Heavy metal contamination in marine fish from the Andaman sea: Influence of habitat and health risk assessment.

This study investigates Hg, Cd, Cu, Zn, and Pb concentrations in 324 fish samples from 43 species, including two cephalopod species, in the Andaman Sea. The fish were categorized into pelagic and demersal groups. The findings revealed average heavy metal concentrations in the order: Zn > Cu > Hg > Pb > Cd, with pelagic fish showing higher levels than demersal fish.

Optimizing cyanine dye properties for enhanced dyeing and inkjet printing on diverse Substrates: Photophysical and colorimetric investigations.

Cyanine-based cationic dyes with different substituents in the donor unit were easily synthesized using readily available starting materials. The prepared dye molecules were spectroscopically characterized by NMR, FT-IR, and HR-Mass, and their thermal stability was measured by TGA, DSC, and XRD. Based on the TGA and DSC measurements, it was concluded that all the dyes are thermally stable up to 200 °C.

Heavy metal bioaccumulation and risk assessment in fishery resources from the Gulf of Thailand.

The muscle tissues of 19 fish species, two crab species, and one shrimp species collected from the Gulf of Thailand (GoT) were analyzed to determine the levels of heavy metals, including Cu, Zn, Fe, Mn, Ni, Pb, Cd, and Hg. The results revealed that the mean concentrations of the heavy metals, in descending order, were Zn > Cu > Fe > Cd > Hg > Mn > Pb > Ni. Among the examined metals, zinc was found to be the most prevalent in fish tissues.

Occurrence of mcr genes and alterations in mgrB gene in intrinsic colistin- resistant Enterobacterales isolated from chicken meat samples.

Background: Tolerance of gram negative pathogens toward last resort colistin is mediated by mcr genes and alterations in chromosomal mgrB via modification of lipopolysaccharide through the PmrAB and PhoPQ component system. Proteus sp., Morganella sp.

A novel fluorophore with multichromic effect and its application in LED light for the volatile vapor detection.

Successfully designed and synthesized diaryl maleimide DAM, and their structure was confirmed by mass spectroscopy and NMR techniques. They investigated their photophysical properties, such as solvatochromic and the aggregation effect of AIE/ACQ on the water/DMF ratio, and other studies of solid-state mechanofluorochromic, such as grinding, exposure to solvent fumes, hydrostatic pressures, and vapochromic. Interestingly, the solvent methods gave very similar results in both the dissolving phase and the vapor phase.

Highly emissions of TPA-linear based pyrazine derivatives with different mechanochromic luminosity.

We designed the TPA-based linear pyrazine derivatives of PP-1 and PP-2, synthesized using the conventional Suzuki cross-linking reaction. It was followed by photophysical studies such as aprotic solvent (Haxene to DMF). A red-shift was observed from the non-polar aprotic solvent to the polar aprotic solvent, and the emission intensity was gradually decreased.

Effects of Xanthene Fluorophore on Light Physical Properties and their Dyeing Performance on Modacrylic Fabrics.

We designed the new xanthene dyes by introducing the donor and acceptor group of electrons in the 5' position of the carboxyphenyl ring. These synthesized dye molecules were identified using spectroscopy. And the photophysical studies, such as solvent optimization, were further explored before and after photodegradation of all synthesized dye compounds in both states (solution and solid).

A novel class of xanthene dyes with chemically linked UV absorber molecule and their photophysical properties.

In this paper, we prepared a new class of chemically linked UV absorber XU2 & XU3, and their photophysical, chemical properties and substrate durability were investigated. Spectroscopic behavior at various solvent and pH levels for this dye solution has been evaluated. Successfully designed an open ring form of xanthene moiety, linked a UV absorber to it, and made XU2 & XU3 that have shown good absorbance and emission band maxima at all solvents and pH mediums.

Endodontic management of pulp canal obliteration using a new single-tooth template: A case series.

Background: Guided Endodontics is suggested as a reliable method for management of teeth with pulp canal obliteration (PCO). The guide used for this usually involves multiple teeth to gain stability but is bulky. It is therefore suboptimal to be used along with rubber dam.

