GWAS for the identification of introgressed candidate genes of with increased branching numbers in backcross lines of the allohexaploid .

Plant architecture is a crucial determinant of crop yield. The number of primary (PB) and secondary branches (SB) is particularly significant in shaping the architecture of Indian mustard. In this study, we analyzed a panel of 86 backcross introgression lines (BCILs) derived from the first stable allohexaploid Brassicas with 170 genome-specific SSR markers to identify associated markers with higher PB and SB through association mapping.

Sensor based precise nitrogen application augmented productivity and profitability of mustard (Brassica juncea L.).

Unremitting decline in crop productivity and nutrient recovery are resulted due to dearth of need based fertilizer recommendation over blanket application apart from nitrogen pollution in several means. An advance nutrient management tactic, GreenSeeker (GS) has developed and used in many field crops following the principle of four "R" (right source, right amount at right time, and place) nutrients stewardship technologies. But no studies have been conducted for evaluation of GS in mustard for improving productivity, profitability and nutrient use efficiency (NUE) while minimizing environmental risks.

Rejuvenation of dearomative cycloaddition reactions visible light energy transfer catalysis.

Dearomative cycloaddition is a powerful technique to access sp-rich three-dimensional structural motifs from simple flat, aromatic feedstock. The building-up of unprecedentedly diverse polycyclic scaffolds with increased saturation and stereochemical information having various applications ranging from pharmaceutical to material sciences, is an essential goal in organic chemistry. However, the requirement of large energy inputs to disrupt the aromaticity of an arene moiety necessitates harsh reaction conditions for ground state dearomative cycloaddition.

Comparative toxicity assessment of individual, binary and ternary mixtures of SiO, FeO, and ZnO nanoparticles in freshwater microalgae, Scenedesmus obliquus: Exploring the role of dissolved ions.

Metal oxide nanoparticles (NPs) are considered among the most prevalent engineered nanomaterials. To have a deeper understanding of the mode of action of multiple metal oxide nanoparticles in mixtures, we have used a unicellular freshwater microalga Scenedesmus obliquus as a model organism. The toxicity of silicon dioxide (SiO), iron oxide (FeO), and zinc oxide (ZnO) NPs was studied individually as well as in their binary (SiO + FeO FeO + ZnO, and ZnO + SiO) and ternary (SiO + FeO + ZnO) combinations.

Fungal effectors versus defense-related genes of and the status of resistant transgenics against fungal pathogens.

Oilseed brassica has become instrumental in securing global food and nutritional security. , colloquially known as Indian mustard, is cultivated across tropics and subtropics including Indian subcontinent. The production of Indian mustard is severely hampered by fungal pathogens which necessitates human interventions.

Comparative ecotoxicity of graphene, functionalized multi-walled CNTs, and their mixture in freshwater microalgae, Scenedesmus obliquus: analyzing the role of oxidative stress.

Due to their remarkable properties, the applications of carbon-based nanomaterials (CNMs) such as graphene and functionalized multi-walled carbon nanotubes (f-MWCNTs) are increasing. These CNMs can enter the freshwater environment via numerous routes, potentially exposing various organisms. The current study assesses the effects of graphene, f-MWCNTs, and their binary mixture on the freshwater algal species Scenedesmus obliquus.

Draft genome sequencing and secretome profiling of Sclerotinia sclerotiorum revealed effector repertoire diversity and allied broad-host range necrotrophy.

White mold commonly known as Sclerotinia sclerotiorum causes stem rot disease and has emerged as one of the major fungal pathogens of oilseed Brassica across the world. In the present study, consistently virulent S. sclerotiorum isolate "ESR-01" was sequenced and an assembly size of ~ 41 Mb with 328 scaffolds having N50 of 447,128 was obtained.

Intermolecular dearomative [4 + 2] cycloaddition of naphthalenes visible-light energy-transfer-catalysis.

The dearomative cycloaddition reaction serves as a blueprint for creating sp-rich three-dimensional molecular topology from flat-aromatic compounds. However, severe reactivity and selectivity issues make this process arduous. Herein, we describe visible-light energy-transfer catalysis for the intermolecular dearomative [4 + 2] cycloaddition reaction of feedstock naphthalene molecules with vinyl benzenes.

Development of genome-specific SSR markers for the identification of introgressed segments of in the background.

Unlabelled: L. (white mustard) is recognized for carrying host resistance against several biotic stresses including, , which is responsible for blight disease in cultivated Brassica. However, another cultivated has a dearth for genetic resistance for these stresses due to its narrow genetic base.

Dicarbofunctionalizations of an Unactivated Alkene via Photoredox/Nickel Dual Catalysis.

1,2-Dicarbofunctionalization of unactivated olefin has been reported under photoredox/nickel dual catalysis. The mildness of the visible-light-mediated reaction allows the use of various alkyl and aryl electrophiles with several sensitive functional groups. The protocol was equally applied for late-stage diversification of drugs and biologically active molecules.

Enantioselective C-H bond functionalization of aromatic ketones with 1,6-enynes photoredox/cobalt dual catalysis.

An enantioselective -C(sp)-H functionalization of ketones with 1,6-enynes is demonstrated photoredox/cobalt dual catalysis. The method exhibits high yields, functional group tolerance, and selectivity. Mechanistic studies suggested the operation of visible-light mediated low-valent cobalt complex generation, intramolecular cyclization, -C-H bond insertion, and reductive elimination as the key mechanistic steps.

