Symmetrical and asymmetrical surface structure expansions of silver nanoclusters with atomic precision.

Controlling symmetrical or asymmetrical growth has allowed a series of novel nanomaterials with prominent physicochemical properties to be produced. However, precise and continuous size growth based on a preserved template has long been a challenging pursuit, yet little has been achieved in terms of manipulation at the atomic level. Here, a correlated silver cluster series has been established, enabling atomically precise manipulation of symmetrical and asymmetrical surface structure expansions of metal nanoclusters.

Study on wettability of water stemming for blasting dust adjusted by surfactants and inorganic salts.

Water stemming is an efficient method of removing blasting dust by wetting. There is still a lack of methods for rapid optimization of water stemming components with high wettability. Herein, blasting dust was collected from a tunnel in Chongqing (China) to investigate its removal performance by different water stemmings.

Identification of a pathogenic SDHD mutation in a Chinese family with hereditary head and neck paraganglioma: implications for genetic counseling and management.

Background: This study aims to identify a pathogenic SDHD mutation associated with hereditary head and neck paraganglioma (HNPGL) in a Chinese family and to explore its implications for genetic counseling.

Methods: The study involved a family with 15 members spanning three generations. A 31-year-old patient (II-4) was diagnosed with a left parotid gland tumor and a right carotid body tumor, while both the father and elder sister had right carotid body tumors, and the third sister had bilateral carotid body tumors.

Formaldehyde-purifying air conditioner with integrated gas-phase photoelectrocatalytic system.

Developing an efficient and economical indoor air purification system for catalytic decomposition of formaldehyde is of great significance. In this work, an indoor air conditioner capable of purifying formaldehyde was designed by directly integrating defective WO/TiO nanotube catalytic fin, with both thermal conductivity and gas-phase photoelectrocatalytic (GPEC) properties, onto the condenser component. The electrochemical treatment of the catalytic fin introduced a substantial number of oxygen vacancies, resulting in a significant increase in carrier concentration and mobility to the semi-metallic level.

An improved ultrasound-assisted synthesis of phenytoin suitable for undergraduate education.

A convenient and efficient method for undergraduate student experiments involves the one-pot synthesis of phenytoin from benzoin. This method utilized ultrasonic irradiation in the presence of basic catalyst at room temperature and atmospheric pressure, resulting in shortened reaction times, good yields, and excellent reproducibility. By employing a low-cost ultrasonic cleaner for ultrasonic irradiation in student experiments, the need for expensive equipment investment during the teaching process can be minimized.

Constructing Heterojunction Photocatalyst Systems with Spatial Distribution of Au Single Atoms for CO Reduction.

In single-atomic photocatalyst systems, the spatial distribution of single atoms on heterojunctions and its impact on photocatalytic processes, particularly on carrier dynamics and the CO reduction process involving multielectron reactions, remains underexplored. To address this gap, a WO/TiO nanotube heterojunction with a spatially selective distribution of Au single atoms was developed using an oxygen vacancy anchoring strategy for CO photoreduction. By anchoring Au atoms onto the WO or TiO components, a substantial number of active sites are generated and the electron transfer pathways from the heterojunction toward Au sites are formed, thereby enhancing carrier separation and concentration.

Application and Output Performance Comparison of Janus and Traditional Transition Metal Chalcogenides in Ytterbium-Doped Fiber Lasers.

Janus transition metal disulfide (TMD) monolayers have two distinct carbon surfaces that break the inherent ground external mirror symmetry. When compared to traditional TMD materials, Janus TMDs not only inherit the advantages of traditional TMDs but also have new characteristics that are different from those of traditional TMDs. This paper describes the development of a stable passive Q-switched ytterbium-doped fiber laser (YDFL) with operating wavelengths of 1032.

Metavirome analysis of domestic sheep in Shaanxi, Gansu, and Ningxia, China.

