Publications by authors named "Pravinkumar Selvam"

In this study, we present three different approaches for the colorimetric detection of Ni ions using a specifically designed benzothiazole-quinoline dyad (L) synthesized the Knoevenagel condensation reaction in high yield. The unique properties of L enable a rapid and selective response to Ni ions, making it an ideal probe for practical applications. The probe L shows a pale yellow color under normal conditions.

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Article Synopsis
  • The text discusses the synthesis and characterization of three new fluorescence probes derived from fluorenone azine, focusing on their structural properties and the methods used for their analysis.
  • These probes exhibit unique photophysical behaviors due to hydrogen bonding interactions that allow for processes like excited state intramolecular proton transfer (ESIPT) and twisted intramolecular charge transfer (TICT).
  • The study highlights the probes' potential applications in bioimaging and viscosity detection, specifically demonstrating that probe 3a is effective for measuring intercellular viscosity in a Caenorhabditis elegans model.
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The manuscript presents the synthesis of a new di-chromene Schiff base (COM-CH) by combining 7-(diethylamino)-2-oxo-2H-chromene-3-carbohydrazide and 4-oxo-4H-chromene-3-carbaldehyde, and its characterization using various analytical techniques. The probe COM-CH functional group contains a hard donor atom that selectively complexes with Th ions. This report investigated COM-CH's sensing ability towards Th chromogenic and fluorogenic methods in ACN: HO (8:2, v/v) with Th ions.

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Herein, an aggregation-induced emission (AIE) active Schiff base (NHS) was synthesized by condensing naphthalimide hydrazide with salicylaldehyde. The non-fluorescent solution of NHS in DMSO turned to emissive NHS upon increasing the HEPES fraction in DMSO from 70 to 95%. The UV-Vis absorption and DLS studies supported the self-aggregation of NHS that restricted the intramolecular rotation and activated the ESIPT process.

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In recent years, Ru(II) complexes have gained high importance in medicinal chemistry due to their significant anti-cancer activities, which are directly related to their DNA binding ability. In this report, the chemistry and cytotoxicity of two new Ru(II) complexes containing imidazole pyridine (Ru-1) and imidazole quinoline (Ru-2) have been studied. The prepared compounds were characterized using infrared (IR), nuclear magnetic resonance (NMR), mass spectrometry (MS), isothermal titration calorimetry (ITC), UV-Vis, and fluorescence spectral techniques.

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