Toward a Cenozoic history of atmospheric CO.

The geological record encodes the relationship between climate and atmospheric carbon dioxide (CO) over long and short timescales, as well as potential drivers of evolutionary transitions. However, reconstructing CO beyond direct measurements requires the use of paleoproxies and herein lies the challenge, as proxies differ in their assumptions, degree of understanding, and even reconstructed values. In this study, we critically evaluated, categorized, and integrated available proxies to create a high-fidelity and transparently constructed atmospheric CO record spanning the past 66 million years.

Pleistocene drivers of Northwest African hydroclimate and vegetation.

Savanna ecosystems were the landscapes for human evolution and are vital to modern Sub-Saharan African food security, yet the fundamental drivers of climate and ecology in these ecosystems remain unclear. Here we generate plant-wax isotope and dust flux records to explore the mechanistic drivers of the Northwest African monsoon, and to assess ecosystem responses to changes in monsoon rainfall and atmospheric pCO. We show that monsoon rainfall is controlled by low-latitude insolation gradients and that while increases in precipitation are associated with expansion of grasslands into desert landscapes, changes in pCO predominantly drive the C/C composition of savanna ecosystems.

Relationship between individual chamber and whole shell Mg/Ca ratios in Trilobatus sacculifer and implications for individual foraminifera palaeoceanographic reconstructions.

Precisely targeted measurements of trace elements using laser ablation inductively coupled plasma mass spectrometry (LA-ICPMS) reveal inter-chamber heterogeneities in specimens of the planktic foraminifer Trilobatus (Globigerinoides) sacculifer. We find that Mg/Ca ratios in the final growth chamber are generally lower compared to previous growth chambers, but final chamber Mg/Ca is elevated in one of thirteen sample intervals. Differences in distributions of Mg/Ca values from separate growth chambers are observed, occurring most often at lower Mg/Ca values, suggesting that single-chamber measurements may not be reflective of the specimen's integrated Mg/Ca.

Modulation of late Pleistocene ENSO strength by the tropical Pacific thermocline.

The El Niño Southern Oscillation (ENSO) is highly dependent on coupled atmosphere-ocean interactions and feedbacks, suggesting a tight relationship between ENSO strength and background climate conditions. However, the extent to which background climate state determines ENSO behavior remains in question. Here we present reconstructions of total variability and El Niño amplitude from individual foraminifera distributions at discrete time intervals over the past ~285,000 years across varying atmospheric CO levels, global ice volume and sea level, and orbital insolation forcing.

Earthquake slip surfaces identified by biomarker thermal maturity within the 2011 Tohoku-Oki earthquake fault zone.

Extreme slip at shallow depths on subduction zone faults is a primary contributor to tsunami generation by earthquakes. Improving earthquake and tsunami risk assessment requires understanding the material and structural conditions that favor earthquake propagation to the trench. We use new biomarker thermal maturity indicators to identify seismic faults in drill core recovered from the Japan Trench subduction zone, which hosted 50 m of shallow slip during the M9.

Picomolar-scale compound-specific isotope analyses.

Rationale: We report modifications to compound-specific isotope analyses (CSIA) to enable high-precision isotopic analyses of picomoles of carbon for intact organic molecules. This sample size is two orders of magnitude below the amounts required for commercial systems. The greatly enhanced sensitivity of this system expands molecular isotope studies and applications previously prohibited by low concentrations and small samples.

Northward extent of East Asian monsoon covaries with intensity on orbital and millennial timescales.

The magnitude, rate, and extent of past and future East Asian monsoon (EAM) rainfall fluctuations remain unresolved. Here, late Pleistocene-Holocene EAM rainfall intensity is reconstructed using a well-dated northeastern China closed-basin lake area record located at the modern northwestern fringe of the EAM. The EAM intensity and northern extent alternated rapidly between wet and dry periods on time scales of centuries.

Changes in northeast African hydrology and vegetation associated with Pliocene-Pleistocene sapropel cycles.

East African climate change since the Late Miocene consisted of persistent shorter-term, orbital-scale wet-dry cycles superimposed upon a long-term trend towards more open, grassy landscapes. Either or both of these modes of palaeoclimate variability may have influenced East African mammalian evolution, yet the interrelationship between these secular and orbital palaeoclimate signals remains poorly understood. Here, we explore whether the long-term secular climate change was also accompanied by significant changes at the orbital-scale.

A Pleistocene palaeovegetation record from plant wax biomarkers from the Nachukui Formation, West Turkana, Kenya.

Reconstructing vegetation at hominin fossil sites provides us critical information about hominin palaeoenvironments and the potential role of climate in their evolution. Here we reconstruct vegetation from carbon isotopes of plant wax biomarkers in sediments of the Nachukui Formation in the Turkana Basin. Plant wax biomarkers were extracted from samples from a wide range of lithologies that include fluvial-lacustrine sediments and palaeosols, and therefore provide a record of vegetation from diverse depositional environments.

Neogene biomarker record of vegetation change in eastern Africa.

The evolution of C4 grassland ecosystems in eastern Africa has been intensely studied because of the potential influence of vegetation on mammalian evolution, including that of our own lineage, hominins. Although a handful of sparse vegetation records exists from middle and early Miocene terrestrial fossil sites, there is no comprehensive record of vegetation through the Neogene. Here we present a vegetation record spanning the Neogene and Quaternary Periods that documents the appearance and subsequent expansion of C4 grasslands in eastern Africa.

Reduced El Niño-Southern Oscillation during the Last Glacial Maximum.

El Niño-Southern Oscillation (ENSO) is a major source of global interannual variability, but its response to climate change is uncertain. Paleoclimate records from the Last Glacial Maximum (LGM) provide insight into ENSO behavior when global boundary conditions (ice sheet extent, atmospheric partial pressure of CO2) were different from those today. In this work, we reconstruct LGM temperature variability at equatorial Pacific sites using measurements of individual planktonic foraminifera shells.

Synchronous interhemispheric Holocene climate trends in the tropical Andes.

Holocene variations of tropical moisture balance have been ascribed to orbitally forced changes in solar insolation. If this model is correct, millennial-scale climate evolution should be antiphased between the northern and southern hemispheres, producing humid intervals in one hemisphere matched to aridity in the other. Here we show that Holocene climate trends were largely synchronous and in the same direction in the northern and southern hemisphere outer-tropical Andes, providing little support for the dominant role of insolation forcing in these regions.

Drought variability in the Pacific Northwest from a 6,000-yr lake sediment record.

We present a 6,000-yr record of changing water balance in the Pacific Northwest inferred from measurements of carbonate δ(18)O and grayscale on a sediment core collected from Castor Lake, Washington. This subdecadally resolved drought record tracks the 1,500-yr tree-ring-based Palmer Drought Severity Index reconstructions of Cook et al. [Cook ER, Woodhouse CA, Eakin CM, Meko DM, Stahle DW (2004) Science 306:1015-1018] in the Pacific Northwest and extends our knowledge back to 6,000 yr B.

Measurement of 13C and 15N isotopic composition on nanomolar quantities of C and N.

We describe a trapping and chromatography system that cryogenically removes CO(2) and N(2) generated from sample combustion in an elemental analyzer (EA) and introduces these gases into a low-flow helium carrier stream for isotopic analysis. The sample size required for measurement by this system (termed nano-EA/IRMS) is almost 3 orders of magnitude less than conventional EA analyses and fills an important niche in the range of analytical isotopic methods. Only 25 nmol of N and 41 nmol of C are needed to achieve 1.