Publications by authors named "Popovich A"

In recent years, 3D printing has emerged as a promising technology in energy storage, particularly for the fabrication of Li-ion battery electrodes. This innovative manufacturing method offers significant material composition and electrode structure flexibility, enabling more complex and efficient designs. While traditional Li-ion battery fabrication methods are well-established, 3D printing opens up new possibilities for enhancing battery performance by allowing for tailored geometries, efficient material usage, and integrating multifunctional components.

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  • This study focuses on the properties of Inconel 718/Ti6Al4V multi-material samples with a Cu and Nb interlayer produced using selective laser melting (SLM).
  • It investigates the microstructure, chemical composition, phase composition, and hardness, revealing island macro-segregation at interfacial zones and distinct transitions in chemical composition.
  • The findings indicate that while no new phases were formed, there were notable changes in microhardness and the ultimate tensile strength of the samples was found to be 910 MPa.
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Multi-material can have functional properties, which are not typical for the materials of which they are composed (for instance, shape-changing effect). This can be used in robotics, micromachines, aerospace, and other fields. In this work, the 316L/FeNi36 multi-material produced by selective laser melting was investigated.

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  • Ion implantation in diamonds is crucial for creating conductive microstructures and isolated photon emitters, with emission lines HR1 and HR2 observed around 536 nm and 560 nm.
  • The study involved a thorough examination of helium-related optical centers in natural single-crystal type IIa diamonds, using a 700 nm-thick layer subjected to multiple-energy helium ion implantation and subsequent annealing at various temperatures.
  • Results revealed over a dozen unique photoluminescence centers within the 530-630 nm range, emphasizing the impact of annealing on the spectra and identifying specific bands related to interstitial defects in diamonds.
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This paper investigated the influence of titanium carbide (TiC) content on the processing, microstructure, mechanical and tribological properties of Inconel 718/TiC composites produced by binder jetting additive manufacturing. It was found that increasing the amount of TiC required an increase of the drying intensity during printing due to a decrease in the thermal conductivity of the powder mixture. The sintering process also depended on the TiC content.

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Recently, progress has been made in fabricating diamond-based scintillators with integrated rare-earth luminescent particles. These luminescent particles are integrated into the bulk of diamond during their synthesis by chemical vapor deposition (CVD). However, the growth conditions include a chemically aggressive plasma environment and elevated temperatures, which results in the partial degradation of particles and a decrease in the intensity of their luminescence.

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Wiedemann-Rautenstrauch syndrome (neonatal progeroid syndrome) is an ultra-orphan disease from the group of premature aging syndromes with an autosomal recessive type of inheritance associated with mutations in the POLR3A, POLR3B, and POLR3GL genes encoding RNA polymerase III. The incidence of the disease is currently unknown. We present the first clinical description in Russian Federation of a patient 7 years 6 months old with Wiedemann-Rautenstrauch syndrome (compound heterozygous mutations in POLR3A gene) with progeroid features, adentia, growth retardation (height SDS -3,41, height velocity SDS -2,47), underweight (BMI SDS -6,20), and generalized lipodystrophy.

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Laser powder bed fusion (LPBF) is a prospective and promising technique of additive manufacturing of which there is a growing interest for the development and production of Fe-based bulk metallic glasses and amorphous-nanocrystalline composites. Many factors affect the quality and properties of the resulting material, and these factors are being actively investigated by many researchers, however, the factor of the inert gas atmosphere used in the process remains virtually unexplored for Fe-based metallic glasses and composites at this time. Here, we present the results of producing amorphous-nanocrystalline composites from amorphous Fe-based powder via LPBF using argon and helium atmospheres.

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  • Bi-allelic pathogenic variations in a specific gene are linked to various hereditary disorders, including the rare Wiedemann-Rautenstrauch syndrome (WRS), which shows neonatal symptoms like growth issues and distinctive facial features.
  • This study details a clinical case of a 7-year-old girl with WRS, where whole-exome sequencing revealed a novel missense variant and two intronic variants associated with the condition.
  • The findings confirm the pathogenic nature of these genetic changes, contributing to the understanding of POLR3A-related disorders and highlighting the need for further research in the area.
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The application of additive manufacturing method such as material extrusion (MEX) allows the successful fabrication of ceramic products, including multi-ceramic products. Promising materials in this research area are TiO and ZrO ceramics, which can be used in electrical and electronic engineering. The aim of this work is to investigate the possibility of fabricating TiO/ZrO multi-materials from ceramic pastes that can be used in the MEX.

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Additive manufacturing is a very rapidly developing industrial field. It opens many possibilities for the fast fabrication of complex-shaped products and devices, including functional materials and smart structures. This paper presents an overview of polymer 3D printing technologies currently used to produce magnetic materials and devices based on them.

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This manuscript shows the study of the structure, mechanical, and chemical properties of high-entropy borides MeB (Me = Ti, Ta, Nb, Hf, Zr). High-entropy borides were synthesized by mechanical alloying and spark plasma sintering. A chemically homogeneous powder with a low iron content (0.