Altered electrochemical properties of iron oxide nanoparticles by carbon enhance molecular biocompatibility through discrepant atomic interaction.

Recent advancement in nanotechnology seeks exploration of new techniques for improvement in the molecular, chemical, and biological properties of nanoparticles. In this study, carbon modification of octahedral-shaped magnetic nanoparticles (MNPs) was done using two-step chemical processes with sucrose as a carbon source for improvement in their electrochemical application and higher molecular biocompatibility. X-ray diffraction analysis and electron microscopy confirmed the alteration in single-phase octahedral morphology and carbon attachment in FeO structure.

Seasonal variation and mobility of trace metals in the beach sediments of NW Borneo.

Miri city has a dynamic coastal environment, mainly influenced by intensive sedimentation from the Baram River and excessive trace metal loading by the Miri River, which are significant environmental concerns. As the mobility, bioavailability, and toxicity of the trace metals in the sediments are largely controlled by their particulate speciation, the modified BCR sequential extraction protocol was applied to determine the particulate speciation of trace metals in the coastal sediments of Miri, to unravel the seasonal geochemical processes responsible for known observations, and to identify possible sources of these trace metals. The granulometric analysis results showed that littoral currents aided by the monsoonal winds have influenced the grain size distribution of the sediments, enabling us to divide the study area into north-east and south-west segments where the geochemical composition are distinct.

Analysis of tebuconazole residues in coconut water, kernel and leaves using LC-MS/MS.

A method was validated for determining tebuconazole residues in coconut water, kernel and leaves using Liquid chromatography-Mass spectrometry/Mass spectrometry (LC-MS/MS) with electro spray ionization in positive ion mode. Samples were extracted with acetonitrile and subsequent clean-up was done using dispersive solid phase extraction. Recovery ranged between 70 and 114.

Geochemical behaviour and risk assessment of trace elements in a tropical river, Northwest Borneo.

By convention, dissolved trace elements in the river water are considered to be the fraction that passes through a 0.45 μm filter. However, several researchers have considered filtration cut-off other than 0.

Thioalkyl-Functionalized Bithiophene (SBT)-Based Organic Sensitizers for High-Performance Dye-Sensitized Solar Cells.

A series of 3,3'-dithioalkyl-2,2'-bithiophene (SBT)-based organic chromophores were designed and developed for the use in dye-sensitized solar cells (DSSCs). By appropriate structural modification of the SBT π-linkers with different alkyl chains and conjugated thiophene units, chromophore aggregation and interfacial charge recombination could be suppressed to a remarkable degree. Single-crystal and optical/electrochemical data clearly show that the SBT core is nearly planar with the torsional angle <1°, likely via S(alkyl)···S(thiophene) intramolecular locks.

Bioaccumulation of trace metals in the coastal Borneo (Malaysia) and health risk assessment.

The concentration of nine trace elements were analyzed in the different tissue organs of commonly available crabs (Portunus sanguinolentus, Portunus pelagicus and Scylla serrate) and bivalve (Polymesoda erosa) species collected from the Miri coast, Borneo in order to evaluate the potential health risk by consumption of these aquatic organisms. Among the analyzed organs, metal accumulation was higher in the gill tissues. The essential (Cu and Zn) and non-essential (Pb and Cd) elements showed the highest (i.

Environmental significance and geochemical speciation of trace elements in Lower Baram River sediments.

The geochemistry and distribution of major, trace and rare earth elements (REE's) was studied in the surface sediments of the Lower Baram River during two seasons: the Monsoon (MON) and Post - monsoon (POM). The major geochemical processes controlling the distribution and mobility of major, trace and REE's in the Lower Baram River surface sediments was revealed through factor analysis. The risk assessment of major and trace element levels was studied at three specific levels; i.

Human health risk assessment and bioaccumulation of trace metals in fish species collected from the Miri coast, Sarawak, Borneo.