2,4,6-trinitrotoluene (TNT) degradation by Indiicoccus explosivorum (S5-TSA-19).

2,4,6-trinitrotoluene (TNT), a nitro-aromatic explosive commonly used for defense and several non-violent applications is contributing to serious environmental pollution problems including human health. The current study investigated the remediation potential of a native soil isolate, i.e.

Nano-SiO transport and retention in saturated porous medium: Influence of pH, ionic strength, and natural organics.

Nano silica (nSiO), induces potential harmful effects on the living environment and human health. It is well established that SiO facilitates the co-transport of a variety of other contaminants, including heavy metals and pesticides. The current study focused on the systematic evaluation of the effects of multiple physicochemical parameters such as pH (5, 7, and 9), ionic strength (10, 50, and 100 mM), and humic acid (0.

Recent Development of Bis-Cyclometalated Chiral-at-Iridium and Rhodium Complexes for Asymmetric Catalysis.

The field of asymmetric catalysis has been developing to access synthetically efficacious chiral molecules from the last century. Although there are many sustainable ways to produce nonracemic molecules, simplified and unique methodologies are always appreciated. In the recent developments of asymmetric catalysis, chiral-at-metal Lewis acid catalysis has been recognized as an attractive strategy.

Conceptualizing a novel Hybrid Decontamination System (HDS) based on UV/HO treatment for the enhanced decontamination and reuse of N95 FFRs.

The ongoing Pandemic of COVID-19 caused by Severe Acute Respiratory Syndrome Coronavirus 2 (SARS-CoV-2) has severely stressed the worldwide healthcare system and has created dangerous shortages of personal protective equipment (PPE) including N95 filtering facepiece respirators (FFRs). Even though suppliers struggled to meet global demand for N95 masks at an unprecedented level, a shortage of FFR appears as a significant factor in the transmission of the disease to frontline workers. CDC, USA has mentioned that FFR decontamination and reuse may be necessary during times of shortage to ensure guaranteed availability.

Cooperative Lewis Acid Catalysis for the Enantioselective C(sp)-H Bond Functionalizations of 2-Alkyl Azaarenes.

Herein, we describe the enantioselective C(sp)-H bond functionalizations of 2-alkyl azaarenes using a cooperative dual Lewis acid catalysis. An achiral Lewis acid activates the unactivated azaarene partner without the need for a strong base. Orthogonally, a chiral-at-metal Lewis acid catalyst enables LUMO lowering and induces chirality.

Discrimination of gallbladder stone employing Laser-Induced Breakdown Spectroscopy (LIBS) and Photoacoustic Spectroscopy (PAS).

Compositional analysis of gallstone samples has been carried out, using Laser-Induced Breakdown Spectroscopy (LIBS) and Photoacoustic Spectroscopy (PAS). Classification of gallstone has been made on the basis of intensities of the inorganic and organic constituents present in the LIBS spectra. A regression plot is drawn between LIBS spectral intensities of organic & inorganic elements and the stoichiometric ratio of Cholesterol, Bilirubin and Calcium Carbonate.

Restoring and preserving capacity of self-affirmation for well-being in Indian adults with non-clinical depressive tendencies.

Background: Although self-affirmation has been reported to enhance well-being and other positive life outcomes in normal adults, little is known about its capacity to restore and preserve well-being in adults with depressive tendencies. The current study attempts to expound the restoring and preserving capacity of self-affirmation for well-being in Indian adults with non-clinical depressive tendencies.

Participants And Procedure: The study used a sequential research design.

Current Status of the Disease-Resistant Gene(s)/QTLs, and Strategies for Improvement in .

is a major oilseed crop in tropical and subtropical countries, especially in south-east Asia like India, China, Bangladesh, and Pakistan. The widespread cultivation of genetically similar varieties tends to attract fungal pathogens which cause heavy yield losses in the absence of resistant sources. The conventional disease management techniques are often expensive, have limited efficacy, and cause additional harm to the environment.

Study on aerobic degradation of 2,4,6-trinitrotoluene (TNT) using Pseudarthrobacter chlorophenolicus collected from the contaminated site.

2,4,6-trinitrotoluene or TNT, a commonly used explosive, can pollute soil and groundwater. Conventional remediation practices for the TNT-contaminated sites are neither eco-friendly nor cost-effective. However, exploring bacteria to biodegrade TNT into environment-friendly compound(s) is an interesting area to explore.

Biodegradation of octogen and hexogen by strain WS2-R2A-65 under aerobic condition.

Biodegradation ability of a native bacterial species strain WS2-R2A-65, isolated from nitramine explosive-contaminated effluent, for octogen (HMX) and hexogen (RDX) under aerobic condition has been explored in this study. Scanning electron microscopy indicated that the isolate WS2-R2A-65 retained its morphology both in the presence and absence of HMX or RDX. During an incubation period of 20 days, the isolate cometabolically degraded 78 and 86% of HMX and RDX with initial concentrations 6 and 60 mg L, respectively.

Evaluation of non-injury inoculation technique for assessing Sclerotinia stem rot (Sclerotinia sclerotiorum) in oilseed Brassica.

The field assessment technique to evaluate the plants with a fungal phytopathogen for their tolerance to the disease is one of the crucial steps in dissecting their genetic control and in developing the resistant crop varieties. The objective behind this study was to develop and evaluate a field-based non-injury method of inoculation technique for Sclerotinia stem rot (SSR) in oilseed Brassica, caused by Sclerotinia sclerotiorum (Lib.) de Bary.