Slip Flow in Hydrophilic Nanopores of Silica Colloidal Crystals.

Slip flow, a fluid flow enhanced in comparison to that calculated using continuum equations, has been reported for many nanopores, mostly those with hydrophobic surfaces. We investigated the flow of water, hexane, and methanol through hydrophilic nanopores in silica colloidal crystals. Three silica sphere sizes were used to prepare the crystals: 150 ± 30, 500 ± 40, and 1500 ± 100 nm.

Flow of long chain hydrocarbons through carbon nanotubes (CNTs).

The pressure-driven flow of long-chain hydrocarbons in nanosized pores is important in energy, environmental, biological, and pharmaceutical applications. This paper examines the flow of hexane, heptane, and decane in carbon nanotubes (CNTs) of pore diameters 1-8 nm using molecular dynamic simulations. Enhancement of water flow in CNTs in comparison to rates predicted by continuum models has been well established in the literature.