Universality class of the special adsorption point of two-dimensional lattice polymers.

In recent work [Rodrigues et al., Phys. Rev.

Adsorption of two-dimensional polymers with two- and three-body self-interactions.

Using extensive Monte Carlo simulations, we investigate the surface adsorption of self-avoiding trails on the triangular lattice with two- and three-body on-site monomer-monomer interactions. In the parameter space of two-body, three-body, and surface interaction strengths, the phase diagram displays four phases: swollen (coil), globule, crystal, and adsorbed. For small values of the surface interaction, we confirm the presence of swollen, globule, and crystal bulk phases.

Adsorption of interacting self-avoiding trails in two dimensions.

We investigate the surface adsorption transition of interacting self-avoiding square lattice trails onto a straight boundary line. The character of this adsorption transition depends on the strength of the bulk interaction, which induces a collapse transition of the trails from a swollen to a collapsed phase, separated by a critical state. If the trail is in the critical state, the universality class of the adsorption transition changes; this is known as the special adsorption point.

Phase transitions in solvent-dependent polymer adsorption in three dimensions.

We consider the phase diagram of self-avoiding walks (SAWs) on the simple cubic lattice subject to surface and bulk interactions, modeling an adsorbing surface and variable solvent quality for a polymer in dilute solution, respectively. We simulate SAWs at specific interaction strengths to focus on locating certain transitions and their critical behavior. By collating these new results with previous results we sketch the complete phase diagram and show how the adsorption transition is affected by changing the bulk interaction strength.

Universality of crossover scaling for the adsorption transition of lattice polymers.

Recently, it has been proposed that the adsorption transition for a single polymer in dilute solution, modeled by lattice walks in three dimensions, is not universal with respect to intermonomer interactions. Moreover, it has been conjectured that key critical exponents ϕ, measuring the growth of the contacts with the surface at the adsorption point, and 1/δ, which measures the finite-size shift of the critical temperature, are not the same. However, applying standard scaling arguments the two key critical exponents should rather be identical, hence pointing to a potential breakdown of these standard scaling arguments.

Grand-canonical solution of semiflexible self-avoiding trails on the Bethe lattice.

We consider a model of semiflexible interacting self-avoiding trails (sISATs) on a lattice, where the walks are constrained to visit each lattice edge at most once. Such models have been studied as an alternative to the self-attracting self-avoiding walks (SASAWs) to investigate the collapse transition of polymers, with the attractive interactions being on site as opposed to nearest-neighbor interactions in SASAWs. The grand-canonical version of the sISAT model is solved on a four-coordinated Bethe lattice, and four phases appear: non-polymerized (NP), regular polymerized (P), dense polymerized (DP), and anisotropic nematic (AN), the last one present in the phase diagram only for sufficiently stiff chains.

Weighting of topologically different interactions in a model of two-dimensional polymer collapse.

We study by computer simulation a recently introduced generalized model of self-interacting self-avoiding trails on the square lattice that distinguishes two topologically different types of self-interaction: namely, crossings where the trail passes across itself and collisions where the lattice path visits the same site without crossing. This model generalizes the canonical interacting self-avoiding trail model of polymer collapse, which has a strongly divergent specific heat at its transition point. We confirm the recent prediction that the asymmetry does not affect the universality class for a range of asymmetry.

Anomalous critical behavior in the polymer collapse transition of three-dimensional lattice trails.

Trails (bond-avoiding walks) provide an alternative lattice model of polymers to self-avoiding walks, and adding self-interaction at multiply visited sites gives a model of polymer collapse. Recently a two-dimensional model (triangular lattice) where doubly and triply visited sites are given different weights was shown to display a rich phase diagram with first- and second-order collapse separated by a multicritical point. A kinetic growth process of trails (KGTs) was conjectured to map precisely to this multicritical point.

Identification of a polymer growth process with an equilibrium multicritical collapse phase transition: the meeting point of swollen, collapsed, and crystalline polymers.

We have investigated a polymer growth process on the triangular lattice where the configurations produced are self-avoiding trails. We show that the scaling behavior of this process is similar to the analogous process on the square lattice. However, while the square lattice process maps to the collapse transition of the canonical interacting self-avoiding trail (ISAT) model on that lattice, the process on the triangular lattice model does not map to the canonical equilibrium model.

Lattice model for parallel and orthogonal beta sheets using hydrogenlike bonding.

We present results for a lattice model of polymers where the type of beta sheet formation can be controlled by different types of hydrogen bonds depending on the relative orientation of close segments of the polymer. Tuning these different interaction strengths leads to low-temperature structures with different types of orientational order. We perform simulations of this model and so present the phase diagram, ascertaining the nature of the phases and the order of the transitions between these phases.

Self-avoiding random walk with multiple site weightings and restrictions.

We introduce a new class of models for polymer collapse, given by random walks on regular lattices which are weighted according to multiple site visits. A Boltzmann weight omegal is assigned to each (l+1)-fold visited lattice site, and self-avoidance is incorporated by restricting to a maximal number K of visits to any site via setting omegal=0 for l>or=K. In this Letter we study this model on the square and simple cubic lattices for the case K=3.

Flat histogram version of the pruned and enriched Rosenbluth method.

In this Letter we present a flat histogram algorithm based on the pruned and enriched Rosenbluth method. This algorithm incorporates in a straightforward manner microcanonical reweighting techniques, leading to "flat histogram" sampling in the chosen parameter space. As an additional benefit, our algorithm is completely parameter free and, hence, easy to implement.

Scaling near the theta point for isolated polymers in solution.

Recently questions have been raised as to the conclusions that can be drawn from currently proposed scaling theory for a single polymer in various types of solution in two and three dimensions. Here we summarize the crossover theory predicted for low dimensions and clarify the scaling arguments that relate thermal exponents for quantities on approaching the theta point from low temperatures to those associated with the asymptotics in polymer length at the theta point itself.

Four-dimensional polymer collapse: pseudo-first-order transition in interacting self-avoiding walks.

In an earlier work we provided the first evidence that the collapse, or coil-globule transition of an isolated polymer in solution can be seen in a four-dimensional model. Here we investigate, via Monte Carlo simulations, the canonical lattice model of polymer collapse, namely, interacting self-avoiding walks, to show that it not only has a distinct collapse transition at finite temperature but that for any finite polymer length this collapse has many characteristics of a rounded first-order phase transition. However, we also show that there exists a "straight theta point" where the polymer behaves in a simple Gaussian manner (which is a critical state), to which these finite-size transition temperatures approach as the polymer length is increased.

Viscoelastic depinning of driven systems: mean-field plastic scallops.

We have investigated the mean-field dynamics of an overdamped viscoelastic medium driven through quenched disorder. The model allows for the coexistence of pinned and sliding regions and can exhibit continuous elastic depinning or first-order hysteretic depinning. Numerical simulations indicate mean-field instabilities that correspond to macroscopic stick-slip events and lead to premature switching.