Multichannel carbon nanofibers (MCNFs), characterized by complex hierarchical structures comprising multiple channels or compartments, have attracted considerable attention owing to their high porosity, large surface area, good directionality, tunable composition, and low density. In recent years, electrospinning (ESP) has emerged as a popular synthetic technique for producing MCNFs with exceptional properties from various polymer blends, driven by phase separation between polymers. These interactions, including van der Waals forces, covalent bonding, and ionic interactions, are crucial for MCNF production.
View Article and Find Full Text PDFMXene is recognized as a promising catalyst for versatile applications due to its abundant metal sites, physicochemical properties, and structural formation. This comprehensive review offers an in-depth analysis of the incorporation of carbon into MXene, resulting in the formation of MXene-carbon-based composites (MCCs). Pristine MXene exhibits numerous outstanding characteristics, such as its atomically thin 2D structure, hydrophilic surface nature, metallic electrical conductivity, and substantial specific surface area.
View Article and Find Full Text PDFOrganophosphorus pesticides, particularly profenofos (PF), pose a significant threat to the food supply and human health due to their persistence, toxicity, and resistance to natural breakdown processes. An urgent need exists for an environmentally friendly solution, and photocatalysis emerges as a practical, cost-effective option. However, challenges like poor light responsiveness and difficulties in material separation and reusability persist.
View Article and Find Full Text PDFThe misuse of antibiotics has become a concerning environmental issue, posing a significant threat to public health. Levofloxacin (LFX), a fluoroquinolone antibiotic, is particularly worrisome due to its detrimental impact on human health and the ecosystem. Therefore, the selective and accurate identification of LFX is of utmost importance.
View Article and Find Full Text PDFThis study introduces an efficient electrochemical method for rapidly identifying the pathogen Pseudomonas aeruginosa (P. aeruginosa), which poses threats to individuals with compromised immune systems and cystic fibrosis. Unlike conventional techniques such as polymerase chain reaction, which fails to detect modifications in the resistant properties of microbes due to environmental stress, our proposed electrochemical approach offers a promising alternative.
View Article and Find Full Text PDFFood Chem
March 2024
A glassy carbon electrode modification by a novel ternary nanocomposite of advantageously united ceria, polypyrrole, and graphitic carbon nitride (CeO/Ppy@g-CN) is reported here. It can be used to tailor the sensor surface for the electrochemical detection of nanomolar-level quinol (Qnl), a chemical widely used as a developing agent in photography and lithography, as a cosmetic, and as an antioxidant in rubber and food industries. The occupational exposure of Qnl may occur by inhalation or dermal contact, leading to lot of health hazards.
View Article and Find Full Text PDFThe measurement of renal function by important clinical parameters such as (Crt) clearance and glomerular filtration rate often goes wrong vis-à-vis the Crt level in human body. Hence, development of an accurate detection system over a wide range of Crt concentration in both blood and urine is medically essential. In this study, a new non-enzymatic electrochemical probe, carbon dots doped tungstic anhydride embedded on graphene oxide nanopanels (CDs/WO@GO) is reported for picomolar-level Crt detection in blood and urine with a wide linear range (0.
View Article and Find Full Text PDFThe fabrication of hetero structured materials with supercapacitor applications for industrial use remains a key challenge. This work reports a new supercapacitor material with high capacitance, comprising samaria and borazon (OSm/BN) synthesized ultrasonically (40 ± 3 kHz, 200 W). The successful synthesis, probable interfaces between OSm and BN and thermal stability of the nanocomposite were studied by UV-Vis.
View Article and Find Full Text PDFWater and soil contamination has become unavoidable due to the enormous usage of pesticides in agriculture. Among the pesticides, monocrotophos (MCP), a popular and largely used pesticide, is extremely toxic to birds and humans, which is easily leached into the environment. Therefore, establishment of a green tactic to clean the environment from such hazard is very essential.
View Article and Find Full Text PDFBisphenol A (BPA) is an endocrine-disrupting chemical which resembles structurally the hormone estrogen. Even a trace amount of BPA can bind estrogen receptors resulting in the inducement of reproductive disorders, cancers and problems related to sexual growth such as manliness in female and womanliness in male. So the determination of BPA in human and animal bodies is very essential.
View Article and Find Full Text PDFA binary nanocomposite of type copper tungstate and polyaniline (CuWO@PANI) is described that was obtained by single step polymerization on the surface of a glassy carbon electrode (GCE). The resulting electrode is shown to be a viable tool for voltammetric sensing of quercetin (Qn) in blood, urine and certain food samples. The nanocomposite was characterized by UV-visible absorption spectroscopy, Fourier-transform infrared spectroscopy, thermogravimetric analysis, X-ray diffraction and high-resolution transmission electron microscopy.
View Article and Find Full Text PDFThe novel N-CeO nanoparticles decorated on reduced graphene oxide (N-CeO@rGO) composite has been synthesized by sonochemical method. The characterization of as prepared nanocomposite was intensely performed by UV-Vis, FT-IR, EDX, FE-SEM, HR-TEM, XRD, and TGA analysis. The synthesized nanomaterial was further investigated for its selective and sensitive sensing of paracetamol (PM) based on a N-CeO@rGO modified glassy carbon electrode.
View Article and Find Full Text PDFA simple and very sensitive electrochemical sensor for the detection of uric acid (UA) has been developed based on polyaniline (PANI) merged into a silver-doped iron oxide (Ag-FeO) nanocomposite-modified glassy carbon electrode. The synthesized ternary composite material (Ag-FeO@PANI) was characterized by UV-visible spectroscopy, Fourier transform infrared spectroscopy, energy-dispersive X-ray, High-resolution transmission electron microscopy, X-ray diffraction, and thermo gravimetric analysis analyses. The nanocomposite-modified electrode shows an exceptional electrocatalytic activity and reversibility to the oxidation of UA in a 0.
View Article and Find Full Text PDFHerein, we have developed a facile and one pot synthesis of ternary CeO-AlO@GO nanocomposite via wet chemical method. The structural and morphological characteristics of the synthesized nanocomposite was investigated using UV-DRS, FT-IR, XRD, FE-SEM, HR-TEM, EDX and TGA analysis. The CeO-AlO@GO composite was tested for its ability to photocatalytically degrade Rhodamine B (RhB) under visible light illumination.
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