Ultrasound-Assisted Synthesis of SnS Quantum Dots Using Acetone as Solvent.

A sonochemical synthesis of SnS quantum dots using acetone as a solvent is investigated. Two different tin sources (SnCl∙2HO or SnCl∙5HO) as well as two different sulfur sources (thioacetamide or NaSO) were applied. The sonication time was also varied between 60 and 120 min.

Multifaceted bone response to immunomodulatory magnesium implants: Osteopromotion at the interface and adipogenesis in the bone marrow.

Orthopedic implants made of biodegradable magnesium (Mg) provide an alternative to nondegradable implants for fracture repair. Widely reported to be pro-osteogenic, Mg implants are also believed to be anti-inflammatory and anti-osteoclastic, but this is difficult to reconcile with the early clinical inflammation observed around these implants. Here, by surveying implant healing in a rat bone model, we determined the cellular responses and structural assembly of bone correlated with the surface changes of Mg implants inherent in degradation.

Bone cells influence the degradation interface of pure Mg and WE43 materials: Insights from multimodal in vitro analysis.

In this study, the interaction of pure Mg and WE43 alloy under the presence of osteoblast (OB) and osteoclast (OC) cells and their influence on the degradation of materials have been deeply analyzed. Since OB and OC interaction has an important role in bone remodeling, we examined the surface morphology and dynamic changes in the chemical composition and thickness of the corrosion layers formed on pure Mg and WE43 alloy by direct monoculture and coculture of pre-differentiated OB and OC cells in vitro. Electrochemical techniques examined the corrosion performance.

Sonochemical synthesis of SnS and SnS quantum dots from aqueous solutions, and their photo- and sonocatalytic activity.

Our study reports the ultrasound-assisted synthesis of SnS and SnS in the form of nanoparticles using aqueous solutions of respective tin chloride and thioacetamide varying sonication time. The presence of both compounds is confirmed by powder X-ray diffraction, energy-dispersive X-ray spectroscopy, as well as Raman and FT-IR spectroscopic techniques. The existence of nanoparticles is proven by powder X-ray diffraction investigation and by high resolution transmission electron microscopy observations.

degradation behavior of Mg-0.45Zn-0.45Ca (ZX00) screws for orthopedic applications.

Magnesium (Mg) alloys have become a potential material for orthopedic implants due to their unnecessary implant removal, biocompatibility, and mechanical integrity until fracture healing. This study examined the and degradation of an Mg fixation screw composed of Mg-0.45Zn-0.

Magnesium implant degradation provides immunomodulatory and proangiogenic effects and attenuates peri-implant fibrosis in soft tissues.

Implants made of magnesium (Mg) are increasingly employed in patients to achieve osteosynthesis while degrading . Since Mg implants and Mg have been suggested to possess anti-inflammatory properties, the clinically observed soft tissue inflammation around Mg implants is enigmatic. Here, using a rat soft tissue model and a 1-28 d observation period, we determined the temporo-spatial cell distribution and behavior in relation to sequential changes of pure Mg implant surface properties and Mg release.

On the Influence of Manufacturing Parameters on the Microstructure, Mechanical Properties and Corrosion Resistance of AISI 316L Steel Deposited by Laser Engineered Net Shaping (LENS).

Samples of 316L SS were manufactured by Laser Engineered Net Shaping (LENS) using different technological parameters. The deposited samples were investigated in terms of microstructure, mechanical properties, phase content and corrosion resistance (salt chamber and electrochemical corrosion). Parameters were chosen to obtain a proper sample built for layer thicknesses of 0.

The combined effect of zinc and calcium on the biodegradation of ultrahigh-purity magnesium implants.

Magnesium (Mg)-based implants are promising candidates for orthopedic interventions, because of their biocompatibility, good mechanical features, and ability to degrade completely in the body, eliminating the need for an additional removal surgery. In the present study, we synthesized and investigated two Mg-based materials, ultrahigh-purity ZX00 (Mg-Zn-Ca; <0.5 wt% Zn and <0.

Comprehensive study upon physicochemical properties of bio-ZnO NCs.

In this study, for the first time, the comparison of commercially available chemical ZnO NCs and bio-ZnO NCs produced extracellularly by two different probiotic isolates (Latilactobacillus curvatus MEVP1 [OM736187] and Limosilactobacillus fermentum MEVP2 [OM736188]) were performed. All types of ZnO formulations were characterized by comprehensive interdisciplinary approach including various instrumental techniques in order to obtain nanocomposites with suitable properties for further applications, i.e.

Effects of Composite Coatings Functionalized with Material Additives Applied on Textile Materials for Cut Resistant Protective Gloves.

The objective of the present work was to evaluate the effects of different types of particles added to a polymer paste applied onto a textile carrier on the cut resistance of the resulting material. Knitted aramid textile samples were coated in laboratory conditions using a polymer paste that was functionalized with 12 types of reinforcing particles of different chemical compositions and size fractions. Cut resistance was tested in accordance with the standard EN ISO 13997:1999 and the results were subjected to statistical analysis.

Analysis of the Morphology and Structure of Carbon Deposit Formed on the Surface of NiAl Foils as a Result of Thermocatalytic Decomposition of Ethanol.

This article presents the results of investigations of the morphology and structure of carbon deposit formed as a result of ethanol decomposition at 500 °C, 600 °C, and 700 °C without water vapour and with water vapour (0.35 and 1.1% by volume).

Facile and reproducible method of stabilizing [Formula: see text] phases confined in nanocrystallites embedded in amorphous matrix.