The concentrations of nine trace metals (Cr, Mn, Co, Ni, Cu, Zn, Rb, Cd, and Pb) were measured in different tissues of two pelagic and five demersal fish species collected from the Miri coast, Sarawak. The sequence of accumulation of trace metals in different tissues were: liver > gill > gonad > muscle. Zn (301.

Distribution of isopod parasites in commercially important marine fishes of the Miri coast, East Malaysia.

Isopods occur very commonly as parasites in food fishes. Parasitic isopods are typically marine and usually inhabit the warmer seas. They are blood-feeding; several species settle in the buccal cavity of fish, others live in the gill chamber or on the body surface including the fins.

Synthesis of new colori/fluorimetric chemosensor for selective sensing of biologically important Fe³⁺, Cu²⁺ and Zn²⁺ metal ions.

New Schiff base chemosensors (1 and 2) based on aryl ether amine were synthesized and demonstrated positional isomer and functional group dependent colori/fluorimetric sensing of Fe(3+), Cu(2+) and Zn(2+) at ppm level. Methoxy salicylaldehyde based chemosensor 1 exhibited selective colorimetric sensing of Fe(3+) whereas 2-hydroxy naphthaldehyde based chemosensor 2 showed selective disappearance of yellow color for Cu(2+) ions. Interestingly, both 1 and 2 exhibited a highly selective strong turn-on fluorescence for Zn(2+).

Metal-free tetrathienoacene sensitizers for high-performance dye-sensitized solar cells.

A new series of metal-free organic chromophores (TPA-TTAR-A (1), TPA-T-TTAR-A (2), TPA-TTAR-T-A (3), and TPA-T-TTAR-T-A (4)) are synthesized for application in dye-sensitized solar cells (DSSC) based on a donor-π-bridge-acceptor (D-π-A) design. Here a simple triphenylamine (TPA) moiety serves as the electron donor, a cyanoacrylic acid as the electron acceptor and anchoring group, and a novel tetrathienoacene (TTA) as the π-bridge unit. Because of the extensively conjugated TTA π-bridge, these dyes exhibit high extinction coefficients (4.

A highly conjugated benzimidazole carbene-based ruthenium sensitizer for dye-sensitized solar cells.

A new type of carbene-based ruthenium sensitizer, CB104, with a highly conjugated ancillary ligand, diphenylvinylthiophene-substituted benzimidazolepyridine, was designed and developed for dye-sensitized solar cell applications. The influence of the thiophene antenna on the performance of the cell anchored with CB104 was investigated. Compared with the dye CBTR, the conjugated thiophene in the ancillary ligand of CB104 enhanced the molar extinction coefficient of the intraligand π-π* transition and the intensity of the lower energy metal-to-ligand charge-transfer band.

Generation of sub wavelength super-long dark channel using high NA lens axicon.

We investigate the focusing properties of a double-ring-shaped azimuthally polarized beam by a high numerical aperture (NA) lens axicon based on vector diffraction theory. We observe that our proposed system generates a sub wavelength focal hole of 0.5λ having large uniform focal depth of 48λ without any annular aperture.

Empirical evidence of the effectiveness of concept mapping as a learning intervention for nuclear medicine technology students in a distance learning radiation protection and biology course.

Unlabelled: Metacognitive learning strategies are based on instructional learning theory, which promotes deep, meaningful learning. Educators in a baccalaureate-level nuclear medicine technology program demonstrated that students enrolled in an online, distance learning section of an introductory radiation protection and radiobiology course performed better when traditional instruction was supplemented with nontraditional metacognitive learning strategies.

Methods: The metacognitive learning strategy that was used is best known as concept mapping.

6-Methyl-2,3,4,9-tetra-hydro-1H-carbazole-1-thione.

In the title mol-ecule, C(13)H(13)NS, the dihedral angle between the benzene ring and the fused pyrrole ring is 0.71 (8)° and the cyclo-hexene ring is in an envelope form. The (CH(2))(3) atoms of the cyclo-hexene ring are disordered over two positions; the site-occupancy factor for the major component refined to 0.