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Chemical vapor deposition synthesis of graphene on polycrystalline copper substrates from methane is a promising technique for industrial production and application. However, the quality of grown graphene can be improved by using single-crystal copper (111). In this paper, we propose to synthesize graphene on epitaxial single-crystal Cu film deposited and recrystallized on a basal-plane sapphire substrate.

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We report on a novel method for porous diamond fabrication, which is based on the synthesis of diamond-germanium composite films followed by etching of the Ge component. The composites were grown by microwave plasma assisted CVD in CH-H-GeH mixtures on (100) silicon, and microcrystalline- and single-crystal diamond substrates. The structure and the phase composition of the films before and after etching were analyzed with scanning electron microscopy and Raman spectroscopy.

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In the search for novel anode materials for lithium-ion batteries (LIBs), organic electrode materials have recently attracted substantial attention and seem to be the next preferred candidates for use as high-performance anode materials in rechargeable LIBs due to their low cost, high theoretical capacity, structural diversity, environmental friendliness, and facile synthesis. Up to now, the electrochemical properties of numerous organic compounds with different functional groups (carbonyl, azo, sulfur, imine, etc.) have been thoroughly explored as anode materials for LIBs, dividing organic anode materials into four main classes: organic carbonyl compounds, covalent organic frameworks (COFs), metal-organic frameworks (MOFs), and organic compounds with nitrogen-containing groups.

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Additive Manufacturing (AM) of multimaterial components is a promising way of fabricating parts with improved functional properties. It allows for the combination of materials with different properties into a single component. The TiAlNb-based intermetallic alloy provides high temperature strength, while the Ti-6Al-4V (Ti64) alloy has good fracture toughness, ductility, and a relatively low cost.

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The article presents the results of the synthesis of lead-free piezoceramic materials (BaCa)(TiZr)O (BCZT system) in spherical powder form and their subsequent application in the binder jetting additive manufacturing process. Green models were manufactured using this powder material with binder jetting, different sintering modes were investigated, and the functional piezoelectric properties were measured. Lattice structures with triply periodic minimum surface topologies, such as Gyroid and Schwarz, were designed and manufactured.

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The paper presents the results of a study of the possibility of Inconel 718 alloy properties modifying by adding Yttrium in situ in the process of selective laser melting. The single and double laser processing of each layer was used. Yttrium was introduced into the alloy in an amount of 0.

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Algal biomass synthesised nanocomposites have a higher surface area and reusability advantages. This study aimed to synthesise and characterise ZnMgO and silica-supported graphene with ZnMgO (G-ZnMgO) nanocomposites from and evaluate their potential in the application of photocatalysis to remove Rhodamine-B (RhB) and methylene blue (MB) dyes from their aqueous medium by maximising the percentage removal using response surface methodology (RSM) modelling. Nanocomposites were synthesised and characterised by biogenic and instrumental (Powder X-ray diffraction (P-XRD), electron microscopic analysis (SEM and TEM), Fourier transform infrared spectroscopy (FTIR), Energy dispersive analysis of X-rays (EDAX).

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Functionally graded piezoceramics are a new generation of engineering materials whose final properties are determined by a chemical composition gradient (volume distribution), material microstructure, or design characteristics. This review analyzes possible ways to create a functionally graded piezoceramic material (gradient chemical composition, gradient porosity-controlled and disordered porosity) by additive manufacturing methods, to control such materials' functional characteristics. An analysis of the creation of gradient piezoceramics using binder jetting technology is presented in more detail.

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Original 1CP powder was studied and it was founded that powder material partially consists of the amorphous phase, in which crystallization begins at 450 °C and ends at 575 °C. Selective laser melting parameters were investigated through the track study, and more suitable ones were found: laser power = 90, 120 W; scanning speed = 1200 mm/s. Crack-free columnar elements were obtained.

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The present paper illustrates a comparison of open-cell aluminum foams. The foams were fabricated by two different methods: spark plasma sintering and replication on a polyurethane template. The influence of pressure, temperature, and diameter of space holding material on foam obtained by the spark plasma sintering method was investigated.

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Solid-state reaction was used for LiLaZrO material synthesis from LiCO, LaO and ZrO powders. Phase investigation of LiLaZrO was carried out by x-ray diffraction (XRD), scanning electron microscopy (SEM) and energy-dispersive x-ray spectroscopy (EDS) methods. The thermodynamic characteristics were investigated by calorimetry measurements.

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Three-dimensional printed nitinol (NiTi) alloys have broad prospects for application in medicine due to their unique mechanical properties (shape memory effect and superplasticity) and the possibilities of additive technologies. However, in addition to mechanical properties, specific physicochemical characteristics of the surface are necessary for successful medical applications. In this work, a comparative study of additively manufactured (AM) NiTi samples etched in HSO/HO, HCl/HSO and NHOH/HO mixtures was performed.

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LiFeN material was synthesized by the two-step solid-state method from LiN (adiabatic camera) and FeN (tube furnace) powders. Phase investigation of LiN, FeN, and LiFeN was carried out. The discharge capacity of LiFeN is 343 mAh g, which is about 44.

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