In this study, we present three different approaches for the colorimetric detection of Ni ions using a specifically designed benzothiazole-quinoline dyad (L) synthesized the Knoevenagel condensation reaction in high yield. The unique properties of L enable a rapid and selective response to Ni ions, making it an ideal probe for practical applications. The probe L shows a pale yellow color under normal conditions.
View Article and Find Full Text PDFThe manuscript presents the synthesis of a new di-chromene Schiff base (COM-CH) by combining 7-(diethylamino)-2-oxo-2H-chromene-3-carbohydrazide and 4-oxo-4H-chromene-3-carbaldehyde, and its characterization using various analytical techniques. The probe COM-CH functional group contains a hard donor atom that selectively complexes with Th ions. This report investigated COM-CH's sensing ability towards Th chromogenic and fluorogenic methods in ACN: HO (8:2, v/v) with Th ions.
View Article and Find Full Text PDFHerein, an aggregation-induced emission (AIE) active Schiff base (NHS) was synthesized by condensing naphthalimide hydrazide with salicylaldehyde. The non-fluorescent solution of NHS in DMSO turned to emissive NHS upon increasing the HEPES fraction in DMSO from 70 to 95%. The UV-Vis absorption and DLS studies supported the self-aggregation of NHS that restricted the intramolecular rotation and activated the ESIPT process.
View Article and Find Full Text PDFIn recent years, Ru(II) complexes have gained high importance in medicinal chemistry due to their significant anti-cancer activities, which are directly related to their DNA binding ability. In this report, the chemistry and cytotoxicity of two new Ru(II) complexes containing imidazole pyridine (Ru-1) and imidazole quinoline (Ru-2) have been studied. The prepared compounds were characterized using infrared (IR), nuclear magnetic resonance (NMR), mass spectrometry (MS), isothermal titration calorimetry (ITC), UV-Vis, and fluorescence spectral techniques.
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