CuO nanorod arrays by gas-phase cation exchange for efficient photoelectrochemical water splitting.

CuO has been considered a promising candidate for photoelectrochemical water splitting electrodes owing to its suitable bandgap, favorable band alignments, and earth-abundant nature. In this paper, a novel gas-phase cation exchange method was developed to synthesize CuO nanorod arrays by using ZnO nanorod arrays as the template. ZnO nanorods were fully converted to CuO nanorods with aspect ratios of 10-20 at the temperature range from 350 to 600 °C.