Sheep play an important role in China's agricultural development, but they are also potential hosts for many viruses, some of which have been identified as zoonotic pathogens, which may pose a serious threat to social public health and animal husbandry. Therefore, clarifying the characteristics of viruses in sheep will provide an important basis for the study of pathogenic ecology and viral evolution of viruses carried by sheep. We collected nasal and anal swabs from 688 sheep in 22 counties in Shaanxi, Gansu, and Ningxia, China, between January 2022 and July 2023, and utilized next-generation sequencing technology and bioinformatics approaches to identify the viruses in the samples.

Improving electron injection of organic light-emitting transistors interface layer design.

Ambipolar transport is crucial for constructing high performance organic light-emitting transistors (OLETs), but the ambipolar feature is usually not exhibited due to ineffective electron injection especially in symmetric device geometry. Herein, we show that electron injection could be greatly enhanced through the judicious design of an organic interface layer of 3,7-di(2-naphthyl)dibenzothiophene ,-dioxide (DNaDBSO) which shows an interfacial dipole effect upon contact with a metal electrode, especially an Au electrode. When incorporating a DNaDBSO film beneath Au electrodes, the electron injection and mobility were significantly enhanced in 2,6-diphenylanthracene-based OLETs, and thus ambipolar transport (maxh: 2.

6.7-8.1 µm tunable single-frequency difference frequency generation in ZGP for high-resolution spectroscopy.

Difference frequency generation (DFG) based tunable single-frequency mid-infrared (MIR) light sources are desirable for high-resolution spectroscopy, sensing, and imaging. In this work, we demonstrate a continuous-wave (CW) single-frequency DFG in a ZnGeP (ZGP) crystal driven by all-fiber near-infrared (NIR) fiber lasers, for the first time to our knowledge. The all-fiber NIR laser sources consist of a 1.

Light-chain amyloidosis with concomitant symptomatic myeloma (CRAB-SLiM features): clinical characteristics, cytogenetic abnormalities, and outcomes.

Background: Patients with light-chain (AL) amyloidosis and concomitant multiple myeloma (MM) are known to have a worse prognosis, while the prognostic implication of cytogenetic abnormalities (CA) and optimal treatment schemes are not well-established. By comparing patients with MM or AL amyloidosis (AL) alone, this study aimed to evaluate the clinical characteristics, CA, and outcomes of patients with AL amyloidosis and concomitant symptomatic MM (MM-AL) and sought to provide evidence for their management.

Methods: In total, 915 consecutive patients with newly diagnosed AL amyloidosis or MM were retrospectively analyzed.

Synchronous control of nitrogen and phosphorus release from sediments in shallow lakes under wind disturbance by modified zeolite and Ca/Al-based sludge combination.

To inhibit eutrophication caused by endogenous pollutants release, the experiment explored the efficiency and mechanism of the synchronous control of nitrogen (N) and phosphorus (P) release from sediments in shallow lakes under wind disturbance by modified Ca/Al-based sludge (MS) and modified zeolite (MZ). High-temperature calcination and NaCl impregnation increased the pore volume of MS and Na content of MZ, and the adsorption capacity of MS for PO-P and MZ for NH-N was as high as 42.01 and 20.

Generation of 8-fs and 13-nJ pulse from a Yb-fiber system with nonlinear-pulse-compression.

In this study, we demonstrated a few-cycle pulse generation system delivering an 8-fs and 13-nJ pulse. The oscillator of this system is a mode-locked fiber laser based on a nonlinear amplifying loop mirror (NALM), which is injected into the gain management nonlinear (GMN) amplifier after pre-chirp management by a chirped fiber Bragg grating (CFBG) and a passive fiber. Subsequently, a hollow-core photonic bandgap (HC-PBG) fiber is employed to compensate for the dispersion, achieving a pulse duration of 49.

Simultaneous generation of hydroxyl and hydrogen radicals from H/OH pairs caused by water-solid contact electrification.

Water-solid contact electrification is a common physical phenomenon involving interfacial electron and ion transfer, recently discovered to trigger unique redox reactions. Here, we demonstrate the generation of both hydroxyl and hydrogen radicals when water contacts SiO. The coexistence of hydroxyl and hydrogen radicals is confirmed by simultaneous nitrate reduction and nitrite oxidation during the contact.

Real-Time Gait Intention Recognition for Active Control of Unilateral Knee Exoskeleton.

