Publications by authors named "Prasanta K Guha"

Herein, we fabricated nanoscale 2D CeOsheet structure to develop a stable resistive gas sensor for detection of low concentration (ppm) level formaldehyde vapors. The fabricated CeOnanosheets (NSs) showed an optical band gap of 3.53 eV and cubic fluorite crystal structure with enriched defect states.

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We report a study to improve the ternary oxide NiVO's electrochemical energy storage capabilities through correct surfactanization during hydrothermal synthesis. In this study, NiVOnanomaterials were synthesized in three different forms: one with a cationic surfactant (CTAB), one with an anionic surfactant (SLS), and one without any surfactant. FESEM study reveals that all the synthesized NiVOnanomaterials had a small stone-like morphology.

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The work presents the identification of fish adulteration and quality assessment by incorporating a chemiresistive gas sensor and machine learning (ML) techniques. Highly sensitive SnO nanopetals were synthesized chemically and integrated with interdigitated electrodes to fabricate a sensor device. The sensor was calibrated with formaldehyde (37 %) with a theoretical detection limit of 75 ppb and further utilized to detect the vapors emitted from fresh and formalin-adulterated fish.

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This work reports an, one-step hydrothermal preparation procedure of a binder-free electrode growth of NiSeon nickel foam (NiSe/NF) with a rod-like structure. NiSeis an enveloped transition metal chalcogenides of formula MX(where 2 ≤≤ 8, M is a transition metal and X is chalcogen) of the nickel selenide family. The NiSe/NF electrode described here demonstrates an exceptional lifetime of 81% capacitance retention over 20000 cycles and a high specific capacitance of 473.

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The selective and rapid detection of trace amounts of highly toxic chemical warfare agents has become imperative for efficiently using military and civilian defense. Metal-organic frameworks (MOFs) are a class of inorganic-organic hybrid porous material that could be potential next-generation toxic gas sensors. However, the growth of a MOF thin film for efficiently utilizing the material properties for fabricating electronic devices has been challenging.

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Article Synopsis
  • β-FeSi was doped with Boron through a cost-effective chemical reduction process at 800 °C, which resulted in observable changes in material properties as seen in XRD and Raman spectrometry.
  • Hall effect experiments showed that the doped material exhibits p-type conductivity, with various contributions from shallow and deep acceptor levels depending on temperature and doping levels.
  • Density functional theory (DFT) calculations confirmed the findings, illustrating how Boron doping and the presence of defects influence the electronic structure and enhance p-type characteristics in β-FeSi.
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Diagnosing heavy metals poisoning in human beings is of paramount importance. In this work, we present the design of a biocompatible FeNiO hierarchical nanostructure-based sensor for ultraselective detection of arsenate (As(V)) ions in biological environments (e.g.

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Selective detection of gases has been a major concern among metal-oxide based chemiresistive gas sensors due to their intrinsic cross-sensitivity. In this endeavor, we report integration of single metal-oxide based chemiresistive sensor with different soft computing tools to obtain perfect recognition of tested analyte molecules by means of signal processing, feature extraction and machine learning. The fabricated sensor device consists of SnO hollow-spheres as the sensing material, which was synthesized chemically.

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Rapidly changing demand on energy storage systems makes it essential to redesign the device architecture and materials required to fabricate the devices. It is crucial to introduce capacitive behaviour in a conventional energy storage device (batteries) to improve the lifetime and power efficiency of the hole energy storage system. The charge storing nature of electrode material primarily depends on particle size, grain size, the electrode's chemical structure, and effective diffusion lengths for electrolytes within the electrode.

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  • Two-dimensional layered materials like MoS and WS used in gas sensors have low sensitivity and selectivity, which limits their effectiveness.
  • A new substitutional doping technique using noble metals such as gold has been shown to significantly enhance the performance of MoS, as evidenced by material characterization methods.
  • Gold-doped MoS exhibited a much higher sensitivity to ammonia, with a response of 150% for a 500 ppm concentration, while platinum-doped MoS showed an impressive response to humidity, highlighting the advantages of noble metal doping in improving sensor responses.
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Semiconducting metal oxide-based gas sensors have inadequate selectivity as they are responsive toward a variety of gases. Here, we report the implementation of gas sensing kinetic analysis of the sensor to identify the tested volatile organic compounds (VOCs) (2-propanol, formaldehyde, methanol, and toluene) precisely. A single chemiresistive sensor was employed having tin oxide-based hollow spheres as the sensing material, which were obtained by chemical synthesis.

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Metal oxide resistive gas sensors suffer from poor selectivity that restricts their practical applicability. Conventional sensor arrays are used to improve selectivity which increased the system complexity. Here, we have proposed a novel NiO/ZnO-based p-n junction single-diode device for selective sensing of several volatile organic compounds (VOCs) simultaneously by tuning bias voltage.

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A forest like 3D carbon structure formed by reduced graphene oxide (RGO) was prepared to use as an electrode material for a highly power efficient supercapacitor. To improve the specific energy of the electrode, pore like defects were incorporated on the RGO forests by atomic oxygen etching, during the UV-ozone treatment. The modified surface helps to increase the net capacitance by permitting the electrolyte to the inner core of the active material and improving the minimal quantum capacitance.

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  • Researchers developed a low-power humidity sensor using platinum nanoparticles on molybdenum disulphide nanoflakes as the sensing material.
  • The fabrication involved a novel reduction technique for creating Pt/MoS composites, confirmed by multiple characterization methods including electron microscopy and spectroscopy.
  • The sensor achieved a remarkable response rate of approximately 4000 times at 85% relative humidity, with stable performance and good response times over several months.
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WS nanosheets have been synthesized by ultrasonication in a binary mixture of acetone and 2-propanol, with a volume ratio of 80:20. Hansen solubility parameters were taken into consideration as part of the process. These nanosheets have been characterized by electron microscopy, atomic force microscopy, and x-ray diffraction, along with spectroscopy such as ultraviolet-visible spectroscopy, Raman spectroscopy, and x-ray photoelectron spectroscopy.

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It remains a challenge to find a suitable gas sensing material that shows a high response and shows selectivity towards various gases simultaneously. Here, we report a mixed metal oxide WO3-SnO2 nanostructured material synthesized in situ by a simple, single-step, one-pot hydrothermal method at 200 °C in 12 h, and demonstrate its superior sensing behavior towards volatile organic compounds (VOCs) such as ammonia, ethanol and acetone. SnO2 nanoparticles with controlled size and density were uniformly grown on WO3 nanoplates by varying the tin precursor.

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Chemically reduced graphene oxide (RGO) has recently attracted growing interest in the area of chemical sensors because of its high electrical conductivity and chemically active defect sites. This paper reports the synthesis of chemically reduced GO using NaBH4 and its performance for ammonia detection at room temperature. The sensing layer was synthesized on a ceramic substrate containing platinum electrodes.

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Here we demonstrate a novel technique to grow carbon nanotubes (CNTs) on addressable localized areas, at wafer level, on a fully processed CMOS substrate. The CNTs were grown using tungsten micro-heaters (local growth technique) at elevated temperature on wafer scale by connecting adjacent micro-heaters through metal tracks in the scribe lane. The electrical and optical characterization show that the CNTs are identical and reproducible.

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