 x 10(-2) mol x L(-1), the fluorescence intensity of HBN significantly reduced with increasing concentration of Fe3+ in ethanol/water (1:1, volume ratio).
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