Ultra-sensitive detection and scavenging of arsenic ions and ciprofloxacin using 3D multipurpose hemicellulose based aerogel: Adsorption mechanism and RSM optimization.

Trace level detection and efficient removal of arsenite ions (As (III)) and ciprofloxacin (CPR) antibiotic was achieved using hemicellulose based ratiometric fluorescent aerogel. Hemicellulose derived from rice straw was oxidised to dialdehyde hemicellulose followed by crosslinking using chitosan via a Schiff base reaction (C = N) yielding a highly porous 3D fluorescent aerogel (CS@DAHCA). Various factors governing adsorption were analyzed by applying response surface methodology (RSM) approach.

Highly fluorescent composite of boron nitride quantum dots decorated on cellulose nanofibers for detection and removal of Hg(II) ions from waste water.

To address the challenge of heavy-metal ions in wastewater, boron nitride quantum dots (BNQDs) were synthesized in-situ on rice straw derived cellulose nanofibers (CNFs) as substrate. The composite system exhibited strong hydrophilic-hydrophobic interactions, as corroborated by FTIR, integrated the extraordinary fluorescence properties of BNQDs with fibrous-network of CNFs (BNQD@CNFs) yielding a surface of 35.147 m g of luminescent fibers.

Bioremediation of multifarious pollutants using laccase immobilized on magnetized and carbonyldiimidazole-functionalized cellulose nanofibers.

An easily recyclable biocatalyst (Lac@CDI-MCNFs) was synthesized by immobilizing laccase on rice straw-derived carbonyldiimidazole mediated magnetized cellulose nanofibers (MCNFs). Lac@CDI-MCNFs were utilized for bioremediation of cefixime antibiotic (CT), carbofuran pesticide (CF) and safranin O dye (SO) via oxidation-reduction reactions in wastewater. MCNFs provided enhanced pH, temperature and storage stability to laccase and allowed reusability for up to 25 cycles with mere 20 % decline in efficacy.

Sensing and annihilation of ultra-trace level arsenic (III) using fluoranthene decorated fluorescent nanofibrous cellulose probe.

Besides presence of heavy metals, especially arsenic in water bodies, northern India is striving to obliterate crop residue, which is otherwise burnt to make the fields ready for subsequent crop, causing acute air pollution. Through this study, an effort has been made to utilize wheat-straw cellulose to develop inexpensive and efficacious sensing cum annihilation system for deleterious arsenite ions As(III) in water by grafting a novel fluorophore, 3-bromofluoranthene on cellulose (BF@CFs). BF@CFs were characterized for structural, morphological and thermal properties using FTIR, XRD, TGA, FESEM, EDS and TEM, which confirmed the successful insertion of fluoranthene molecule on cellulose while preserving its crystalline nanofibrous structure.

Diamidoximated cellulosic bioadsorbents from hemp stalks for elimination of uranium (VI) and textile waste in aqueous systems.

Selective abolition of hazardous U(VI) ions from nuclear power plants and removal of toxic colorants from textile industries pose great challenge. The work aims to develop cellulosic bioadsorbents from waste stalks of local weed, Cannabis sativa, commonly known as hemp. Cellulose nanofibers (PCFs) were chosen as substrates owing to their unique characteristics like surface hydroxyl groups, large surface to volume ratio and excellent mechanical properties.