Publications by authors named "Prerna Paliwal"

Over the past years, the development of experimental techniques for the coherent manipulation and control of isolated quantum systems has made impressive progress. Such 'quantum-logic' methods are also highly attractive in a chemical context in view of unravelling and controlling the quantum dynamics of molecular collisions and chemical reactions. Quantum technologies have the potential to transform the way chemical dynamics are investigated - by providing highly sensitive methods for state readout and spectroscopy, by opening up new pathways for the quantum-state preparation of molecules and by enabling an improved control of their microscopic behavior on the single-particle level.

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Article Synopsis
  • Asymmetric spectral line shapes indicate interference between a quasi-bound state and a continuum of states, commonly seen in multichannel systems like photoionization or molecular scattering.
  • The research demonstrates that by examining how the angular dependence of the cross section changes, asymmetric Fano profiles can be detected even in single channel shape resonance scenarios.
  • Experiments on elastic collisions between metastable helium and deuterium reveal a peak shift in the resonance profile with detection angle, aligning well with theoretical predictions, and allow for the extraction of the relative phase that causes these characteristic profiles.
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Scattering resonances play a central role in collision processes in physics and chemistry. They help build an intuitive understanding of the collision dynamics due to the spatial localization of the scattering wavefunctions. For resonances that are localized in the reaction region, located at short separation behind the centrifugal barrier, sharp peaks in the reaction rates are the characteristic signature, observed recently with state-of-the-art experiments in low-energy collisions.

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Decay of bound states due to coupling with free particle states is a general phenomenon occurring at energy scales from MeV in nuclear physics to peV in ultracold atomic gases. Such a coupling gives rise to Fano-Feshbach resonances (FFR) that have become key to understanding and controlling interactions-in ultracold atomic gases, but also between quasiparticles, such as microcavity polaritons. Their energy positions were shown to follow quantum chaotic statistics.

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