Real-time gait estimation is important for the synchrony control of robotic exoskeleton to provide walking assistance. However, for stroke patients with hemiplegic paralysis, the gait pattern is very complex. Accurate and timely gait intention recognition is therefore difficult.

Quinoline Substituted Anthracene Isomers: A Case Study for Simultaneously Optimizing High Mobility and Strong Luminescence in Herringbone-Packed Organic Semiconductors.

The development of high mobility emissive organic semiconductors is significant for advancing optoelectronic devices with simplified architecture and enhanced performance. The herringbone-packed structure is regarded as the ideal arrangement for simultaneously achieving high mobility and strong emission in organic semiconductors. However, it remains a great challenge that the relationship between molecular structure and optoelectronic property is still elusive.

Genome-wide identification and expression analysis of SpUGE gene family and heterologous expression-mediated Arabidopsis thaliana tolerance to Cd stress.

The UDP-glucose 4-epimerase (UGE) enzyme plays a critical role in plant growth and responses to abiotic stressors, such as heavy metal exposure. However, UGE-mediated remodeling of cell wall polysaccharides in response to these stressors remains poorly understood in willow. This study investigated the structure, function, and expression patterns of the UGE gene family in willow, focusing on cadmium treatment to elucidate how SpUGE1 enhances Cd resistance.

Quantitative analysis of three bioactive components of Biancaea decapetala extracts in rat plasma and RAW264.7 cells using UPLC-MS/MS and its application to comparative pharmacokinetics in normal and diseased states.

Biancaea decapetala (Roth) O.Deg. (Fabaceae), traditionally utilized by the Hmong for treating rheumatoid arthritis (RA), has its pharmacokinetic behavior under disease conditions largely unexplored.

Maximizing the environmental benefits of gas power development in China: A multidisciplinary modeling approach.

China, holding nearly half of the global coal-fired power capacity, must shift from its coal-centric energy system to meet climate and air quality goals. This study explores the optimal utilization of natural gas by evaluating the environmental and economic costs of gas- and coal-fired power using plant-level data and a multidisciplinary modeling approach. We find that gas power has substantially lower air pollution costs (0.

Early minimal residual disease eradication in light chain amyloidosis generates deeper and faster cardiac response.

Minimal residual disease (MRD) is of growing interest in light chain (AL) amyloidosis and is associated with higher rates of cardiac response. A new graded cardiac response criteria has been proposed for better assessment of cardiac improvement. We evaluated MRD status in 63 patients with cardiac AL amyloidosis using next generation flow cytometry (sensitivity ≥ 1*10) within four cycles after treatment initiation and cardiac response kinetics.

Injectable Salecan/hyaluronic acid-based hydrogels with antibacterial, rapid self-healing, pH-responsive and controllable drug release capability for infected wound repair.

Designing materials for wound dressings with superior therapeutic benefits, self-healing and injectable characteristics is important in clinical practice. Herein, a new self-healing injectable hydrogel was prepared via thermal treatment and dynamic Schiff base reaction by mixing oxidized hyaluronic acid (OHA) and hydrazided Salecan (Sal-ADH). The versatility of the wound dressing was confirmed by studying the inherent rheological properties, high swelling rate, sustained-release behavior of the drug, pH/hyaluronidase-dependent biodegradation, in vitro antimicrobial as well as in vivo wound healing performance.

Protein Scaffold-Mediated Multi-Enzyme Self-Assembly and Ordered Co-Immobilization of Flavin-Dependent Halogenase-Coenzyme Cycle System for Efficient Biosynthesis of 6-Cl-L-Trp.

Flavin-dependent halogenase (FDH) is highly prized in pharmaceutical and chemical industries for its exceptional capacity to produce halogenated aromatic compounds with precise regioselectivity. This study has devised a multi-enzyme self-assembly strategy to construct an effective and reliable in vitro coenzyme cycling system tailored for FDHs. Initially, tri-enzyme self-assembling nanoclusters (TESNCs) were developed, comprising glucose dehydrogenase (GDH), flavin reductase (FR) and FDH.