Bismuth sesquioxide ([Formula: see text]) draws much attention due to wide variety of phases in which it exists depending on the temperature. Among them, [Formula: see text] phase is specially interesting because of its high oxide ion conductivity and prospects of applications as an electrolyte in fuel cells. Unfortunately, it is stable only in a narrow temperature range ca.

Design of SiC-Doped Piezoresistive Pressure Sensor for High-Temperature Applications.

Within these studies the piezoresistive effect was analyzed for 6H-SiC and 4H-SiC material doped with various elements: N, B, and Sc. Bulk SiC crystals with a specific concentration of dopants were fabricated by the Physical Vapor Transport (PVT) technique. For such materials, the structures and properties were analyzed using X-ray diffraction, SEM, and Hall measurements.

Insight into diatom frustule structures using various imaging techniques.

The diatom shell is an example of complex siliceous structure which is a suitable model to demonstrate the process of digging into the third dimension using modern visualization techniques. This paper demonstrates importance of a comprehensive multi-length scale approach to the bio-structures/materials with the usage of state-of-the-art imaging techniques. Imaging of diatoms applying visible light, electron and X-ray microscopy provide a deeper insight into the morphology of their frustules.

Sonochemical preparation of SnS and SnS nano- and micropowders and their characterization.

Sonochemical production of tin(II) and tin(IV) sulfides is investigated. Different conditions of syntheses are examined: used solvent (ethanol or ethylenediamine), source of tin (SnCl or SnCl), the molar ratio of thioacetamide to the tin source, and time of sonication. The obtained powders are characterized by the X-ray diffraction method (PXRD), scanning electron microscopy (SEM), scanning transmission electron microscopy (STEM), energy-dispersive X-ray spectroscopy (EDX), and the Tauc method.

Biodiversity of carapace epibiont diatoms in loggerhead sea turtles ( Linnaeus 1758) in the Aegean Sea Turkish coast.

Background: The Aegean Sea coast of Turkey hosts one of the most important nesting grounds for loggerhead sea turtles () in the Mediterranean Sea. Previous studies have revealed that the sea turtle carapace provides favourable conditions for various epibiontic organisms. Epibionts occurring on the carapace have been examined from different locations in the oceans.

Electron Microscopy Characterization of the High Temperature Degradation of the Aluminide Layer on Turbine Blades Made of a Nickel Superalloy.

The effects of exposure to overheating (temperature above 1000 °C) on the degradation (modification) of layers of coatings (coatings based on aluminum) of uncooled polycrystalline rotor blades of aircraft turbine jet engines were investigated under laboratory conditions. In order to determine the nature of the changes as well as the structural changes in the various zones, a multi-factor analysis of the layers of the coating, including the observation of the surface of the blades, using, among others, electron microscopy, structural tests, surface morphology, and chemical composition testing, was carried out. As a result of the possibility of strengthening the physical foundations of the non-destructive testing of blades, the undertaken research mainly focused on the characteristics of the changes occurring in the outermost layers of the coatings.

The Taxonomy and Diversity of Proschkinia (Bacillariophyta), A Common But Enigmatic Genus from Marine Coasts.

Detailed morphological documentation is provided for established Proschkinia taxa, including the generitype, P. bulnheimii, and P. complanata, P.

Cubic Silver Nanoparticles Fixed on TiO Nanotubes as Simple and Efficient Substrates for Surface Enhanced Raman Scattering.

In this work we show that ordered freestanding titanium oxide nanotubes (TiO NT) may be used as substrates for the simple and efficient immobilization of anisotropic plasmonic nanoparticles. This is important because anisotropic plasmonic nanostructures usually give greater spectral enhancement than spherical nanoparticles. The size of the pores in a layer of titanium oxide nanotubes can be easily fitted to the size of many silver plasmonic nanoparticles highly active in SERS (surface-enhanced Raman scattering) spectroscopy (for example, silver nanocubes with an edge length of ca.

Structure and properties of composite surface layers produced on NiTi shape memory alloy by a hybrid method.

A hybrid process that combines oxidation under glow-discharge conditions with ion beam-assisted deposition (IBAD) has been applied to mechanically polished NiTi shape memory alloy in order to produce composite surface layers consisting of a TiO layer and an external carbon coating with an addition of silver. The produced surface layers a-C(Ag) + TiO type have shown increased surface roughness, improved corrosion resistance, altered wettability, and surface free energy, as well as reduced platelet adhesion, aggregation, and activation in comparison to NiTi alloy in initial state. Such characteristics can be of great benefit for cardiac applications.

Hybrid a-CNH+TiO+TiN-type surface layers produced on NiTi shape memory alloy for cardiovascular applications.

Aim: The goal was to improve the properties of NiTi shape memory alloy to make it suitable for cardiac applications. For this purpose, a hybrid a-CNH+TiO+TiN-type surface layer was produced on NiTi alloy and characterized.

Materials & Methods: The NiTi alloy subjected to hybrid process combining low-temperature oxynitriding under glow discharge conditions and radio frequency chemical vapor deposition process was examined for microstructure, surface topography, corrosion resistance, wettability and surface-free energy, Ni ion release and platelets adhesion, aggregation and activation.

Phase imaging quality improvement by modification of AFM probes' cantilever.

Imaging of the surface of materials by atomic force microscopy under tapping and phase imaging mode, with use of modified probes is addressed. In this study, the circularly shaped holes located in varying distance from the probe base, were cut out by focused ion beam. Such modification was a consequence of the results of the previous experiments (probe tip sharpening and cantilever thinning) where significant improvement of image quality in tapping and phase imaging mode has been revealed.